• Journal of the Korea Concrete Institute
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• v.29 no.4
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• pp.407-413
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• 2017

The fundamental property of magnesia phosphate cement (MPC) for concrete repair material was investigated in this research. For mechanical properties, setting time, compressive strength and tensile/flexural bond strength were measured, and hydration products were detected by X-ray diffraction. The specimens were manufactured with dead burnt magnesia and potassium dihydrogen phosphate was admixed to activate the hydration of magnesia and a borax was used as a retarder. To observe the pore structure and ionic permeability of MPC mortar, mercury intrusion porosimetry was performed together with rapid chloride penetration test (RCPT). As a result, time to set of Fresh MPC mortar was in range of 16 to 21 min depend on the M/P ratio. Borax helped delaying setting time of MPC to 68 min. The compressive strength of MPC with M/P of 4 was sharply developed to 30 MPa within 12 hours. The compressive strength of MPC mortar was in range of 11.0 to 30.0 MPa depend on the M/P ratio at 12 hours of curing. Both tensile and flexural bond strength of MPC to old substrate (i.e. MPC; New substrate to OPC; Old substrate) were even higher than ordinary Portland cement mortar (i.e. [OPC; New substrate] to [OPC; Old substrate]) does, accounting 19 and 17 MPa, respectively. The total pore volume of MPC mortar was lower than that of OPC mortar. MPC mortar had the entrained air void rather than capillary pore. The RCPT showed that total charge passed of OPC mortar had more than that of MPC mortar, which can be explained by the pore volume and pore distribution.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.18 no.7
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• pp.357-364
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• 2017

In this paper, we investigated the influence of flow and compressive strength on the mixing ratio and water-to-binder (W/B) ratio of magnesia - potassium phosphate composites for controlling the quality of the Magnesia-Potassium Phosphate Composites(Magnesia-Potassium Phosphate Composites, MPPC) as a matrix material for biological panels. MPPC was produced at 7 W/B ratios (30, 35, 40, 45, 50, 55 and 60 vol.%) and 4 P:M ratios (1:0.5, 1:1.0, 1:2.0 and 1:3.0). The experiment results confirmed that the flow and compressive strength of MPPC depend strongly on both P:M and W/B ratios. The flow of MPPC showed that as P: M was increased, the mixing did not occur due to the shortage of the compounding amount for the reaction, because of the large density difference between P and M. The compressive strength of MPPC showed a tendency to decrease with increasing P:Mratio but there was a contradictory result with no proportional change according to W/B ratio. These results indicate that the optimum compounding ratio exists for MPPC according to W/B ratio. These results will be used as the basis data for quality control of the fluidity and compressive strength of matrix materials in terms of material in biological panel design.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2013.11a
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• pp.160-161
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• 2013

Recently, the enviroment problem is serious due to the global warming phenomenon because of the greenhouse gas exhaustion. In addition, the effort to reduce the problem in the situation where the severity of the destruction of environment because of the indiscriminate picking of the that is the raw material of the cement, Accordingly, in the interior of a country, the industrial site using the artificial stone instead of the natural stone is increased. Thus the cement reduction amount of use and substitute material research is the urgent actual condition with the gas emission, which here it is generated in conducting compression molding in the building stone manufacturing process performance degradation phenomenon and fire resistance, and problem of the durability. limestone and aggregate and exhaustion of resource are emphasized is continued. In this research, the fly ash and waste porcelain is applied to the magnesia phosphate composite (MPC) and the characteristic of the artificial stone according to it tries to be looked into.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2014.11a
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• pp.51-52
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• 2014

Recently, it is the global warming phenomenon because of the greenhouse gas exhaustion caused by and the environment problem is serious. And it is the situation where the problem of the exhaustion of resource because of the indiscriminate picking of the that is the raw material of the cement, limestone and natural aggregate are emphasized. In addition, thus the cement reduction amount of use and substitute material research is the urgent actual condition with the gas emission, which here it is generated in conducting compression molding in the building stone manufacturing process performance degradation phenomenon and fire resistance, and problem of the durability. Therefore, in this research, because of being the magnesia phosphate ceramics, the waste porcelain is applied and the anti-wearing character of the artificial stone according to it tries to be investigated.

• The Korean Journal of Ceramics
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• v.3 no.4
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• pp.269-273
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• 1997

Chemical composition of cement powder influences the setting time and early compressive strength development. The setting time increases as the amounts of zinc oxide and magnesium oxide are increased. For one day compressive strength development, a cement powder with a composition 90% ZnO, 8% MgO and 2% silica resulted in the highest strength (greater than 1, 090 kg/$\textrm{cm}^2$). Cement-forming liquids also need to be buffered, with both aluminum and zinc ions, for a good consistency and a higher strength of the zinc phosphate cement. These liquids control the setting reactions.

• Proceedings of the Korea Concrete Institute Conference
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• 2008.04a
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• pp.609-612
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• 2008

Ultra Super Early Strength Cement is a material that satisfies these requirements. early hydration heat however, is significant over regular concrete, thus discretion is advised for thermal cracks in accordance with heat generation when constructing a large-scale structures. In addition, the negative point that it is difficult to achieve required strength in a short period of time following rubbing process while retaining workability, the cement is being used conditionally for engineering material and Ultra Super Early Strength Cement for maintenance material for construction doesn't exist. Magnesia Phosphate Cement, which is currently under studies in overseas uses no extra admixture and has strong points of Ultra Super Early Strength as well as favorable construction-ability and adhesive stability to the prototype concrete. These factors stem recognition that it could be used as maintenance material for construction of diverse applicability. In order to provide necessary data to increase practicality of the magnesia phosphate cement for Ultra Super Early Strength Mortar, the study carried out simulate experiment on member of framework to review field applicability.

• Journal of the Korea institute for structural maintenance and inspection
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• v.17 no.5
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• pp.59-66
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• 2013

Because ordinary concrete cannot be hardened well under sub-zero temperatures, anti-freeze agents are typically added to prevent the frost damage and to ensure the proper hardening of concrete. With the advantage of a rapid exothermic reaction property, jet set concrete may be used as a cold weather concrete because it can reach the required strength before being damaged by cold weather. Recent studies are reported that magnesia-phosphate composites can be hardened very quickly and hydrated even in low temperature, which can be used as an alternative of severe cold weather concrete in arctic regions. This study developed the magnesia-phosphate composites that can be used in severe cold regions and suggested an appropriate mixture design from the experimental results.

• Magazine of the Korea Concrete Institute
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• v.27 no.6
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• pp.57-62
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• 2015

• Journal of the Korean Chemical Society
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• v.66 no.3
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• pp.202-208
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• 2022

In this study, we tried to obtain the optimal conditions to reduce odors generated from pig wastewater using magnesia (MgO) through in-situ test after producing a reactor for removing odors. For this purpose, the filling amount of magnesia, the injection amount of pig wastewater, the aeration method, the aeration amount and the aeration time were considered. The field experiment was conducted at Cheongwoon Livestock Farm, which has a pig wastewater reservoir. As the amount of magnesia added to the weight of wastewater (500 kg) increases, the amount of ammonia (NH₃) and hydrogen sulfide (H₂S) generated tended to gradually decrease. As a result of the test, ammonia and hydrogen sulfide in the pig wastewater decreased up to 65% and 77%, respectively, for 2 days aeration after 0.8% of magnesia was added to the reaction tank. The initial pH of the pig wastewater in the reactor was 8.2, and the pH was found to be 9.2 when magnesia was added up to 0.8%. In the light of this trend, it can be known that magnesia gradually increases the pH in the pig wastewater and makes it weakly alkaline. As the pH increases, part of the ammonia gas present in the pig wastewater vaporizes into the air and the remaining part is removed by precipitation after chemical bonding with dissolved magnesium ions and phosphate ions. In order to remove the odor of pig wastewater and turn it into compost, most of the existing livestock farms go through a six-month aeration process using microorganisms. In contrast, the current study proved the effect of removing odors from pig wastewater within 2 days through chemical reactions that do not affect microbial activity.

• Journal of the Korea Concrete Institute
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• v.29 no.3
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• pp.275-281
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• 2017

This study examined the effect of water-to-binder ratio (W/B) and phosphate-to-binder ratio (P/B) on the flow, setting time, compressive strength development, and pH variation of magnesium-potassium phosphate composites, MKPC mortars. Ten mortars mixtures were prepared with the W/B varying from 20% to 40% at each P/B of 0.3 or 0.5. The hydration products and microstructural pore distribution of the MKPC pastes were investigated using X-ray diffraction (XRD), scanning electron microscope (SEM) and mercury intrusion porosimetry (MIP). The initial flow and setting time of MKPC mortars tended to decrease with an increase of P/B, indicating that the final setting time was shortened by approximately 24% when P/B increased from 0.3 to 0.5. The slope of the early-strength development measured in the MKPC mortars was considerably higher than that of cement concrete specified in code provisions. For obtaining a relatively good 28-day strength (above 30 MPa) and a near neutral pH (below 9.0) in MKPC mortars, the P/B and W/B need to be selected as 0.5 and 30%, respectively. The strubite-K crystal increased with the increases of P/B and W/B, which leads to the decrease of the macro-capillary pores.