• Macromolecular Research
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• v.17 no.5
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• pp.289-295
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• 2009

Low viscosity aromatic hyperbranched polyester epoxy resin (HTBE) was synthesized by the reaction between epichlorohydrin (ECH) and carboxyl-end hyperbranched polyester (HTB) which was prepared from inexpensive materials $A_2$ (1,4-butanediol glycol, BEG) and $B_3$ (trimellitic anhydride, TMA) by pseudo one-step method. The molar mass of the HTB was calculated from its acid value by "Recursive Probability Approach". The degree of branching (DB) of the HTB was characterized by model compounds and $^1H$ NMR-minus spectrum technology, and the DB of the HTB was about $0.47{\sim}0.63$. The viscosity and epoxy equivalent weight of the HTBE were $3,600{\sim}5,000\;cp$ and lower than 540 g/mol respectively. The reaction mechanism and structure of the $AB_2$ monomer, HTB and HTBE were investigated by MS, $^1H$ NMR and FTIR spectra technology. The molecular size of HTBE is under 8.65 nm and its shape is ellipsoid-like as determined by molecular simulation.

• Tribology and Lubricants
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• v.31 no.1
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• pp.28-34
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• 2015

This paper addresses the problems of using anti-freeze lubricants for different machines that must function at extremely low temperatures during winter operation in the Republic of Sakha (Yakutia). We discuss the possibility of obtaining anti-freeze base oils from Talakan crude oil, an area with major oil and gas deposits of the Republic of Sakha, and also provide the trade and technological classification of Talakan crude oil. We propose two different schemes for processing Talakan crude oil: the fuel scheme (obtaining light and heavy fractions as a fuel oil) and the base oil scheme (obtaining light fractions and base oils). We investigate the influence of pour point depressants on alkyl-methacrylate base on the low-temperature properties of the fractions obtained from Talakan crude oil and Korean base oils, and establish the optimal concentration of pour point depressants. We compare the properties of these fractions with the low-temperature properties of Korean base oils and find that the commercial oil "Ravenol 0W-40" provides optimistic results. We obtain oil with a pour point of minus $50^{\circ}C$ and a viscosity index greater than 100. The Design of Experiment was used to establish the optimum composition of the pour point depressants and the base oil S-8 to obtain lubricant oil with a kinematic viscosity of 17 cSt, viscosity index of 208, and a pour point of minus $64^{\circ}C$.

• Korea-Australia Rheology Journal
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• v.19 no.2
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• pp.75-80
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• 2007

The slotted plate technique has previously been shown to be a successful method for directly measuring the static yield stress of suspensions. In this study, we further establish the usefulness of the slotted plate device as a rheometer especially at low shear rates, taking advantage of the extremely low speeds of the slotted plate technique. Newtonian fluids, a shear thinning fluid, and yield stress fluids were tested using the slotted plate device and the results were compared with those from a commercial rheometer using different standard flow geometries. The relationship between the stress on the plate and the viscosity for the slotted plate device obtained by dimensional analysis (drag) predicts a linear relationship between the force at the plate and the plate speed, consistent with the experimental data. The slotted plate device can measure viscosities at very low shear rates. The apparent viscosity - shear-rate data obtained from the slotted plate device are complementary to those obtained using a commercial rheometer. That is : the slotted plate can measure viscosity in the shear rate range $10^{-7}<\dot{\gamma}<10^{-3}\;s^{-1}$, while the commercial rheometer measures viscosity at shear rates higher than $10^{-3}\;s^{-1}$.

• Journal of the Korean Electrochemical Society
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• v.13 no.3
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• pp.198-202
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• 2010

Lithium co-polyelectrolyte-ionic liquid systems, using poly (lithium 2-acrylamido-2-methyl propanesulfonate; PAMPSLi) and polyvinyl formamid (PVF) were prepared and their electrochemical and physical properties were measured. The conductivity of co-polymer systems, PAMPSLi/PVF/N, N-dimethyl-N-propyl-N-butylammonium tricyanomethanide (PAMPSLi/PVF/$N_{1134}$TCM) and PAMPSLi/PVF/N, N-dimethyl-N-propyl-N-butylammonium dicyanamide (PAMPSLi/PVF/$N_{1134}$DCA) exhibited low viscosity ($N_{1134}$TCM:$N_{1134}$DCA 28.6cP, 28.7cP) and higher conductivity ($2.48{\times}10^{-3}Scm^{-1}$, $2.2{\times}10^{-3}Scm^{-1}$) than homopolymer system. The ionic conductivity PAMPSLi/PVF/1-ethyl-3-methyl imidazolium dicyanamide (PAMPSLi/PVF/emImDCA) exhibited $1.54{\times}10^{-3}Scm^{-1}$ and low viscosity (emImDCA: 28.09cP). High flexibility of imidazolium cation and dissociation of lithium cation from the co-polymer chains were affected by high conductivity and low viscosity.

• Electrical & Electronic Materials
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• v.8 no.5
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• pp.587-593
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• 1995

Silicone oils used insulating substances exhibit the both of organic and inorganic properties, and it has many superior characteristics such as the high thermal resistance and low thermal oxidation level when compared to other insulation oils. In order to investigate the dielectric loss due to the increase of viscosity, silicone oils of viscosity 1, 2, 5[cSt] had been chosen as the specimen and experiment has been performed in the temperature range of -70[.deg. C] - 65[.deg. C] and frequency range of 30 - 1*10$\^$5/[Hz]. As a result, the linear decrease of loss at low frequency region in high temperature was due to the influence of applying frequency, whereas the increase of loss at high frequency region was contributed by electrode's resistance. And increasing viscosity, the activation energy increased from 3.77[kcal/mole] to 7.21[kcal/mole]. The dipole moment of specimen was become clear 1.48 - 2.26[debyel in high temperature region(5 - 65[.deg. C]) and 1.05 - 1.80[debye] in low temperature region (-70 - -25[.deg. C])respectively.

• Journal of the Korean Applied Science and Technology
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• v.35 no.3
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• pp.985-1001
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• 2018

In this study, we tried the various experiments using the emulsifier, electrolyte, stabilizer and gelling agent in order to improve a stability of low viscosity W/O emulsion. As a result, when we used polyglyceryl-4 diisostearate/polyhydroxystearate/sebacate as a main emulsifier, PEG-30 dipolyhydroxystearate and cetyl PEG/PPG-10/1 dimethicone as a co-emulsifier for stable emulsification system, 0.5 % sodium chloride as an electrolyte, 1 % distearyldimonium chloride as a stabilizer, 0.5 % glyceryl behenate/eicosadioate as an oil gelling agent, emulsion particle is the best. Also, we got the stable and low viscosity W/O emulsion maintained at a constant viscosity at 2,000 cps or less. In addition, we were able to examine the possibility of development of low viscosity fluids type sunscreens with excellent feeling and stability through the application of inorganic sunscreen agents.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.16 no.5
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• pp.452-458
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• 2004

The major cause of compressor failure is the decrease of oil viscosity due to floodback. In most previous researches on the compressor reliability, the relationship between oil circulation rate and performance or oil viscosity has been studied. Another research topic is flow visualization by using a sight glass on the bottom of a compressor sump area and accumulator. Both oil film thickness and oil level through the sight glass should be assessed for compressor reliability if the oil content of the mixture is small and low viscosity raise poor lubrication of pump bearing. In this study, the compressor reliability was assessed by measuring the viscosity of the mixture and calculating oil film thickness. The analysis of the relationship between bottom shell super heat and oil film thickness at heating operation was peformed. It is concluded that bottom shell superheat does not perfectly stand for the mixture's behavior for a low ambient heating operation and oil film thickness can give more detailed and direct criteria for compressor reliability.

• Korea-Australia Rheology Journal
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• v.16 no.1
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• pp.47-54
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• 2004

Low Reynolds number, dilute, and surfactant-free bubble suspensions are prepared by mechanical mixing after introducing carbon dioxide bubbles into a Newtonian liquid, polyol. The apparent shear viscosity is measured with a wide-gap parallel plate rheometer by imposing a simple shear flow of capillary numbers(Ca) of the order of $10^{-2}$ ~ $10^{-1}$ and for various gas volume fractions ($\phi$). Effects of capillary numbers and gas volume fractions on the viscosity of polyol foam are investigated. At high capillary number, viscosity of the suspension increases as the gas volume fraction increases, while at low capillary number, the viscosity decreases as the gas volume fraction increases. An empirical constitutive equation that is similar to the Frankel and Acrivos equation is proposed by fitting experimental data. A numerical simulation for deformation of a single bubble suspended in a Newtonian fluid is conducted by using a newly developed two-dimensional numerical code using a finite volume method (FVM). Although the bubble is treated by a circular cylinder in the two dimensional analysis, numerical results are in good agreement with experimental results.

• Tribology and Lubricants
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• v.3 no.2
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• pp.34-43
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• 1987

The effect of dilution solvent ratio, and the mixing ratio of MEK and toluene on the solvent dewaxing process has been studied. The results of this study are Summarized as follows; 1. The best mixing ratio of solvent of MEK process and Toluene when in case of light and medium Waxy oils, which has low viscosity was 48: 52, and when in case of heavy waxy oil, which has high viscosity was 45: 55. 2. The best dilution solvent ratio when in case of low viscosity oils. was 1:2.8 against waxy oils after annexing 5 times divided as well as, when incase of high viscosity oil was 1:3.5 after annexing 2 times divided. 3. The chilling temperature was -26$\circ$C and the reguired dewaxing time depends on the viscosity of waxy oils.

• Journal of Adhesion and Interface
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• v.10 no.4
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• pp.174-181
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• 2009

The viscosity for hi-solid pressure sensitive adhesive to improve water soluble low viscosity pressure sensitive adhesive polymerized using seeded polymerization. While seed binder polymerizing it produces an optimum polymerization condition, and acrylic acid and seed binder concentration changed were measurement of viscosity variation and adhesive power at the substrate (SUS420J) as flowing results. In adhesive polymerization, seed binder concentration 7 wt%/monomer was recovered 60% of solid content, 2,100 cps of low viscosity and clear adhesive film. When acrylic acid content was 4 wt%/monomer, it was turned excellent adhesive power and holding power.