• Title/Summary/Keyword: low temperature reduction

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Effects of Oxygen Enrichment on the Structure of Premixed Methane/Fluorinated Compound Flames (메탄-불소계 화합물의 예혼합화염 구조에서 산소 부화의 효과)

  • Lee, Ki-Yong
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.35 no.8
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    • pp.839-845
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    • 2011
  • We performed numerical simulations of freely propagating premixed flames at atmospheric pressure to investigate the influence of trifluoromethane on $CH_4/O_2/N_2$ flames under oxygen enrichment. Trifluoromethane significantly contributed toward a reduction in flame speed, the magnitude of which was larger in terms of the physical effect than the chemical effect. More trifluoromethane could be added and consumed on oxygen-enriched $CH_4/O_2/N_2$ flames. $CHF_3$ was decomposed primarily via $CF_3{\rightarrow}CF_2{\rightarrow}CF{\rightarrow}CF:O{\rightarrow}CO$ and $CHF_3+M{\rightarrow}CF_2+HF+M$ played an important role in oxygen-enhanced flames. When an inhibitor was added to oxygen-enriched flames, the position of the maximum concentration of active radicals was shifted to a relatively low temperature range, and the net rate of OH became higher than that of H.

Analysis for the Economic efficiency of District Heating and Gas Engine Co-generation System comparing with Central Heating System (중앙난방방식을 지역난방.소형열병합난방방식으로 전환시의 경제성 비교 분석)

  • Kim, Kyu-Saeng;Lee, Sang-Hyeok;Hong, Kyung-Pyo;Won, Young-Jae
    • Proceedings of the SAREK Conference
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    • 2007.11a
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    • pp.459-465
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    • 2007
  • This study was conducted to calculate the LCC of a apartment complex with a type of heating system, district heating and cogeneration system. For the purpose of analyzing LCC according to size of apartment complex, 500, 1,500 and 4,000 houses of model apartment selected. This research performs design of heating system and the life cycle cost analysis including an initial cost, energy cost, maintenance and operation cost, replacement cost and renovation cost during the project period(15years). According to the calculated results, 1) Initial cost of cogeneration system with 500, 1500 and 4000 houses is higher than district heating system each of 20%, 13%, 12%. 2) In case of cogeneration system, the payback period by electric generation is 5.21, 4.92 and 4.47 years and saving cost was calculated 29 billion won, 94 billion won and 262 billion won after payback period. 3) Cogeneration system LCC was 1.12, 1.07 and 1.06 times larger than district system with the size of apartment complex. According to the case of this study district heating system is more efficient than cogeneration system in terms of the reduction of LCC. 4) Gas Engine Co-generation System is more efficient than other systems because it can collect progressive part from electric charge progressive stage system. However, the efficiency is decreasing because of raising of fuel bills(LNG) and lowering of power rate for house use. Especially the engine is foreign-made so the cost of maintenance and repair is high and the technical expert is short. 5) District heating is also affected by fuel bills so we should improve energy efficiency through recovering of waste heat(incineration heat, etc.). Also, we should supply district cooling on the pattern of heat using of let the temperature high in winter and low in summer.

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Design and Performance of a Catadioptric Omnidirectional Zoom Optical System Using a Hybrid Lens for Visible Light (가시광에서 하이브리드 렌즈를 사용한 반사굴절식 전방위 줌 광학계의 설계 및 성능평가)

  • Park, Hyun Sik;Jo, Jae Heung
    • Korean Journal of Optics and Photonics
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    • v.31 no.2
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    • pp.96-104
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    • 2020
  • A catadioptric omnidirectional zoom optical system using a hybrid lens (COZOSH) that performs simultaneously two functions of a lens and a mirror was designed at the visible wavelength range for daytime unmanned surveillance, and its performance was analyzed. The hybrid lens has lots of advantages in terms of fabrication and assembly of a COZOSH, because of the obviation of a lens boring process and reduction of the number of optical components. Additionally, we designed the COZOSH to expand the compressed inner-image region of a donut image at low spatial frequencies. As a result, the optimized design performance of the optical system that satisfies all initial design specifications was obtained from calculation of the modulation transfer function, spot diagram, and tolerance analysis. We confirmed that the COZOSH is a passively athermalized optical system under conditions of temperature variation from -30℃ to 50℃, by using athermalization analysis during zooming.

Analysis of the Economic Efficiency of the District Heating and Gas Engine Co-Generation System Compared with the Central Heating System (중앙난방방식을 지역난방과 소형열병합난방 방식으로 전환 시 경제성 비교 분석)

  • Kim, Kyu Saeng
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.27 no.10
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    • pp.544-551
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    • 2015
  • This study was conducted to determine the LCC of apartment complexes with district heating and a cogeneration system. For the purpose of analyzing LCC according to the size of the apartment complex, 500, 1,500, and 4,000-unit model apartments were selected. Analysis was performed on the design of the heating system and the life cycle cost including total construction cost, maintenance and operation cost for the duration of the project period (15 years). According to the calculated results, 1) The initial cost of the cogeneration system for 500, 1,500, and 4,000-unit apartments is higher than that of the district heating system by 20%, 13%, and 12%, respectively. 2) In the case of the cogeneration system, the payback period by electric generation was found to be 5.21, 4.92 and 4.47 years, and saving cost was calculated to be 29 billion won, 94 billion won and 262 billion won after the payback period for 500, 1,500, and 4,000-unit apartments, respectively. 3) The LCC values of the cogeneration system were 1.12, 1.07 and 1.06 times larger than those of the district system according to the size of the apartment complex. In this study, the district heating system was found to be more efficient than the cogeneration system in terms of LCC reduction. 4) District heating is affected by fuel bills, so energy efficiency should be improved through recovering waste heat (incineration heat, etc.). Also, district cooling should be provided according to heat use to keep the temperature high in winter and low in summer.

Nanostructured Metal Organic Framework Modified Glassy Carbon Electrode as a High Efficient Non-Enzymatic Amperometric Sensor for Electrochemical Detection of H2O2

  • Naseri, Maryam;Fotouhi, Lida;Ehsani, Ali
    • Journal of Electrochemical Science and Technology
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    • v.9 no.1
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    • pp.28-36
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    • 2018
  • Metal-organic frameworks have recently been considered very promising modifiers in electrochemical analysis due to their unique characteristics among which tunable pore sizes, crystalline ordered structures, large surface areas and chemical tenability are worth noting. In the present research, $Cu(btec)_{0.5}DMF$ was electrodeposited on the surface of glassy carbon electrode at room temperature under cathodic potential and was initially used as the active materials for the detection of $H_2O_2$. The cyclic voltammogram of $Cu(btec)_{0.5}DMF$ modified GC electrode shows distinct redox peaks potentials at +0.002 and +0.212 V in 0.1 M phosphate buffer solution (pH 6.5) corresponding to $Cu^{(II)}/Cu^{(I)}$ in $Cu(btec)_{0.5}DMF$. Acting as the electrode materials of a non-enzymatic $H_2O_2$ biosensor, the $Cu(btec)_{0.5}DMF$ brings about a promising electrocatalytic performance. The high electrocatalytic activity of the $Cu(btec)_{0.5}DMF$ modified GC electrode is demonstrated by the amperometric response towards $H_2O_2$ reduction with a wide linear range from $5{\mu}M$ to $8000{\mu}M$, a low detection limit of $0.865{\mu}M$, good stability and high selectivity at an applied potential of -0.2 V, which was higher than some $H_2O_2$ biosensors.

A brief review of the bilayer electrolyte strategy to achieve high performance solid oxide fuel cells (고성능 고체산화물 연료전지를 위한 이중층 전해질 전략)

  • Park, Jeong Hwa;Kim, Doyeub;Kim, Kyeong Joon;Bae, Kyung Taek;Lee, Kang Taek
    • Ceramist
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    • v.23 no.2
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    • pp.184-199
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    • 2020
  • The solid oxide fuel cells (SOFCs) are the one of the most promising energy conversion devices which can directly convert chemical energy into electric power with high efficiency and low emission. The lowering operating temperature below 800 ℃ has been considered as the mostly considerable research and development for commercialization. The major issue is to maintain reasonably high performance of SOFCs at reduced temperatures due to increment of polarization resistance of electrodes and electrolyte. Thus, the alternative materials with high catalytic activities and fast oxygen ion conductivity are required. For recent advances in electrolyte materials and technology, newly designed, highly conductive electrolyte materials and structural engineering of them provide a new path for further reduction in ohmic polarization resistance from electrolytes. Here, a powerful strategy of the bilayer concept with various oxide electrolytes of SOFCs are briefly reviewed. These recent developments also highlight the need for electrolytes with greater conductivity to achieve a high performance, thus providing a useful guidance for the rational design of cell structures for SOFCs. Moreover, cell design, materials compatibility, processing methods, are discussed, along with their role in determining cell performance. Results from state-of-the-art SOFCs are presented, and future prospects are discussed.

FLIP CHIP ON ORGANIC BOARD TECHNOLOGY USING MODIFIED ANISOTROPIC CONDUCTIVE FILMS AND ELECTROLESS NICKEL/GOLD BUMP

  • Yim, Myung-Jin;Jeon, Young-Doo;Paik, Kyung-Wook
    • Journal of the Microelectronics and Packaging Society
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    • v.6 no.2
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    • pp.13-21
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    • 1999
  • Flip chip assembly directly on organic boards offers miniaturization of package size as well as reduction in interconnection distances resulting in a high performance and cost-competitive Packaging method. This paper describes the investigation of alternative low cost flip-chip mounting processes using electroless Ni/Au bump and anisotropic conductive adhesives/films as an interconnection material on organic boards such as FR-4. As bumps for flip chip, electroless Ni/Au plating was performed and characterized in mechanical and metallurgical point of view. Effect of annealing on Ni bump characteristics informed that the formation of crystalline nickel with $Ni_3$P precipitation above $300^{\circ}C$ causes an increase of hardness and an increase of the intrinsic stress resulting in a reliability limitation. As an interconnection material, modified ACFs composed of nickel conductive fillers for electrical conductor and non-conductive inorganic fillers for modification of film properties such as coefficient of thermal expansion(CTE) and tensile strength were formulated for improved electrical and mechanical properties of ACF interconnection. The thermal fatigue life of ACA/F flip chip on organic board limited by the thermal expansion mismatch between the chip and the board could be increased by a modified ACA/F. Three ACF materials with different CTE values were prepared and bonded between Si chip and FR-4 board for the thermal strain measurement using moire interferometry. The thermal strain of ACF interconnection layer induced by temperature excursion of $80^{\circ}C$ was decreased with decreasing CTEs of ACF materials.

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Quality Characteristics of Black Raspberry Wine added with wild grape by Yeast Strains and Fermentation Conditions (효모 종류와 발효조건에 따른 머루 첨가 복분자주의 품질 특성)

  • Kong, Tae-In;Cheong, Chul
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.16 no.5
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    • pp.3361-3369
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    • 2015
  • The objective of this study was to improve the quality of black raspberry wine added with wild grape, based on selection of yeast strains and fermentation conditions. The Y1 yeast(Lalvin 71B) indicated significantly higher lactic acid, ester, fusel oil content after fermented mashing than other samples tested and had an effect on the reduction of acidity and enhanced aroma of black raspberry wine. In addition, the high fermentation temperature($25^{\circ}C$) using Y1 yeast showed much higher tendency to retain components of aroma (ethyl acetate, higher alcohols) and the highest overall preference including sensory evaluation than that of low fermentation temperture($15^{\circ}C$). Thus, the fermentation using Y1 yeast at $25^{\circ}C$ can be applied to positively improve the taste and flavor of production of black raspberry wine added wild grape.

Thermal Characteristics Investigation of 6U CubeSat's Deployable Solar Panel Employing Thermal Gap Pad (열전도 패드가 적용된 6U 큐브위성용 태양전지판의 열적 특성 분석)

  • Kim, Hye-In;Kim, Hong-Rae;Oh, Hyun-Ung
    • Journal of Aerospace System Engineering
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    • v.14 no.3
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    • pp.51-59
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    • 2020
  • In the case of cubesat, a PCB-based deployable solar panel advantageous in terms of weight reduction and electrical circuit design is widely used considering the limited weight and volume of satellites. However, because of the low thermal conductivity of PCB, there is a limit relative to heat dissipation. In this paper, the thermal gap pad is applied to the contact between the PCB-based solar panel and the aluminum stiffener mounted on the outside of the panel. Thus, the heat transfer from the solar cell to the rear side of the panel is facilitated. It maximizes the heat dissipation performance while maintaining the merits of PCB panel, and thus, it is possible to improve the power generation efficiency from reducing the temperature of the solar cell. The effectiveness of the thermal design of the 6U cubesat's deployable solar panel using the thermal gap pad has been verified through on-orbit thermal analysis based on the results, compared with the conventional PCB-based solar panel.

Comparison of CH4 Emission between Auto Chamber and Manual Chamber in the Rice Paddy (벼논에서 자동 챔버와 수동 챔버를 이용한 CH4 배출량 비교)

  • Jeong, Hyun Cheol;Choi, Eun Jung;Lee, Jong Sik;Kim, Gun Yeob;Lee, Sun Il
    • Journal of Climate Change Research
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    • v.9 no.4
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    • pp.377-384
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    • 2018
  • The chamber method is widely used for measuring methane emission from paddy rice fields. The closed static chamber has advantages of easy installation and removal in the field and low manufacturing cost. However, the manual chamber method requires a lot of labor and has a limited sampling time and frequency. To overcome the disadvantages of the manual chamber, the auto-chamber system is used for measuring methane emission. We compared the differences in methane flux between the auto-chamber and manual chamber. To investigate methane emissions by the two methods, a chamber was installed for each of the following treatments : control without rice straw (NA), spring plowing after autumn rice straw application (SPRA) and autumn plowing after autumn rice straw application (APRA). The total methane emission was lowest in the control and highest in APRA with both methods. There was no significant difference in total methane emission between the methods, but dynamic fluctuation in methane with temperature change was accurately measured in the auto-chamber. Measuring methane emission with an auto-chamber system is expected to reduce uncertainty and increase accuracy, accompanied by labor reduction.