• 제목/요약/키워드: magnetic oxide

검색결과 513건 처리시간 0.026초

폐 산화철촉매로부터 마그네타이트의 자력선별에 관한 연구 (A Study on the Magnetic Separation of Magnetite from Spent Iron-oxide Catalyst)

  • 현종영;이효숙;이우철;채영배
    • 자원리싸이클링
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    • 제11권3호
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    • pp.31-36
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    • 2002
  • 스틸렌 모노머 합성반응에서 발생하는 폐산화철 촉매로부터 마그네타이트의 품위향상을 위하여 5oo gauss와 1800 gauss에서 습식자력선별을 행하였다. 폐산화철 촉매는 주로 마그네타이트($Fe_3$$O_4$)와 세리아($CeO_2$) 및 가용성염($K_2$O, $MoO_3$)으로 이루어졌다. 습식자력선별에 의한 폐촉매중 자력산물의 회수율은 99% 이상이었으며, 마그네타이트 품위는 자력선별 전 70%에서 80%로 향상되었다. 이는 자력선별의 효과보다는 수세효과에 의한 가용성분인 K, Mo 염이 제거되었기 때문이다 자력산물 중 불순물은 주로 미세한 세리아이며 마그네타이트와 단체분리가 되지 않았다.

Formation of iron oxides from acid mine drainage and magnetic separation of the heavy metals adsorbed iron oxides

  • Kwon, Hee-won;Kim, JeongJin;Ha, Dong-Woo;Kim, Young-Hun
    • 한국초전도ㆍ저온공학회논문지
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    • 제18권1호
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    • pp.28-32
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    • 2016
  • There are a few thousand abandoned metal mines in South Korea. The abandoned mines cause several environmental problems including releasing acid mine drainage (AMD), which contain a very high acidity and heavy metal ions such as Fe, Cu, Cd, Pb, and As. Iron oxides can be formed from the AMD by increasing the solution pH and inducing precipitation. Current study focused on the formation of iron oxide in an AMD and used the oxide for adsorption of heavy metals. The heavy metal adsorbed iron oxide was separated with a superconducting magnet. The duration of iron oxide formation affected on the type of mineral and the degree of magnetization. The removal rate of heavy metal by the adsorption process with the formed iron oxide was highly dependent on the type of iron oxide and the solution pH. A high gradient magnetic separation (HGMS) system successfully separated the iron oxide and harmful heavy metals.

알루미늄 양극산화 피막의 구조 및 형상이 자기적 특성에 미치는 영향 (Effects of structure and morphology of anodized Al thin film on magnetic properties)

  • 권용덕;박용수
    • 한국표면공학회지
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    • 제26권2호
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    • pp.45-54
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    • 1993
  • In this study, magnetic properties of anodized Al film deposited with ferro-magnetic metals in the capacity of perpendicular magnetic recording media were measured and evaluated to find out the role of structure and morphology of the oxide films on magnetic characteristics. The object of this work was to present the conditions of magnetic thin film formation with more superior magnetic property. Anodizing was carried out under various conditions, and then the anodized film were electro-deposited with Co, Ni, Fe and their alloys. Coercive force and residual magnetization in perpendicular direction increased as the pore length of anodized film increased. It was attributed to the increase of the amount of depoisted metals and the ratio of length/diameter of pores. Morphology of anodized films in phosperic acid was not similar to that of sulfuric acid, and thin films in the former solution had perpendcular magnetic anisostropy because of large diameter, irregular length and distribution of the pores. It was found that magnetic properties of the thin films, which had doubled layer of two metals, were dominated by the metal electrodeposited on the surface of the anodized oxide films.

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자화된 헬리칼 공진기 플라즈마 소스를 이용한 고선택비 산화막 식각에 관한 연구 (A study on the high selective oxide etching using magnetized helical resonator plasma source)

  • 이수부;임승완;이석현
    • 대한전기학회논문지:전기물성ㆍ응용부문C
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    • 제48권5호
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    • pp.309-314
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    • 1999
  • The magnetized helical resonator plasma etcher has been built. Electron density and temperature were measured as functions of rf source power, axial magnetic field, and pressure. The results show electron density increases as the magnetic field increases and reached $2\times1012cm^{-3}$,/TEX>. The oxide etch rate and selectivity to polysilicon were investigated as the above mentioned conditions and self-bias voltage. We can obtain the much improved oxide etch selectivity to polysilicon (60 : 1) by applying the external axial weak magnetic field in magnetized helical resonator plasma etcher.

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자기 온열 시스템의 열 발생 효율에 관한 실험적 연구 (The Experimental Study of Heat Generation Efficiency of Magnetic Hyperthermia System)

  • 송영진;오정환
    • 한국연소학회지
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    • 제16권2호
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    • pp.33-39
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    • 2011
  • We demonstrated heat generation efficiency of the magnetic hyperthermia system to find optimal condition using gelatin tissue phantom. Magnetic hyperthermia induction can be used to make heat generation with different concentration of $Fe_3O_4$ iron oxide inside tissue phantom and magnetically labeled cells by applying AC magntic field at a frequency of 145 kHz. It was observed that the maximum temperature achieved in the magnetic gelatin tissue phantom increased with the concentration of $Fe_3O_4$ iron oxide and alternating magnetic field intensity. Results were discussed with respect to further optimization of therapeutic technique for biomedical application with modified functional nanoparticles.

산화철 나노 입자의 발열 효과의 제어 (Controlling the Heat Generation Capability of Iron Oxide-Base Nanoparticles)

  • 최진실
    • 한국분말재료학회지
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    • 제28권6호
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    • pp.518-526
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    • 2021
  • This review summarizes the recent progress in iron-oxide-based heat generators. Cancer treatment using magnetic nanoparticles as a heat generator, termed magnetic fluid hyperthermia, is a promising noninvasive approach that has gained significant interest. Most previous studies on improving the hyperthermia effect have focused on the construction of dopant-containing iron oxides. However, their applications in a clinical application can be limited due to extra dopants, and pure iron oxide is the only inorganic material approved by the Food and Drug Administration (FDA). Several factors that influence the heat generation capability of iron-oxide-based nanoparticles are summarized by reviewing recent studies on hyperthermia agents. Thus, our paper will provide the guideline for developing pure iron oxide-based heat generators with high heat dissipation capabilities.

전이금속산화물 클러스터의 자기구조 및 자기이방성에너지 계산 (The Magnetic Structure and Magnetic Anisotropy Energy Calculations for Transition Metal Mono-oxide Clusters)

  • 박기택
    • 한국자기학회지
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    • 제21권1호
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    • pp.1-4
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    • 2011
  • 정육면체 전이금속 산화물 FeO, MnO의 자기적 상호작용을 제1원리의 범밀도함수법을 이용하여 계산하였다. 그 결과, 모두 초교환작용으로 인해 반강자성적 상호작용이 가장 낮은 에너지를 가지고 있었다. 자기이방성은 반강자성 스핀 배열의 FeO 클러스터에서만 발견되었다. 그 원인은 <111> 방향으로 각운동량을 가지는 3d down-spin 전자의 스핀-궤도 결합에 기인하였다.

Purification of Iron Oxides and Application to Magnetic Hard Ferrite

  • Kim, Jeong-Seog;Chou, Kyoung-Ho;Kim, Jai-Young
    • The Korean Journal of Ceramics
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    • 제2권3호
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    • pp.125-130
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    • 1996
  • Hematite iron ore and waste iron oxide sludge containing about 3-5 wt% $SiO_2$ were purified by three types of method developed on the basis of the Bayer process which is known as the purification process of bauxite ore. The basic principle of the developed methods lies in the fact that the impurities contained in the iron oxides, such as $SiO_2$ and $Al_2O_3$ are soluble in the alkaline reagents. Reaction of the raw materials with KOH was done in pressure vessel, at atmospheric pressure, and by both of these two. By the pressure vessel method $SiO_2$ content was reduced to below 0.5 wt% in the waste iron oxide sludge, while, in iron ore, $SiO_2$ remained at 2-3 wt%. The atmospheric pressure reaction rendered the waste iron oxide sludge $SiO_2$ content below 0.5wt% when the reaction temperature increased to above 90$0^{\circ}C$. The combined method of two previous methods was the most effective process and rendered the refined iron oxide about 300-400ppm of $SiO_2$. Using some refined iron oxides, Ba-ferrite was produced and magnetic properties were measured. The highest quality of magnetic properties obtained in this study were Br=2.09 G, bHc=1.99 KOe, iHc=4.54 KOe, $(BH)_{max}$=1.06 MGOe. Effect of sintering condition and chemical composition will be discussed.

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초음파 습식 자기분류법을 이용한 MgxNiyZn1-x-yFe2O4 나노입자 제조 (Preparation of Nano-sized MgxNiyZn1-x-yFe2O4 by Ultrasonic Wet-Magnetic Separation Method)

  • 구문선;권혁주;최용
    • 한국표면공학회지
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    • 제50권3호
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    • pp.212-218
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    • 2017
  • $Mg_xNi_yZn_{1-x-y}Fe_2O_4$ ferrite powders were prepared by self-propagating high temperature synthesis followed by classifying with an ultrasonic wet-magnetic separation unit to get high pure nano-sized particles. The $Mg_xNi_yZn_{1-x-y}Fe_2O_4$ ferrites were well formed by using several powders like iron, nickel oxide, zinc oxide and magnesium oxide at 0.1 MPa of oxygen pressure. The ultrasonic wet-magnetic separation of pre-mechanical milled ferrite powders resulted in producing the powders with average size of 800 nm. The addition of a surfactant during the wet-magnetic separation process improved productivity more than twice. The coercive force, maximum magnetization and residual magnetization of the $Mg_xNi_yZn_{1-x-y}Fe_2O_4$ nano-powders with 800 nm size were 3651 A/m, $53.92Am^2/kg$ and $4.0Am^2/kg$, respectively.