• Title/Summary/Keyword: low-temperature recovery

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Measurement of Evaporation Rates for Lanthanum and Neodymium Chlorides

  • Kwon, S.W.;Lee, Y.S.;Jung, J.H.;Chang, J.H.;Kim, S.H.;Lee, S.J.
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2017.10a
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    • pp.74-74
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    • 2017
  • Electrorefining is a key step in pyroprocessing. The electrorefining process is generally composed of two recovery steps - the deposit of uranium onto a solid cathode and the recovery of the remaining uranium and TRU elements simultaneously by a liquid cadmium cathode. Uranium deposit recovered from the solid cathode is a dendritic powder. It is necessary to separate the adhered salt from the deposits prior to the consolidation of uranium deposit. The adhered salt is composed of lithium, potassium, uranium, and rare earth chlorides. Distillation process was employed for the cathode processing. One of the operation methods is distillation of the salt at low temperature ($900^{\circ}C$), and then melting of the deposit at high temperature to avoid a backward reaction. For the development of the salt distiller, the distillation behavior of the low vapor pressure chlorides should be studied. Rare earth chlorides in the adhered salt of uranium deposits have relatively low vapor pressures compared to the process salt (LiCl-KCl). In this study, the evaporation rates of the lanthanum and neodymium chlorides were measured for the salt separation from electrorefiner uranium deposits in the temperature range of $825{\sim}910^{\circ}C$. The evaporation rate of both chlorides increased with an increasing templerature. The evaporation rate of lanthanum chloride varied from 0.12 to $1.68g/cm^2/h$. Neodymium chloride was more volatile than lanthanum chloride. The evaporation rate of neodymium chloride varied from 0.20 to $4.55g/cm^2/h$. The evaporation rate of both chlorides are more than $1g/cm^2/h$ at $900^{\circ}C$. Even though the evaporation rates of both chlorides were less than that of the process salt, the contents of the lanthanide chlorides were small in the adhered salt. Therefore it can be concluded that $900^{\circ}C$ is suitable for the operation temperature of the salt distiller.

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Changes in Growth Characteristics of Waxy Corn 'Ilmichal' due to Low Temperature during the Seedling Stage (일미찰옥수수의 유묘기 저온에 따른 생육특성 변화)

  • Jeon, Seung Ho;Oh, Seung Ka;Kim, Han Yong;Na, Chae-In;Bae, Hui Su;Cho, Young Son
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.65 no.4
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    • pp.426-435
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    • 2020
  • To determine the damages to waxy corn caused by low temperature weather, we investigated the relationship between the temperature and duration of low temperature treatment and the changes in growth characteristics during the recovery period after the treatments in different growth periods. Growth inhibition started in the low temperature group treated at temperatures below 5℃ for three days. The inhibition ratio (IR) was more than 22% or more in all sample groups. As the treatment duration increased and the Temperature decreased, the growth was more greatly inhibited than that in the control. The IR was the highest at 27% or more in the 2nd leaf stage group treated at below 5℃ for 5 days. The IR was in the order of 2nd leaf stage > 1st leaf stage > coleoptile. The IR during recovery was the highest in the 2nd leaf stage group treated at -3℃ degree for 7 days, nd the values were 82% and 98% for NDVI and Fv/Fm, respectively. Especially, all groups treated at -3℃ showed either no changes or decreases in the growth characteristics. As a result, growth inhibition increased as the temperature decreased, and as the duration of the low temperature increased. The degree of damage was in the order of 2nd leaf stage > 1st leaf stage > coleoptile. All early seedlings stopped growing and withered when exposed to temperatures at or below -3℃ for 3 days or more.

Characteristics of Thermodynamic Performance of Organic Flash Cycle (OFC) (유기 플래쉬 사이클(OFC)의 열역학적 성능 특성)

  • Kim, Kyounghoon;Jung, Youngguan;Park, Sanghee
    • Transactions of the Korean hydrogen and new energy society
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    • v.24 no.1
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    • pp.91-97
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    • 2013
  • Recently a novel cycle named organic flash cycle (OFC) has been proposed which has improved potential for power generation from low-temperature heat sources. This study carries out thermodynamic performance analysis of OFC using various working fluids for recovery of low-grade heat sources in the form of sensible energy. Special attention is focused on the optimum flash temperature at which the exergy efficiency has the maximum value. Under the optimal conditions with respect to the flash temperature, the thermodynamic performances of important system variables including mass flow ratio, separation ratio, heat addition, specific volume flow rate at turbine exit, and exergy efficiency are thoroughly investigated. Results show that the exergy efficiency has a peak value with respect to the flash temperature and the optimum working fluid which shows the best exergy efficiency varies with the operating conditions.

Effects of Aromatics and T90 Temperature of Low Cetane Number Fuels on Exhaust Emissions in Low-Temperature Diesel Combustion (저온디젤연소에서 저세탄가 연료의 방향족 및 T90 온도가 배기가스에 미치는 영향)

  • Han, Man-Bae
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.34 no.12
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    • pp.1121-1126
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    • 2010
  • This study is to investigate the effects of aromatics and T90 for low cetane number (CN) fuels on combustion and exhaust emissions in low-temperature diesel combustion. We use a 1.9-L common rail direct injection diesel engine at 1500 rpm and 2.6 bar BMEP. Low temperature diesel combustion was achieved via a high external EGR rate and strategic injection control. The tested fuels four sets: the aromatic content was 20% (A20) or 45% (A45) and the T90 temperature was $270^{\circ}C$ (T270) or $340^{\circ}C$ (T340) with CN 30. Given the engine operating conditions, the T90 was the stronger factor on the ignition delay time, resulting in a longer ignition delay time for higher T90 fuels. All the fuels produced nearly zero PM because of the extension of the ignition delay time induced by the low cetane number. The aromatic content was the main factor that affected the NOx and the NOx increased with the aromatic content.

Optimization Study on the Performance Analysis of Organic Rankine Cycle for Characteristics of Low Temperature Heat Sources (저온열원의 특성에 따른 ORC 성능해석 최적화 연구)

  • Eom, Hong-Sun;Yoon, Cheon-Seog;Kim, Young-Min;Shin, Dong-Gil;Kim, Chang-Gi
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.24 no.1
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    • pp.51-60
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    • 2012
  • Optimization procedures of performance analysis for ORC(Organic Rankine Cycle) system are established to the characteristics of low temperature heat sources such as open-type and closed-type. Effective heat recovery and heat extraction related to maximum power of the cycle as well as heat quality and thermal efficiency must be considered in the case of the open-type low temperature heat source. On the other hand, in the case of the closed-type low temperature heat source, only thermal efficiency is important due to constant heat input. In this study, thermal efficiency and exergy efficiency representing a level of close to Carnot cycle are studied, as useful index for the optimization of the ORC system. To validate the results of cycle analysis, those are compared with appropriate experimental data of ORC system as a thermal efficiency point of view.

Study on the Rankine Cycle using Ammonia-Water Mixture as Working Fluid for Use of Low-Temperature Waste Heat (저온폐열 활용을 위한 암모니아-물 혼합물을 작업유체로 하는 랭킨사이클에 관한 연구)

  • Kim, Kyoung-Hoon;Kim, Se-Woong;Ko, Hyung-Jong
    • Transactions of the Korean hydrogen and new energy society
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    • v.21 no.6
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    • pp.570-579
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    • 2010
  • Since the temperature of waste heat source is relatively low, it is difficult to maintain high level of efficiency in power generation when the waste heat recovery is employed in the system. In an effort to improve the thermal efficiency and power output, use of ammonia-water mixture as a working fluid in the power cycle becomes a viable option. In this work, the performance of ammonia-water mixture based Rankine cycle is thoroughly investigated in order to maximize the power generation from the low temperature waste heat. In analyzing the power cycle, several key system parameters such as mass fraction of ammonia in the mixture and turbine inlet pressure are studied to examine their effects on the system performance. The results of the cycle analysis find a substantial increase both in power output and thermal efficiency if the fraction of ammonia increases in the working fluid.

Performance Design of Boiler for Waste Heat Recovery of Engine Coolant by Rankine Steam Cycle (엔진 냉각수 폐열 회수를 위한 랭킨 스팀 사이클용 보일러의 성능 설계)

  • Heo, Hyung-Seok;Bae, Suk-Jung;Hwang, Jae-Soon;Lee, Heon-Kyun;Lee, Dong-Hyuk;Park, Jeong-Sang;Lee, Hong-Yeol
    • Transactions of the Korean Society of Automotive Engineers
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    • v.19 no.5
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    • pp.58-66
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    • 2011
  • A 2-loop waste heat recovery system with Rankine steam cycles for the improvement of fuel efficiency of gasoline vehicles has been investigated. A high temperature loop(HT loop) is a system to recover the waste heat from the exhaust gas, a low temperature loop(LT loop) is for heat recovery from the engine coolant cold relatively. This paper has dealt with a layout of a LT loop system, the review of the working fluids, and the design of the cycle. The design point and the target heat recovery of the LT boiler, a core part of a LT loop, has been presented and analytically investigated. Considering the characteristics of the cycle, the basic concept of the LT boiler has been determined as a shell-and tube type counterflow heat exchanger, the performance characteristics for various design parameters were investigated.

The Development and Performance Evaluation of the Air-preheating Heat Exchanger for Ultra-high Temperature Applications (초고온융 공기예열식 열교환기의 개발 및 성능 평가)

  • 박용환
    • Journal of the Korean Society of Safety
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    • v.14 no.4
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    • pp.78-84
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    • 1999
  • A compact air-preheating type heat exchanger was developed and tested for the ultra-high temperature heat recovery applications. For the direct use of exhaust gases up to $1200^{\circ}C$, the heat exchanger adopted a ceramic core with high strength and low thermal expansion coefficient less than $1{\times}10^{-6}^{\circ}C^{-1}$. The ceramic core was fabricated by special extrusion and bonding techniques. To minimize thermal stresses in the core, spring-loaded sealing mechanism was designed and successfully installed. 1-pass air flow scheme was adopted for the compactness and cost-savings. The pressure test for the ceramic core showed no failure under 35 kPa and less than 3% leak under 7 kPa. Flue gas simulation system was developed to investigate the performance of the heat exchanger. The test results showed normal operations of the heat exchanger up to $1200^{\circ}C$ of exhaust gases and relatively high heat recovery efficiencies of 31~39% depending upon exhaust gas temperatures..

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Recovery of Radiation-Induced Damage in MOSFETs Using Low-Temperature Heat Treatment (저온 열처리를 통한 MOSFETs 소자의 방사선 손상 복구)

  • Hyo-Jun Park;Tae-Hyun Kil;Ju-Won Yeon;Moon-Kwon Lee;Eui-Cheol Yun;Jun-Young Park
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.37 no.5
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    • pp.507-511
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    • 2024
  • Various process modifications have been used to minimize SiO2 gate oxide aging in metal-oxide-semiconductor field-effect transistors (MOSFETs). In particular, post-metallization annealing (PMA) with a deuterium ambient can effectively eliminate both bulk traps and interface traps in the gate oxide. However, even with the use of PMA, it remains difficult to prevent high levels of radiation-induced gate oxide damage such as total ionizing dose (TID) during long-term missions. In this context, additional low-temperature heat treatment (LTHT) is proposed to recover from radiation-induced damage. Positive traps in the damaged gate oxide can be neutralized using LTHT, thereby prolonging device reliability in harsh radioactive environments.