• 한국방사선학회논문지
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• 제13권4호
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• pp.645-652
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• 2019

폴리 인산염 모체에 이온 반경이 유사한 Sr과 Eu 치환에 적합한 형광체를 찾아 단일 희토류 이온이 첨가된 형광체를 합성하고 후처리를 통해 형광 영역이 변화를 연구하였다. 고상법을 이용하여 Eu 이온이 첨가된 $NaSr(PO_3)_3$형광체를 합성하고 탄소열환원법을 통하여 $NaSr(PO_3)_3:Eu^{2+}$ 형광체를 완성하였다. 두 형광체 모두 X선 회절 측정을 통하여 결정상을 확인하였다. $NaSr(PO_3)_3:Eu^{3+}$의 여기 및 방출 스펙트럼 모두 $Eu^{3+}$ 농도가 증가할수록 형광 강도가 증가하였고 농도소광을 확인하였다. 방출스펙트럼에서 $Eu^{3+}$ 농도가 높아질수록 $Eu^{3+}$ 주변 환경의 국부적 대칭성이 높아지는 것 알 수 있었다. $NaSr(PO_3)_3:Eu^{2+}$ 농도별 방출스펙트럼에서 $Eu^{2+}$ 이온 농도 증가에 따른 $Eu^{2+}$ 이온 사이의 임계 거리가 가장 가까운 $Eu^{2+}$ 사이의 에너지 전달에 의해 형광이 감소하는 농도소광의 메커니즘을 확인하였다. 단일 희토류 이온이 첨가된 형광체의 후처리를 통해 형광 영역 변화가 가능하며 형광체 내 $Eu^{3+}$ 주변 환경의 국부적 대칭성과 $Eu^{2+}$ 이온간 거리에 따른 에너지 전달 및 농도소광 메커니즘 연구를 통하여 형광 특성 응용에 적합하고 효율성이 높은 형광체 개발에 좋은 모체 결정으로 사용 될 것으로 기대된다.

• 새물리
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• 제68권11호
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• pp.1196-1202
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• 2018

고상 반응법을 이용하여 처음으로 $Li_2SrSiO_{4-{\alpha}}N_{\alpha}:Eu^{2+}$ 형광체를 제조하고, 제조된 시료들에 대한 결정성 및 광학적 특성을 비교, 분석하였다. 제조된 시료들은 모두 230~530 nm의 넓은 영역에서 효율적인 여기 특성을 보이고 있다. 본 연구에 사용된 시료들 모두 568 nm에서 최대 발광 세기를 보이는데 이는 현재 상용 중인 $YAG:Ce^{3+}$에 비하여 최대 발광 세기가 약 18 nm 장파장 영역으로 이동함을 의미한다. 따라서 450 nm의 빛을 발하는 청색 LED와 결합하면, $YAG:Ce^{3+}$를 사용하여 상용화된 기존의 백색광보다 보다 따듯한 느낌의 백색광원용 형광체로 활용될 수 있으리라 판단한다. 또한 질소의 원료 물질로 사용된 $Si_3N_4$의 분말크기가 마이크론인 경우에 광활성 이온인 $Eu^{2+}$가 첨가되지 않아도 모체발광이 일어난다는 것을 처음으로 알게 되었다.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2015년도 제49회 하계 정기학술대회 초록집
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• pp.222.1-222.1
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• 2015

Recently, graphene quantum dots (GQDs) have attracted great attention due to various properties including cost-effectiveness of synthesis, low toxicity, and high photostability. Nevertheless, the origins of photoluminescence (PL) from GQDs are unclear because of extrinsic states of the impurities, disorder structures, and oxygen-functional groups. Therefore, to utilize GQDs in various applications, their optical properties generated from the extrinsic states should be understood. In this work, we have focused on the effect of oxygen-functional groups in PL of the GQDs. The GQDs with nanoscale and single layer are synthesized by employing graphite nanoparticles (GNPs) with 4 nm. The series of GQDs with different amount of oxygen-functional groups were prepared by the chain of chemical oxidation and reduction process. The fabrication of a series of graphene oxide QDs (GOQDs) with different amounts of oxygen-contents is first reported by a direct oxidation route of GNPs. In addition, for preparing a series of reduced GOQDs (rGOQDs), we employed the conventional chemical reduction to GOQDs solution and controlled the amount of reduction agents. The GOQDs and rGOQDs showed irreversible PL properties even though both routes have similar amount of oxyen-functional groups. In the case of a series of GOQDs, the PL spectrum was clearly redshifted into blue and green-yellowish color. On the other hand, the PL spectrum of rGOQDs did not change significantly. By various optical measurement such as the PL excitation, UV-vis absorbance, and time-resolved PL, we could verify that their PL mechanisms of GOQDs and rGOQDs are closely associated with different atomic structures formed by chemical oxidation and reduction. Our study provides an important insights for understanding the optical properties of GQDs affected by oxygen-functional groups. [1]

• 한국재료학회지
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• 제19권9호
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• pp.510-515
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• 2009

The compound of 2,6-Bis[(9-phenylcarbazolyl)ethenyl]naphthalene (BPCEN-1), 2-[6-{1-Cyano-2-(9-phenylcarbazoly)vinyl}naphthyl]-3-(9-phenylcarbazolyl)acrylonitrile (BPCEN-2), 2,6-Bis[{4-(1-naphthy l)phenylamino} styrenyl] naphthalene (BNPASN-1), 2-[6-{1-Cyano-2-(naphthylphenylaminophenyl) vinyl}naphthyl]-3-(naphthylphenylaminophenyl)acrylonitrile (BNPASN-2) was analyzed electrochemically and spectroscopically and can be obtained by bonding phenylcarbazolyl, naphthylphenylaminophenyl and -CN ligands to 2,7-naphthalene. The electrochemical and spectroscopic study resulted in the P-type (BPCEN-1, BNPASN-1) being changed to N-type (BPCEN-2, BNPASN-2) according to -CN bonding despite having the same structure. The value of band gap(Eg) was revealed to be small as HOMO had shifted higher and LUMO lower. The Eg value for naphthylphenylaminophenyl ligand was reduced because it has a smaller HOMO/LUMO value than that of phenylcarbazolyl from a structural perspective. The electrochemical HOMO/LUMO values for BPCEN-1, BPCEN-2, BNPASN-1, BNPASN-2 were measured to be 5.55eV / 2.83eV, 5.73eV / 3.06eV, 5.48eV / 2.78eV, and 5.53eV / 2.98eV, respectively. By -CN ligand, the UV max, Eg and PL max were shifted to longer wavelength in their spectra and the luminescence band could be also confirmed to be broad in the photoluminescence (PL) spectrum.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2009년도 제38회 동계학술대회 초록집
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• pp.453-453
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• 2010

In this study, zinc germanate ($Zn_2GeO_4$) thin films has been synthesized by using radio frequency magnetron sputtering and the divalent manganese-activated luminescence was characterized. X-ray diffraction patterns of the as-deposited $Zn_2GeO_4$:Mn films showed only a broad feature, indicative of an amorphous structure. Scanning electron microscopy images revealed that the as-deposited $Zn_2GeO_4$:Mn has a smooth surface morphology. The $Zn_2GeO_4$:Mn films were found to be crystallized by annealing in air ambient at temperatures as low as $700^{\circ}C$. The annealed $Zn_2GeO_4$:Mn possessed a rhombohedral polycrystalline structure. The broad-band photoluminescent emission spectrum from 470 to 650nm was obtained at room temperature from the $Zn_2GeO_4$:Mn films. The emission peak was centered at around 535nm in the green range, which originates from the intrashell transition of manganese $3d^5$ electrons from $^4T_1$ excited-state level to the $^6A_1$ ground state. The PL emission spectrum had an asymmetric line shape, which results from the $^3d_5$ electron transitions of divalent manganese ions located at different sites of the zinc germanate host crystal lattice. Electroluminescent devices were fabricated using $Zn_2GeO_4$:Mn as an emission layer. The fabricated devices showed a green EL emission similar to the PL emission. The CIE chromaticity color coordinates of the EL emission were determined to be x=0.308 and y=0.657.

• Journal of Information Display
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• 제6권2호
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• pp.25-29
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• 2005

The luminescent properties of $Eu^{3+}$ and $Sm^{3+}$ doped potassium tungstate phosphor are investigated. The $K_{4-3x}(WO_4)_2:Eu^{3+}\;_x,Sm^{3+}\;_y$ phosphor is produced by firing the mixed precursors, followed by re-firing with a flux. The re-firing process results in the defect-free surface and uniform growth of the particles. The strong absorption in the region of ultra violet light is observed due to the 4f-4f electron transitions of the $Eu^{3+}$ and $Sm^{3+}$ ions. The doping concentration of europium into potassium tungstate is relatively high, compared to other host materials. It is revealed that the crystal structure is a monoclinic with space group, C2/c. This crystal structure facilitated the $Eu^{3+}$ ions to be located with the Eu-Eu distance larger than 5 ${\AA}$ so that concentration quenching does not occur even at high doping concentration. The excitation spectrum could be adjusted by the introduction of the samarium. A small amount of the $Sm^{3+}$ ions that acts as a sensitizer increases the energy absorption peak around 405 nm.

• Bulletin of the Korean Chemical Society
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• 제32권spc8호
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• pp.2988-2996
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• 2011

Shape memory polyurethane (SMPU), grafted with a fluorescent dye (Rhodamine, Mehylene violet, or Fluorescein) through an allophanate linking, was tested for the fluorescence and the shape recovery effect. The main chain of SMPU was composed of 4,4'-methylenebis(phenylisocyanate) (MDI), poly(tetramethyleneglycol) (PTMG), and 1,4-butanediol (BD), and a fluorescent dye was connected through a second MDI linked to the carbamate moiety of the main chain. Three series of SMPU, differing according to their dye content, were prepared to compare their shape recovery and fluorescence properties. In tensile mechanical property, maximum stress increased up to 350% compared to the linear SMPU, and strain remained above 2000%. Shape recovery went to as high as 97%, and remained almost same after repetitive shape recovery test cycles. Finally, the fluorescence emission of SMPU was demonstrated in the luminescence spectrum and fluorescent light emission pictures. In addition, the response of SMPU to external stimuli such as metal ions was investigated.

• Bulletin of the Korean Chemical Society
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• 제33권9호
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• pp.2910-2916
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• 2012

Cadmium sulphide (CdS) nanorods were prepared by a single precursor thermal decomposition (SPTD) method. The formation of CdS nanorods and their structure, morphology and elemental composition were studied by means of FT-IR, XRD, FE-SEM, HR-TEM and EDAX analysis. Photoluminescence (PL) and lifetime measurements were recorded to study the luminescence properties of the material. The PL spectrum of the CdS nanorods showed one broad peak and four shoulders and the cause for this emission was discussed. The PL emissions from the band edge and deep trap state of the CdS nanorods were studied by lifetime measurements. Further, the synthesized CdS nanorods showed an increase in efficiency of photocatalytic degradation of methylene blue (MB) and rhodamine B (RhB). The increase in the photocatalytic activity was attributed to the mixed phase of the CdS nanorods.

• 대한전기학회:학술대회논문집
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• 대한전기학회 1988년도 추계학술대회 논문집 학회본부
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• pp.168-171
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• 1988

The p-n homo junction diode of the III-V ternary alloy semiconductor $In_{1-x}Ga_xP$ : S grown by the temperature gradient solution (TGS) was fabricated by Zn-diffusion, and it's characteristics was investigated. The carrier concentration of $In_{1-x}Ga_xP$ doped with sulfur, 0.5 mol %, was $1{\times}10^{17}cm^{-3}$ and the mobility was varied with the composition. In the case that the diffusion time was constant as 30 minutes. The temperature dependence of diffusion coefficient was decreased from D= $4.2{\times}10^{-5}$ exp (-1.74/$k_{B}T$) to D= $2.5{\times}10^{-5}$ exp (-3.272/$k_{B}T$) with increasing of composition $\times$ from 0.43 to 0.98. The major peak of E.L spectrum was due to D-A pair recombination and the peak intensity was increased with the increasing of input current. And the E.L intensity was decreased with the increasing temperature, and shift to the long wavelength. The luminescence efficiencies measured at $5^{\circ}C$, atmosphere temperature, was decreased from $2.6{\times}10^{-4}$% to $9.49{\times}10^{-6}$ % with increasing of composition it from 0.39, direct transition region, to 0.98, indirect transition region.

• Transactions on Electrical and Electronic Materials
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• 제6권4호
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• pp.169-172
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• 2005

[ $Y_2O_3:Eu$ ] powder was synthesized using a solution-combustion method by dissolving $(CH_3CO_2)_3Y$ and $(CH_3CO_2)_3$ Eu in methyl-alcohol solution. Results from X-ray diffractometery (XRD), thermogravimetry (TG)-differential thermal analysis (DTA) show that $Y_2O_3:Eu$ crystallizes completely when the dry powder is sintered at $500^{\circ}C$. The investigated optical properties were the photoluminescence emission spectra, the excitation spectra and luminescence decay curve. Europium (Eu) concentration had no observable effect on the optical spectrum which depended on the emission intensity. The mean lifetime of synthesized phosphors was $2.3\~2.6 ms$.