• 제목/요약/키워드: magnesium sulfate

검색결과 227건 처리시간 0.023초

칼슘과 마그네슘염을 이용한 축산폐수의 응집처리 (Treatment of stock wastewater by flocculation with Calsium and Magnesium salts)

  • 김재용
    • 환경위생공학
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    • 제17권4호
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    • pp.10-18
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    • 2002
  • The changes of conventional clarification processe and an increase in treatment cost are required to meet increasingly stringent regulations related to the treated water quality. Although many enhanced coagulations have introduced to improve organic matter removal, the results to remove color, nitrogen and phosphorus as well as organic material have not been very efficient yet. In this context as new flocculation using calcium hydroxide and magnesum sulfate was carried out. The removal of waste matters such as SS, organic matter, COD, nitrogen and phosphorus contained in stock wastewater was carried out by using the combination of calcium hydroxide and magnesium sulfate. The flocculation was investigated as a function of coagulant dose, pH, mixing time, settling time and coagulant addition modes such as the sequential addition of the two coagulants and the simultaneous addition of them. The flocculation by the combination of calcium hydroxide and magnesium sulfate was compared with that by aluminum sulfate. The mechanism of flocculation was investigated as well. About 60% of COD in stock watewater was removed by flocculation with combination of calcium hydroxide and magnesium sulfate.

폐유리를 혼입한 콘크리트의 황산마그네슘 저항성에 관한 연구 (Magnesium Sulfate Resistance of Concrete Containing Waste Glass)

  • 김영수;정유진;이동운
    • 한국건축시공학회지
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    • 제9권3호
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    • pp.109-116
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    • 2009
  • The magnesium sulfate solution digestion test carried out for resistance of concrete containing waste glass powder on magnesium sulfate attack. Moreover, it yielded S.D.F index was used for the criteria of quantitative assessment to the resistance of magnesium sulfate for the purpose of evaluation of chemical deterioration on concrete. Furthermore, to evaluate for micro-cracks within concrete and external corrosion, the weight variation of specimens and the dynamic elasticity were compared and analyzed and also the applicability was examined using the analysis of product of hydration through out observing external deformation and micro-structural deformation.

Performance of FRP confined and unconfined geopolymer concrete exposed to sulfate attacks

  • Alzeebaree, Radhwan;Gulsan, Mehmet Eren;Nis, Anil;Mohammedameen, Alaa;Cevik, Abdulkadir
    • Steel and Composite Structures
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    • 제29권2호
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    • pp.201-218
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    • 2018
  • In this study, the effects of magnesium sulfate on the mechanical performance and the durability of confined and unconfined geopolymer concrete (GPC) specimens were investigated. The carbon and basalt fiber reinforced polymer (FRP) fabrics with 1-layer and 3-layers were used to evaluate the performances of the specimens under static and cyclic loading in the ambient and magnesium sulfate environments. In addition, the use of FRP materials as a rehabilitation technique was also studied. For the geopolymerization process of GPC specimens, the alkaline activator has selected a mixture of sodium silicate solution ($Na_2SiO_3$) and sodium hydroxide solution (NaOH) with a ratio ($Na_2SiO_3/NaOH$) of 2.5. In addition to GPC specimens, an ordinary concrete (NC) specimens were also produced as a reference specimens and some of the GPC and NC specimens were immersed in 5% magnesium sulfate solutions. The mechanical performance and the durability of the specimens were evaluated by visual appearance, weight change, static and cyclic loading, and failure modes of the specimens under magnesium sulfate and ambient environments. In addition, the microscopic changes of the specimens due to sulfate attack were also assessed by scanning electron microscopy (SEM) to understand the macroscale behavior of the specimens. Results indicated that geopolymer specimens produced with nano-silica and fly ash showed superior performance than the NC specimens in the sulfate environment. In addition, confined specimens with FRP fabrics significantly improved the compressive strength, ductility and durability resistance of the specimens and the improvement was found higher with the increased number of FRP layers. Specimens wrapped with carbon FRP fabrics showed better mechanical performance and durability properties than the specimens wrapped with basalt FRP fabrics. Both FRP materials can be used as a rehabilitation material in the sulfate environment.

고온기 육계의 수송 스트레스에 대한 버퍼제 급여에 따른 닭고기 품질 및 PSE 발생에 미치는 영향 (Effects of Dietary Buffer Material for Chicken Meat Grades and PSE Incidence in Broilers under Transport Heat Stress)

  • 채현석;최희철;나재천;장애라;김민지;방한태;강환구;김동욱;서옥석;박성복;함준상
    • 한국가금학회지
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    • 제37권2호
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    • pp.131-137
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    • 2010
  • 고온기 때 육계 수송 스트레스를 줄이기 위한 대비책으로 농가에서 출하 2일전에 버퍼제(sodium phosphate, sodium bicarbonate, magnesium sulfate)를 급여함으로 육계의 품질에 미치는 영향을 구명하기 위해 수행하였다 닭고기의 품질 $1^+$ 등급 평가에서 버퍼제를 급여하지 않는 대조구에서 4%를 차지하였으나 sodium phosphate 급여구가 8%, sodium bicarbonate 급여구 14%, magnesium sulfate 급여구가 28%로 대조구에 비하여 버퍼제를 급여한 처리구에서 $1^+$등급 출현율이 증가하였다. PSE 발생율은 대조구에서 경증 및 중증 모두 합하여 92%를 차지하였으나, sodium phosphate 급여구가 88%, sodium bicarbonate 급여구 28%, magnesium sulfate 급여구가 56%로 대조구에 비하여 버퍼제를 급여한 처리구에서 PSE 발생율이 현저히 저하되었다. 닭고기 외관의 멍은 대조구에서는 1~6 cm의 멍이 32%를 차지하였으나, sodium phosphate 급여구는 22%, sodium bicarbonate 급여구 24%, magnesium sulfate 급여구가 44%로 magnesium sulfate 급여구를 제외하고는 대조구에 비해 멍 발생율의 8~10% 정도 저하하였다. 닭고기의 명도($L^*$) 값의 변화는 가슴 근육 부위에서 대조구가 67.88을 나타내었고, sodium phosphate 급여구가 67.05, sodium bicarbonate 급여구 66.27, magnesium sulfate 급여구가 65.89로 magnesium sulfate 급여구에 명도가 가장 낮은 경향을 나타내었고, 전체적으로 대조구에 비해 버퍼제를 급여한 구에서 명도 값이 저하되었다. 상기와 같이 고온기 때 육계 수송 스트레스를 줄이기 위하여 버퍼제(sodium phosphate, sodium bicarbonate, magnesium sulfate)를 급여함으로 사계 및 닭고기의 이상 도체를 줄일 수 있을 것으로 사료된다.

칼슘과 마그네슘염을 이용한 염색폐수의 응집처리 (Treatment of Dyeing Wastewater by Flocculation with Calsium and Magnesium salts)

  • 김재용;서완주
    • 환경위생공학
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    • 제17권3호
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    • pp.89-98
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    • 2002
  • The changes of conventional clarification process and an increase in treatment cost are required to meet increasingly stringent regulations related to the treated water quality. Although many enhanced coagulations have introduced to improve organic matter removal, the results to remove color, nitrogen and phosphorus as well as organic material have not been very efficient yet. The removal of waste matters such as SS, organic matter, color and turbidity contained in dyeing wastewater was carried out by using the combination of calcium hydroxide and magnesium sulfate. The flocculation was investigated as a function of coagulant dose, pH, mixing time, settling time and coagulant addition modes such as the sequential addition of the two coagulants and the simultaneous addition of them. The flocculation by the combination of calcium hydroxide and magnesium sulfate was compared with that by aluminum sulfate. The mechanism of flocculation was investigated as well. About 84% of color in dyeing watewater was removed by flocculation with combination of calcium hydroxide and magnesium sulfate.

Durability properties of fly ash-based geopolymer mortars with different quarry waste fillers

  • Tammam, Yosra;Uysal, Mucteba;Canpolat, Orhan
    • Computers and Concrete
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    • 제29권 5호
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    • pp.335-346
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    • 2022
  • Geopolymers are an important alternative material supporting recycling, sustainability, and waste management. Durability properties are among the most critical parameters to be investigated; in this study, the durability of manufactured geopolymer samples under the attack of 10% magnesium sulfate and 10% sodium sulfate solution was investigated. 180 cycles of freezing and thawing were also tested. The experimentally obtained results investigate the durability of geopolymer mortar prepared with fly ash (class F) and alkali activator. Three different quarry dust wastes replaced the river sand aggregate: limestone, marble, and basalt powder as fine filler aggregate in three different replacement ratios of 25%, 50%, and 75% to produce ten series of geopolymer composites. The geopolymer samples' visual appearance, weight changes, UPV, and strength properties were studied for up to 12 months at different time intervals of exposure to sulfate solutions to investigate sulfate resistance. In addition, Scanning Electron Microscopy (SEM), EDS, and XRD were used to study the microstructure of the samples. It was beneficial to include quarry waste as a filler aggregate in durability and mechanical properties. The compact matrix was demonstrated by microstructural analysis of the manufactured specimens. The geopolymer mortars immersed in sodium sulfate showed less strength reduction and deterioration than magnesium sulfate, indicating that magnesium sulfate is more aggressive than sodium sulfate. Therefore, it is concluded that using waste dust interrogation with partial replacement of river sand with fly ash-based geopolymers has satisfactory results in terms of durability properties of freeze-thaw and sulfate resistance.

치과용 석고계 매몰재의 특성에 관한 연구 (STUDY ON THE PROPERTIES OF GYPSUM-BONDED DENTAL INVESTMENTS)

  • 김경선;우이형;최부병
    • 대한치과보철학회지
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    • 제28권1호
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    • pp.137-163
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    • 1990
  • The properties of a investment material can be described by the consistency at the slurry state, the setting time, the compressive strength and the thermal expansion during the casting. In this study the effect of the production parameters which are included the ratio of quartz and cristobalite, the content of binder, the water powder ratio and the content and concentration of additives on the Properties of the gypsum-bonded investments has been investigated with help of the consistency test, the vicat needle test, the compressive strength test, the thermal expansion test, x-ray diffraction and DTA thermal differential test. The experimental results showed that the constitution of a investment with W/P ratio of 0.34, 30% of gypsum, 0.8% aluminium sulfate, 2% magnesium sulfate, 0.6% sodium phosphate was adapted for the properties of the KDA Spec. No. 13 type I investment. The important experimental results are summarized as follows. 1. The consistency of the investment decreased with increasing amount of aluminium sulfate and decreasing amount of sodium phosphate. An addition of magnesium sulfate up to 2% an increase of the consistency was shown. But 3% magnesium sulfate in investment showed a decrease of the consistency. The consistency did not vary significantly with a variation of the content of gypsum and cristobalite and the W/P ratio. 2. Aluminium sulfate and the magnesium sulfate promoted the hardening and the aluminium phosphate delayed the hardening. The setting time increased with amount of gypsum. The effect of the matrix on the setting time was insignificant. With the W/P ratio of 0.34 the setting time was 14 min. 3. The compressive strength decreased with the amount of aluminium sulfate up to 0.25% and increased with the amount of aluminium sulfate greater than 3%. The compressive strength decreased as decreasing the amount of magnesium sulfate and gypsum and as increasing the W/P ratio. The effect of the refractory on the compressive strength was also not significant. With the W/P ratio of 0.34 the compressive strength was $34Kg/mm^2$. 4. The 1st thermal expansion was found at the temperature near and the steady state or the contraction stage was found at the temperature between $250^{\circ}C$ and $500^{\circ}C$. After this stage the 2nd thermal expansion took place at the temperature near $500^{\circ}C$. The amount of thermal expansion increased with decreasing the content of magnesium sulfate, aluminium sulfate and gypsum and the W/P ratio. And the amount of thermal expansion increased as the content of sodium phosphate and cristobalite. With the W/P ratio of 0.34 the amount of total expansion was 1.2%.

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응고제 종류가 감 분말 첨가 두부의 품질과 저장성에 미치는 영향 (Effect of Different Coagulants on Quality of Tofu Incorporated with Persimmon Fruit Powder)

  • 이윤래;정헌식;성종환;문광덕
    • 한국식품저장유통학회지
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    • 제18권5호
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    • pp.678-683
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    • 2011
  • 떫은감 분말 첨가 두부의 수율, 품질 및 저장성에 응고제의 종류(magnesium chloride, calcium chloride, calcium sulfate, glucono-${\delta}$-lactone)가 미치는 영향을 조사하였다. Glucono-${\delta}$-lactone으로 응고시킨 두부가 가장 높은 수율, hardness, chewness, crispness, overall acceptability 및 가장 낮은 L값, b값, pH, 침지저장액 탁도, 총균수를 보였다. Calcium sulfate와 calcium chloride으로 응고시킨 두부는 비교적 높은 L과 b값을 나타내었다. Magnesium chloride로 응고시킨 두부는 관능적 품질특성(firmness, taste, overall acceptability)이 glucono-${\delta}$-lactone 응고 두부와 상호 유의적인 차이가 없이 비교적 높게 평가되었다. 이러한 결과로써 glucono-${\delta}$-lactone과 magnesium chloride가 떫은감 분말 첨가 두부 제조에 적합한 응고제로 판단된다.

The impact of magnesium sulfate as adjuvant to intrathecal bupivacaine on intra-operative surgeon satisfaction and postoperative analgesia during laparoscopic gynecological surgery: randomized clinical study

  • Mohamed, Khaled Salah;Abd-Elshafy, Sayed Kaoud;El Saman, Ali Mahmoud
    • The Korean Journal of Pain
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    • 제30권3호
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    • pp.207-213
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    • 2017
  • Background: Surgeon satisfaction and patient analgesia during the procedure of laparoscopic surgery are important issues. The aim of this work was to study if an intrathecal (IT) Bupivacaine combined with Magnesium sulfate may or may not provide good surgeon satisfaction in addition to improvement of intraoperative and postoperative analgesia. Methods: Sixty female patients were enrolled in this prospective, randomized, double-blind controlled clinical trial study. All patients were operated for gynecological laparoscopic surgery under spinal anesthesia. Patients were divided into two groups (Bupivacaine and Magnesium). Group Bupivacaine (30 patients) received intrathecal Bupivacaine 0.5% only (15 mg), while 30 patients in group Magnesium received intrathecal Bupivacaine (15 mg) in addition to intrathecal Magnesium sulfate (50 mg). The sensory block level, the intensity of motor block, the surgeon satisfaction, the intraoperative visual analog scale (VAS) for pain assessment, the postoperative VAS, and side effects were recorded during the intraoperative period and within the first 24 hours after surgery in the post-anesthesia care unit. Results: Surgeon satisfaction, intraoperative shoulder pain, postoperative pain after 2 h, and perioperative analgesic consumption (ketorolac) were significant better in group Magnesium than in group Bupivacaine. (P < 0.05). The onset of motor and sensory blocks was significant longer in group Magnesium than the other one. The incidence of PONV, pruritus and urinary retention was insignificant statistically between both groups. Conclusions: Magnesium sulfate if used intrathecally as an adjuvant to Bupivacaine would provide a better surgeon satisfaction and would improve the analgesic effect of spinal anesthesia used for gynecological laparoscopic surgery.

치과용 석고계 매몰재의 특성에 관한 연구 (STUDY ON THE PROPERTIES OF GYPSUM-BONDED DENTAL INVESTMENTS)

  • 김경선;우이형;최부병
    • 대한치과보철학회지
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    • 제29권1호
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    • pp.139-165
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    • 1991
  • The properties of a investment material can be described by the consistency at the slurry state, the setting time, the compressive strength and the thermal expansion during the casting. In this study the effect of the production parameters which are included the ratio of quartz and cristobalite, the content of binder, the water powder ratio and the content and concentration of additives on the properties of the gypsum-bonded investments has been investigated with help of the consistency test, the vicat needle test, the compressive strength test, the thermal expansion test, x-ray diffraction and DTA thermal differential test. The experimental results showed that the constitution of a investment with W/P ratio of 0.34, 30% of gypsum, 0.8% aluminium sulfate, 2% magnesium sulfate, 0.6% sodium phosphate was adapted for the properties of the KDA Spec. No. 13 type I investment. The important experimental results are summarized as follows. 1. The consistency of the investment decreased with increasing amount of aluminium sulfate and decreasing amount of sodium phosphate. An addition of magnesium sulfate up to 2% an increase of the consistency was shown. But 3% magnesium sulfate in investment showed a decrease of consistency. The consistency did not vary significantly with a variation of the content of gypsum and cristobalite and the W/P ratio. 2. Aluminium sulfata and the magnesium sulfate promoted the hardening and the aluminium phoshpate delayed the hardening. The setting time increased with amount of gypsum. The effect of the matrix on the setting time was insignificant. With the W/P ratio of 0.34 the setting time was 14 min. 3. The compressive strength decreased with the amount of aluminium sulfate up to 0.25% and increased with the amount of aluminium sulfate greater than 3%. The compressive strength decreased as decreasing the amount of magnesium sulfate and gypsum and as increasing the W/P ratio. The effect fo the refractory on the compressive strength was also not significant. With the W/P ratio of 0.34 the compressive strength was $34Kg/mm^2$. 4. The 1st thermal expansion was found at the temperature near $250^{\circ}C$ and the steady state or the contraction stage was found at the temperature between $250^{\circ}C$ and $500^{\circ}C$. After this stage the 2nd thermal expansion took place at the temperature near $500^{\circ}C$. The amount of thermal expansion increased with decreasing the content of magnesium sulfate, aluminium sulfate and gypsum and the W/P ratio. And the amount of thermal expansion increased as the content of sodium phosphate ad cristobalite. With the W/P ratio of 0.34 the amount of total expansion was 1.2%.

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