• International Journal of Automotive Technology
• /
• 제6권6호
• /
• pp.591-598
• /
• 2005

A three-way catalyst system of a natural gas vehicle (NGV) has characteristics of higher fuel consumption and higher thermal load than a lean-bum catalyst system. To meet stringent emission standards in the future, NGV with the lean-bum engine may need a catalyst system to reduce the amounts of HC, CO and NOx emission, although natural gas system has low emission characteristics. We conducted experiments to evaluate the conversion efficiency of the NOx reduction catalyst for the lean-burn natural gas engine. The NOx reduction catalysts were prepared with the ${\gamma}-Al_{2}O_3$ washcoat including Ba based on Pt, Pd and Rh precious metal. In the experiments, effective parameters were space velocity, spike duration of the rich condition, and the temperature of flowing model gas. From the results of the experiments, we found that the temperature for maximum NOx reduction was around $450^{\circ}C$, and the space velocity for optimum NOx reduction was around $30,000\;h^{-1}$ And we developed an evaluation model of the NOx reduction catalyst to evaluate the conversion performance of each other catalysts.

• 한국태양에너지학회 논문집
• /
• 제34권3호
• /
• pp.82-88
• /
• 2014

Using low outdoor temperature, free cooling system is used in a data center or industrial air-conditioning for energy saving. Because use of IT equipment has increased in some office building recently, there is a growing trend towards using free cooing system. Free cooling system performance is influenced by outdoor temperature. Therefore the performance is different with regions. In this study, performance characteristic of free cooling system is analysed and energy reduction is compared with some regions. Selected regions are 4 cities; including Ulsan analyzed in preceding research, Seoul, ChunCheon and Daejeon. The Aspentech software HYSYS 8.0v was used to conduct the analysis of free cooling system based on temperature per hour of 4 cities in 2013, respectively. The main result is following as. Free cooing system in this study has energy saving effect when outdoor temperature below $7^{\circ}C$. Becuase temperature of Chuncheon is relatively low, using free cooling system can conserve most air-conditioning energy. Energy reduction amount of Seoul is 11%, Chuncheon is 17.5%, Deajeon is 15%, Ulsan is 14%. In case of large scale of air-conditioning, it is reasonable to use free cooling system although the system is used in Seoul.

• 한국세라믹학회지
• /
• 제48권3호
• /
• pp.205-210
• /
• 2011

The dependence of sulfur redox behavior and its diffusivity on temperature and composition was studied in mixed alkali silicate melts by means of square wave voltammetry (SWV) at different frequencies in a temperature range of $1000^{\circ}C$ to $1400^{\circ}C$. The voltammograms showed two reduction peaks at high frequency but only one peak at low frequency. Irrespective of $K_2O/(Na_2O+K_2O)$, each peak potential due to reduction of $S^{6+}$ to $S^{4+}$ and $S^{4+}$ to $S^0$ moved toward a negative direction with temperature decrease, and the peak current showed a strong dependence on frequency at a constant temperature. However, the compositional dependence of the peak potential showed an inconsistent behavior with an increase of $K_2O$. The mixed alkali effect was not observed in sulfur diffusion. This inconsistency of both peak potential and diffusion for compositional dependence may be derived from the strong volatilization of sulfur in melts.

• 한국환경과학회지
• /
• 제11권6호
• /
• pp.577-582
• /
• 2002

Selective catalytic reduction and selective non-catalytic reduction processes are mainly used to treat nitrogen oxidants generated from fossil-fuel combustion. Especially, the selective non-catalytic reduction process can be operated more economical and designed more simply than the selective catalytic reduction. For this reason, many researchers carried out to increase the removal efficiency of nitrogen oxidants in the condition of low oxygen concentration by using the selective non-catalytic reduction process. However, this study was flue gas contained high oxygen concentration of 20(v/v%) with ammonia as a reducing agent. Moreover, it carried out experiment with many factors that are reaction temperature, retention time, initial NO concentration, NSR(normalized stoichiometric ratio). It was determined optimal operating conditions to improve NO removal efficiency with SNCR process. The De-NOx efficiency was increased with NSR, initial NO concentration and retention time increasement. This study has NO removal efficiency over 80% in the high oxygen concentration as well as low oxygen concentration. The injection of reducing agent may be considered for SNCR process and facility operation in 850$\^{C}$ of optimal condition.

• 지질공학
• /
• 제3권2호
• /
• pp.191-201
• /
• 1993

환원은 심층 지하처분되는 Cr(VI)의 양을 줄이는데 중요한 수단의 하나이다. 이 반응은 pH와 온도에 따라 민감하게 작용하며, 지하심층 처분장의 낮은 pH와 높은 온도는 토양 유기질, 높은 염소이온 농도와 더불어 Cr(VI)의 환원에 좋은 환경을 제공한다. 본 연구에서는 다양한 환경 조건에 따른 토양 유기질과 염소이온에 의한 Cr(VI)의 환원이 조사 되었다. aquifer와 aquitard 샘플은 각각 미국 루이지애나주 세인트 촬스군의 심층 처분장에서 채취되었다. 본 연구에서는 심층처분장을 대표하는 pH(-0.81~2.0), 온도($50^{\circ}C와{\;}70^{\circ}C$), 염소이온 농도(0, 0.26, 0.52 몰)를 이용하였다.

• 한국세라믹학회지
• /
• 제51권1호
• /
• pp.25-31
• /
• 2014

New green phosphor is synthesized by reducing $LiAlO_2:xEu^{3+}$ phosphors in a low pressure $H_2$ atmosphere. The $LiAlO_2:xEu^{3+}$ prepared by a solid state reaction method is reported as red phosphor. The effect of the reduction treatment on the $LiAlO_2:xEu^{3+}$ on the crystalline phase change and photoluminescence (PL) property are characterized. The reduced phosphor had a broad green light spectrum centered at 524 nm. The PL intensity of the reduced phosphor increased to a maximum at the reduction temperature of $1100^{\circ}C$. The PL intensity decreased with a further increase in the reduction temperature. The crystalline phase constituting the reduced phosphor varied with the temperature. A new crystalline phase $Li_2Al_4O_7$ was observed at $1100^{\circ}C$. The origin of the green-light emission is discussed in relation to the crystalline phase change.

• 한국자동차공학회논문집
• /
• 제21권6호
• /
• pp.81-91
• /
• 2013

A novel design process of a parallel multi-flow type air-cooled condenser of a dual-loop waste heat recovery system with Rankine steam cycles for improving the fuel efficiency of gasoline automobiles has been investigated focusing on reduction of the pressure drop inside the micro-tubes. The low temperature condenser plays a role to dissipate heat from the system by condensing the low temperature loop working fluid sufficiently. However, the refrigerant has low evaporation temperature enough to recover the waste from engine coolant of about $100^{\circ}C$ but has small saturation enthalpy so that excessive mass flow rate of the LT working fluid, e.g., over 150 g/s, causes enormously large pressure drop of the working fluid to maintain the heat dissipation performance of more than 20 kW. This paper has dealt with the scheme to design the low temperature condenser that has reduced pressure drop while ensuring the required thermal performance. The number of pass, the arrangement of the tubes of each pass, and the positions of the inlet and outlet ports on the header are most critical parameters affecting the flow uniformity through all the tubes of the condenser. For the purpose of the performance predictions and the parametric study for the LT condenser, we have developed a 1-dimensional user-friendly performance prediction program that calculates feasibly the phase change of the working fluid in the tubes. An example is presented through the proposed design process and compared with an experiment.

• 한국결정성장학회지
• /
• 제24권1호
• /
• pp.27-32
• /
• 2014

본 연구에서는 매스콘크리트의 수화열 저감 및 초기강도 향상을 목적으로 3성분계 배합에 따른 콘크리트의 기초적 특성을 분석하였는데 결과를 요약하면 다음과 같다. 굳지 않은 콘크리트의 물성은 목표범위를 모두 만족하는 것으로 나타났다. 응결시간은 W/B와 관계없이 저열 시멘트 배합이 가장 빠른 것으로 나타났고, 간이 수화열은 저열 배합의 피크 온도가 가장 높은 것으로 나타났고, 저발열-B 배합이 가장 낮은 온도를 나타내었으며, 조강형 저발열 배합은 저발열-B와 유사한 것으로 나타났다. 경화 콘크리트의 압축강도는 초기재령에서 저발열-B 배합을 제외한 모든 배합이 유사한 강도 범위를 나타내었고, 장기 재령에서는 큰 차이 없이 유사한 강도 범위를 나타내었다.

• 한국대기환경학회지
• /
• 제26권1호
• /
• pp.1-9
• /
• 2010

In this study, the selective catalytic reduction of $NO_x$ with ammonia was carried out in a filter bag support reactor. The experiments were performed by powder type $MnO_x$ and $V_2O_5$/$TiO_2$ catalyst at low temperature between 130 and $250^{\circ}C$. Also, the effect of $SO_2$ and $H_2O$ on the NO conversion was investigated under our test conditions. The powder type catalysts were analyzed by X-ray photoelectron spectrum (XPS), X-ray diffraction(XRD), scanning electron microscopy (SEM) and thermal gravimetric analysis (TGA). It was observed that NO removal efficiency of the powder type $V_2O_5$/$TiO_2$ catalyst was 85% at low temperature($200^{\circ}C$) under presence of oxygen and that of $MnO_x$ was 50% at the same condition. The powder type $V_2O_5$/$TiO_2$ catalyst, in conclusion, was found to be available for SCR reaction in a filter bag support system.

• 한국도로학회논문집
• /
• 제16권2호
• /
• pp.1-9
• /
• 2014

PURPOSES : This study aims to evaluate the performance of interlocking block pavement system for low speed highway. METHODS : Through on-site monitoring, environmental impact assessment of interlocking block pavement such as heat island reduction, traffic safety, noise pollution were evaluated as compared with asphalt pavement. Also the pavement condition and roughness were evaluated according to performance period. RESULTS : Surface temperature of interlocking block pavement was about 7 degree lower than asphalt pavement in midsummer. Compared to asphalt pavement, vehicle speed reduction effect of interlocking block pavement was about 2kph. For low speed driving, the noise pollution was measured at a similar level for both asphalt and interlocking block pavement. After 42month service period, the breakage of block was only 0.24% for the whole surveyed area. IRI of interlock block pavement was estimated within the range of 5~8m/km. CONCLUSIONS : Depending on the performance monitoring results such as heat island reduction, providing traffic safety and keeping a good pavement condition for a long service period, it assures that interlocking block pavement was applicable for low speed road.