• Title/Summary/Keyword: luminescence spectrum

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A Study on Phosphor Synthetic and Low Temperature Photoluminescence Spectrum (저온 photoluminescence 스펙트럼 및 형광체 합성에 관한 연구)

  • Kim, Soo-Yong
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.24 no.4
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    • pp.10-16
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    • 2010
  • In this paper, synthesis here Mn add to Ar injection the state and a vacuum an atomosphere $ZnGa_2O_4$ : Mn, ZnO and $Ga_2O_3$ power of 1 : 1 mole ratio mixture. Manufacture a close examination of oxygen a component variation luminescence a specific character reach an in fluence of $ZnGa_2O_4$ : Mn, luminescence spectrum observation also an explanation of Mn site symmetry and at luminescence spectrum reach an influence from low temperature photoluminescence spectrum.

A study on luminescence a specific character and ZnGa2O4:Mn phosphor synthetic (ZnGa2O4:Mn 형광체 합성 및 발광 특성에 관한 연구)

  • Kim, Soo Yong;Jee, Suk Kun
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2009.05a
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    • pp.703-708
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    • 2009
  • In this paper, synthesis here Mn add to Ar any a vacuum an atomosphere $ZnGa_2O_4$ : Mn, ZnO and $Ga_2O_3$ power of 1:1 mole ratio mixture. Manufacture a close examination of oxygen a component variation luminescence a specific character reach an in fluence of $ZnGa_2O_4$ : Mn, luminescence spectrum, the surface a picture and a component ratio measurement, also an explanation of Mn site symmetry and at luminescence spectrum reach an influence from low temperature photoluminescence spectrum.

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Morphological Change and Luminescence Properties of ZnO Crystals Synthesized by Thermal Evaporation of a Mixture of Zn and Cu Powder (Zn과 Cu 혼합 분말의 열 증발에 의하여 생성된 ZnO 결정의 형상 변화 및 발광 특성)

  • Lee, Geun-Hyoung
    • Korean Journal of Materials Research
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    • v.28 no.10
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    • pp.578-582
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    • 2018
  • ZnO crystals with different morphologies are synthesized through thermal evaporation of the mixture of Zn and Cu powder in air at atmospheric pressure. ZnO crystals with wire shape are synthesized when the process is performed at $1,000^{\circ}C$, while tetrapod-shaped ZnO crystals begin to form at $1,100^{\circ}C$. The wire-shaped ZnO crystals form even at $1,000^{\circ}C$, indicating that Cu acts as a reducing agent. As the temperature increases to $1,200^{\circ}C$, a large quantity of tetrapod-shaped ZnO crystals form and their size also increases. In addition to the tetrapods, rod-shaped ZnO crystals are observed. The atomic ratio of Zn and O in the ZnO crystals is approximately 1:1 with an increasing process temperature from $1,000^{\circ}C$ to $1,200^{\circ}C$. For the ZnO crystals synthesized at $1,000^{\circ}C$, no luminescence spectrum is observed. A weak visible luminescence is detected for the ZnO crystals prepared at $1,100^{\circ}C$. Ultraviolet and visible luminescence peaks with strong intensities are observed in the luminescence spectrum of the ZnO crystals formed at $1,200^{\circ}C$.

Luminescence and Crystal Field Parameters of the Na₃[Eu(ODA)₃]·7H₂O Complex in Single Crystalline State

  • 강준길;윤수경;손영구;김종구
    • Bulletin of the Korean Chemical Society
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    • v.18 no.8
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    • pp.861-864
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    • 1997
  • Luminescence spectrum of Na3[Eu(ODA)3]·7H2O (ODA≡oxydiacetato) was measured at various temperatures. The characteristic band splitting within 5D0→7FJ (J = 1, 2, 3 and 4) were phenomenologically simulated by using crystal field theory. The set of crystal field parameters reproduces the emission lines in a satisfactory manner with a rms deviation of 21.4 cm-1. It leads the reliable assignment of the luminescence bands and the energy level scheme of 7FJ (J = 1, 2, 3 and 4) multiplets.

Luminescence Properties of Ag Doped ZnO as Quantum Dot Materials for Improving Efficiency of Dye-sensitized Solar Cell (염료감응형 태양전지에서 효율 향상을 위한 Quantum Dot 재료로서 Ag가 도핑된 ZnO의 발광 특성 연구)

  • 김현주;이동윤;송재성
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.17 no.9
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    • pp.988-993
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    • 2004
  • Luminescence characteristics of Ag-doped ZnO as the quantum dot materials to increasing the efficiency on dye-sensitized solar cells (DSC) have been studied. Ag doped ZnO powder was produced by the self-sustaining combustion process using ultrasonic spraying heating method. Luminescence wavelength region of the ZnO by Ag doping was shifted to longer wavelength. Tn the case of the Ag doped ZnO powder, broad luminescence spectrum centered on 600nm was observed. On the other hand, we compared PL data of RTA treated ZnO:Ag film at various temperatures because the front electrode of solar cell was in need of the sintering process. In XRD and PL data for RTA treated film at the 500$^{\circ}C$ showed good property. And, it was found that the grain size wasn't growing but only optical property was changed. According to the result of XRD, PL, absorption, emission spectrum and DV-X${\alpha}$ used in theoretical calculation, it is considered to be possible to use Ag doped ZnO as quantum dot material for improving DSC efficiency.

Analysis for luminescence property about an increase quantity of silicate phosphor and reliability (Silicate 형광체 증가에 대한 발광 특성 및 신뢰성 분석)

  • Yoon, Yanggi;Jang, Joongsoon
    • Journal of Applied Reliability
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    • v.12 no.4
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    • pp.275-285
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    • 2012
  • This paper presents a changes of luminescence property for converted white LEDs with the commercially available silicate phosphor. If silicate phosphor's quantity increase step by step. luminescence property will be changing. we analyze luminescence property for these change and carry out the high temperature aging test for 7,000 hours, the high temperature and humidity aging test for 7,000 hours for reliability. LED degradation not only results in reduced light output but also in color changes. so we monitor correlated color temperature (CCT), chromaticity coordinates(x, y) and spectrum intensity. Those results suggest that humidity factor more bad effect in color changes than temperature factor and Lighting quality is related with quantity of phosphor.

Luminescence, Excitation and Far-infrared Spectroscopy of cis-$\alpha$-Dichlorotriethyleneteraminechromium(III) Chloride

  • 최종하
    • Bulletin of the Korean Chemical Society
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    • v.19 no.5
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    • pp.575-579
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    • 1998
  • The 77 K luminescence and excitation spectra, and 298 K infrared and absorption spectra of $cis-{\Alpha}-[Cr(trien)Cl_2]Cl{\cdot}H_2O$ (trien=triethylenetetramine) have been measured. Ligand field electronic transitions due to spin-allowed and spin-forbidden are assigned. The zero-phonon line in the excitation spectrum splits into two components by $198\; cm^{-1}$, and the large $^2E_g$ splitting can be reproduced by the modern ligand field theory. It is confirmed that nitrogen atoms of the trien ligand have a strong σ-donor character, but chloride ligand has weak σ- and π -donor properties toward chromium(III) ion.

Photophysical Properties of Chlorotriethylphosphinegold(I)

  • Kang, Jun-Gill;Jeong, Yong-Kwang;Oh, Sung-Il;Kim, Hyun-Jun;Park, Chang-Moon;Tiekink, Edward R.R.
    • Bulletin of the Korean Chemical Society
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    • v.31 no.8
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    • pp.2151-2157
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    • 2010
  • Spectroscopic and quantum mechanical studies of the Et3PAuCl complex were performed to characterize the effect of aurophilicity on the optical properties. When excited with UV light at low temperature, the crystalline complex produced a deep luminescence in both the blue (high-energy) and red (low-energy) regions of the spectrum. The intensity of the low-energy luminescence was markedly reduced in the powdered state and quenched in the solution state. Time-dependent density functional theory (TD-DFT) calculations on electronic structures of both the ground and excited states of aggregates $[Et_3PAuCl]_n$ (n = 1 - 3) indicated that the low-energy luminescence was attributable to Au-centered transitions, which are significantly affected by aurophilic interactions. By contrast, the high-energy luminescence appeared to be independent of the state of the complex and was strongly associated with the charge transfer from Cl to Au.

A Study on the Growth of ZnGa$_2$O$_4$ Thin Film Phosphors (ZnGa$_2$O$_4$ 박막형광체 성장에 관한 연구)

  • 정영호;김영진
    • Journal of the Korean Ceramic Society
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    • v.35 no.2
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    • pp.145-150
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    • 1998
  • ZnGa2O4 thin film phosphors were deposited on Si(100) (111) wafers by rf magnetron sputtering. The ef-fects of substrates and deposition parameters on the growing mechanisms were studied. As a results of the effect of substrate temperature tranistions of growth orientation and different growing behaviors were ob-served. Also polycrystalline ZnGa2O4 thin film could not be achieved without oxygen gas. PL spectrum of ZnGa2O4 thin films were analyzed and showed broad band luminescence spectrum.

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