• 제목/요약/키워드: low thermal expansion

검색결과 427건 처리시간 0.023초

고출력 레이저를 이용한 세라믹 재료의 용접 실험 (Experiments on Welding of Ceramics by Use of High Power Laser)

  • 변철웅
    • Journal of Welding and Joining
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    • 제12권2호
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    • pp.39-48
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    • 1994
  • In comparison to the conventional brazing, laser welding of ceramics has advantages of direct bonding without filler material, which causes the thermal stress due to the differences of thermal expansion coefficients. In pulse-mode, laser welding of dispersion ceramic having high thermal resistance is possible at relatively low preheating temperature of $1300^{\circ}C$ In CW-mode, alumina can be welded at high preheating temperature $1500^{\circ}C$ under the condition of low feed rate of 500 mm/min, respectively. Further studies on developing mechanism of pores in the bead during laser welding of ceramics is required.

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Fe-29%Ni-17%Co 저열팽창 합금의 피로 특성에 미치는 알파상의 영향 (Effects of Alpha Phase on the Fatigue Properties of Fe-29%Ni-17%Co Low Thermal Expansion Alloy)

  • 김민종;권진한;조규상;이기안
    • 한국재료학회지
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    • 제24권9호
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    • pp.481-487
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    • 2014
  • The effect of alpha phase on the fatigue properties of Fe-29%Ni-17%Co low thermal expansion alloy was investigated. Two kinds of alloys (Base alloy and Alpha alloy) were prepared by controlling the minimal alloy composition. Microstructure observation, tensile, high-cycle fatigue, and low-cycle fatigue results were measured in this study. The Base alloy microstructure showed typical austenite ${\gamma}$ phase. Alpha alloy represented the dispersed phase in the austenite ${\gamma}$ matrix. As a result of tensile testing, Alpha alloy was found to have higher strengths (Y.S. & T.S.) and lower elongation compared to those of the Base alloy. High cycle fatigue results showed that Alpha alloy had a higher fatigue limit (360MPa) than that (330MPa) of the Base alloy. The Alpha alloy exhibited the superior high cycle fatigue property in all of the fatigue stress conditions. SEM fractography results showed that the alpha phase could act to effectively retard both fatigue crack initiation and crack propagation. In the case of low-cycle fatigue, the Base alloy had longer fatigue life in the high plastic strain amplitude region and the Alpha alloy showed better fatigue property only in the low plastic strain amplitude region. The fatigue deformation behavior of the Fe-29%Ni-17%Co alloy was also discussed as related with its microstructure.

주조용 알루미늄합금의 $Al_{2}O_{3}-40%TiO_{2}$ 용사층에 대한 마멸특성 평가 (Evaluation of wear chracteristics for $Al_{2}O_{3}-40%TiO_{2}$ sprayed on casting aluminum alloy)

  • 채영훈;김석삼
    • 한국윤활학회:학술대회논문집
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    • 한국윤활학회 1997년도 제26회 추계학술대회
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    • pp.183-190
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    • 1997
  • The wear behaviors of $Al_2O_3-40%TiO_2$ deposited on casting aluminum alloy(ASTM A356) by plasma spray against SiC ball have been investigated experimentally. Friction and wear tests are carried out at room temperature. The friction coefficient of $Al_2O_3-40%TiO_2$ coating is lower than that of pure $Al_2O_3$ coating(APS). It is found that low friction correspond to low wear and high friction to high wear in the experimental result. The thickness of $Al_2O_3-40%TiO_2$ coatings indicated the existence of the optimal coating thickness. It is found that a voids and porosities of coating surface result in the crack generated. As the tensile stresses in coating increased with the increased friction coefficient. The columnar grain of coating will be fractured to achieve the critical stress. It is found that the cohesive of splats and the porosity of surface play a role in wear characteristics. It is suggested that the mismatch of thermal expansion of substrate and coating play an important role in wear performance. Tensile and compressire under thermo-mechanical stress may be occurred by the mismatch between thermal expansion of substrate and coating. This crack propagation above interface is observed in SEM.

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Permanent disposal of Cs ions in the form of dense pollucite ceramics having low thermal expansion coefficient

  • Omerasevic, Mia;Lukic, Miodrag;Savic-Bisercic, Marjetka;Savic, Andrija;Matovic, Ljiljana;Bascarevic, Zvezdana;Bucevac, Dusan
    • Nuclear Engineering and Technology
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    • 제52권1호
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    • pp.115-122
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    • 2020
  • A promising method for removal of Cs ions from water and their incorporation into stable crystal structure ready for safe and permanent disposal was described. Cs-exchanged X zeolite was hot-pressed at temperature ranging from 800 to 950 ℃ to fabricate dense pollucite ceramics. It was found that the application of external pressure reduced the pollucite formation temperature. The effect of sintering temperature on density, phase composition and mechanical properties was investigated. The highest density of 92.5 %TD and the highest compressive strength of 79 MPa were measured in pollucite hot-pressed at 950 ℃ for 3 h. Heterogeneity of samples obtained at 950 ℃ was determined using scanning electron microscopy. The pollucite hot-pressed at 950 ℃ had low linear thermal expansion coefficient of ~4.67 × 10-6 K-1 in the temperature range from 100 to 1000 ℃.

PbO-B$_2$O$_3$-V$_2$O$_5$계 저융점유리의 열처리에의한 결정화에 따른 기계적 성질 (Mechanical Properties of the System PbO-B$_2$O$_3$-V$_2$O $_5$Low Melting Glass during Crystallization by Heat-treatment)

  • 정창주
    • 한국세라믹학회지
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    • 제11권3호
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    • pp.19-26
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    • 1974
  • Mechanical properties of the system PbO-B2O3-V2O5 low melting glass during crystallization by heat-treatment were investigated. Wettability of the system PbO-B2O3-V2O5 was excellent and appropriate for commercial sealing as a low melting solder glass. Crystals, during heat-treated at 30$0^{\circ}C$ of the system PbO-B2O3-V2O5 were $\beta$-4PbO.B2O3, 5PbO.4B2O3, and Pb2V2O7 mainly. The percent of crystallinity was 82$\pm$5%. Mechanical properties of the system PbO-B2O3-V2O5 were influenced not only by the differences of density and coefficient of thermal expansion and the stress induced from the difference in the density and coefficient of thermal expansion between glass phase and crystals but also crystallization conditions.

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Aluminium Titanate Sintering Study Aimed at Rational Design of Microstructure for Optimal Thermal Shock Characteristics

  • Alecu, Ioan D.;Stead, Rodney J.
    • The Korean Journal of Ceramics
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    • 제5권1호
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    • pp.78-81
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    • 1999
  • Aluminium titanate is highly anisotropic in thermal expansion. As a result, thermal stresses build up in the material and intergranular cracks can develop. Both the outstanding thermal shock resistance and the low mechanical strength of aluminium titanate ceramics are a result of intergranular microcracking. The authors have previously identified a possibility of remarkably increasing fracture toughness of aluminium titanate without excessive penalty on strength. The paper shows that sintered density and porosity measurements can be used for optimizing the sintering and microstructure of aluminium titanate for an ideal balance between toughness and strength and, hence, the best thermal shock resistance.

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Development of 2-inch Plastic Film STN LCD

  • Park, Sung-Kyu;Han, Jeong-In;Kim, Won-Keun;Kwak, Min-Gi
    • Journal of Information Display
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    • 제1권1호
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    • pp.14-19
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    • 2000
  • Due to distinct properties of plastic substrates such as poor thermal resistance, non-rigidness and high thermal expansion, it is difficult to fabricate plastic film LCDs by conventional LCD processes. Poor thermal resistance and high thermal expansion of substrates induced deformation of substrates surface, mismatch of thermal expansion between ITO electrodes and substrates resulted in defects in the ITO electrodes during the high temperature process. Defects of ITO electrodes and non-uniform cell gap caused by non-rigid and flexible properties were also observed in the pressuring process. Based on in these observations, we used a newly developed material and fabrication process to prevent deformation of substrates, defects of electrodes and to maintain uniform cell gap. The maximum temperature of the process is limited up to $110^{\circ}C$ and pressure loaded during the process is five times less than conventional one. With these invented processes and materials, we obtained highly reliable Plastic Film STN LCDs whose electro-optical characteristics are better than or equivalent to those of typical glass LCDs.

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선팽창 온도특성에 의한 저밀도 폴리에틸렌의 유리 천이온도에 대한 고찰 (Investigation on glass transition temperature of low density polyethylene by the characteristics of temperature dependent linear expansion)

  • 김봉흡;강도열;김재환
    • 전기의세계
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    • 제30권7호
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    • pp.441-447
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    • 1981
  • As a preceeding work for the study on dielectric characterstics of a kind of low density polyethylene introduced morphological change by mechanical method, glass transition temperature which is regarded as a macroscopic aspect for relaxation of molecular chain segments has been observed by means of temperature dependent dilatometric measurement. The origina specimen clearly shows two knees which correspond to two peaks (.gamma. and .betha. peak) in the intenal friction measurement, suggesting the existence of separated glass transition temperatures at 150.deg.k and 260.deg.k respectively. On the specimen irradiated to 100 Mrad both glass transition temperatures tend to shift towards high temperature sides because of crosslinking by irradiation. furthemore an evidence can be seen that radiation effect, even in amorphous phase, is also slelctive depending on slight morphological differences. The specimen extended to four times in length shows a peculiar nature such as negative linear thermal expansion coefficient increasing with temperature between 220.deg.k and ambient temperature and that this fact is interpreted by considering that c axis of the lattice aligns along the extended direction by drawing, further c axis inherently possesses the characteristics of negative linear thermal expansion coefficient. For the observations that the relatively small positive linear expansion on the specimen extended to ca. two times as well as the part below 220.deg.k of the specimen extended to four times, it is considered for the reason of the facts that the incompletely oriented region indicated as the middle part of Peterlin's model tends to restore partially to orginal arrangement-a kind of phase transition-as increasing with temperature.

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고온 (750 ~ 850℃) SOFC용 밀봉재의 특성에 미치는 고열팽창계수를 갖는 필러의 영향 (The Effects of a Filler with a High Coefficient of Thermal Expansion on a Sealant for High-Temperature (750 ~ 850℃) SOFCs)

  • 김빛남;이미재;황종희;임태영;김진호;황해진;김일원;정운진
    • 한국세라믹학회지
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    • 제50권6호
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    • pp.470-475
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    • 2013
  • In this study, we report that effects of a filler with a high coefficient of thermal expansion on a sealant for high-temperature ($750{\sim}850^{\circ}C$) SOFC. We designed a $SiO_2-BaO-ZnO-B_2O_3-Al_2O_3$ glass system with a softening temperature higher than $750^{\circ}C$. The properties of the glass system show not only low volumetric shrinking but also low swelling. The glass system did not create a crystal phase during along-term heat treatment. We fabricated a seal gasket with 0, 10, 15, and 20 wt% cristobalite added as filler materials with glass powder. The coefficient of thermal expansion of the seal gasket increased according to cristobalite content. During along-term heat treatment, the leak rate decreased by about 5% after a heat treatment in an oxidizing atmosphere at $750^{\circ}C$ for 2000 h, also decreasing by about 6% after a heat treatment in a reducing atmosphere at $750^{\circ}C$ for 1000 h.

과급에 의한 흡입공기 보상 시 저속 디젤-아트킨슨사이클에서 엔진성능에 대한 연구 (A Study on Engine Performance at the Intake Air Compensation by Supercharging in the Low Speed Diesel-Atkinson Cycle)

  • 장태익
    • Journal of Advanced Marine Engineering and Technology
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    • 제35권8호
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    • pp.1009-1015
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    • 2011
  • 본 연구에서는 고팽창사이클의 경우 가변밸브시스템을 구성하여 흡기밸브 닫힘시기를 늦추는 방식으로 실현하였고, 저압축에 따른 흡입공기의 감소는 과급압력으로 해결하였다. 이와 같이 디젤기관에 아트킨슨사이클을 실현하여 엔진의 열효율향상 가능성을 알아보았다. 그 결과 흡기밸브 닫힘시기 ABDC $40^{\circ}$ 부터 ABDC $80^{\circ}$ 까지 전 영역에 걸쳐 열효율 및 출력의 향상이 있었다. 다만, 흡기밸브 닫힘시기가 ABDC $70^{\circ}$이후로는 열효율 증가 폭이 둔화되는 경향을 보였다. 위와 같은 연구결과 저속 디젤-아트킨슨사이클화의 최적 연소조건은 흡기밸브 닫힘시기가 ABDC $70^{\circ}$전후로 보이며, 고부하영역이 저부하영역보다 더 효과적으로 나타났고, 중부하영역에서 기관운전은 안정적이었다. 이때 정미열효율은 통상의 디젤기관보다 평균 약 12.5% 높게 나타났다.