• 제목/요약/키워드: low temperature reduction

검색결과 1,037건 처리시간 0.027초

가압 유동층 반응기에서 산소공여입자의 메탄 연소 특성에 미치는 온도, 압력 및 기체체류시간의 영향 (Effects of Temperature, Pressure, and Gas Residence Time on Methane Combustion Characteristics of Oxygen Carrier Particle in a Pressurized Fluidized Bed Reactor)

  • 류호정;박상수;문종호;최원길;이영우
    • 한국수소및신에너지학회논문집
    • /
    • 제23권2호
    • /
    • pp.173-182
    • /
    • 2012
  • Effects of temperature, pressure, and gas residence time on methane combustion characteristics of mass produced oxygen carrier particle (OCN706-1100) were investigated in a pressurized fluidized bed reactor using methane and air as reactants for reduction and oxidation, respectively. The oxygen carrier showed high fuel conversion, high $CO_2$ selectivity, and low CO concentration at reduction condition and very low NO emission at oxidation condition. Moreover OCN706-1100 particle showed good regeneration ability during successive reduction-oxidation cyclic tests up to the 10th cycle. Fuel conversion and $CO_2$ selectivity decreased and CO emission increased as temperature increased. These results can be explained by trend of calculated equilibrium CO concentration. However, $CO_2$ selectivity increased as pressure increased and fuel conversion increased as gas residence time increased.

저탄소 미량합금강의 미세조직에 미치는 고온변형의 효과 (Effects of Austenitization Temperature and Hot Deformation on Microstructure of Microalloyed Low Carbon Steels)

  • 김새암;이상우
    • 열처리공학회지
    • /
    • 제16권2호
    • /
    • pp.83-89
    • /
    • 2003
  • As a research for developing fine-grained high strength low carbon steels, the effects of austenitization temperature and hot deformation on microstructure was investigated in 0.15 wt.% carbon steels with microalloying elements such as Nb and Ti. When the steels were reheated at $1250^{\circ}C$, Nb containing steel showed very coarse austenite grain size of $200{\mu}m$ whereas Nb-Ti steel did fine one of $70{\mu}m$ because Ti carbonitrides could suppress the austenite grain growth. In case of 50% reduction at $850^{\circ}C$, the austenite grains in the Nb steel partially recrystallized while those in the Nb-Ti steel fully recrystallized probably due to finer prior austenite grains.For the Nb-Ti steel, ferrite grain size was not sensitively changed with austenitization temperature and compression strain and, severe deformation of 80% reduction was not essentially necessary to refine ferrite grains to about $3{\mu}m$ which could be obtained through lighter deformation of 40% reduction.

저온하에서 시차열 수축에 의한 WMA 콘크리트의 휨강도 변화 (Variation of Flexural Strength of Warm-mix Asphalt Concretes Due to Differential Thermal Contraction at Low Temperatures)

  • 최정순;김성운;김광우
    • 한국도로학회논문집
    • /
    • 제14권4호
    • /
    • pp.63-72
    • /
    • 2012
  • PURPOSES : Hot-mix asphalt(HMA) concretes show a trend of strength increase at low temperature due to binder stiffness increase, but strength decrease below a ceratin low temperature. This is due to the differential thermal contraction(DTC) which is induced by a significant difference in coefficients of thermal contraction between aggregate and asphalt which is coated around the aggregate. This DTC damage is well known to occur in HMA concrete, but is not yet investigated in warm-mix asphalt(WMA) concretes. METHODS : To evaluate DTC damage on WMA in this study, the flexural strength($S_f$) of WMA concretes, which were produced at $30{\sim}40^{\circ}C$ lower temperature, was evaluated in comparison with that of HMA at -5, -15 and $-25^{\circ}C$. RESULTS : Most of WMA and HMA mixtures showed flexural strength increase down to $-15^{\circ}C$ and decrease below $-15^{\circ}C$. this type of strength reduction below $-15^{\circ}C$ can e explained as the effect of differential thermal contraction that is a consequence of the large difference in coefficients of thermal contraction between aggregate and asphalt. the property reduction of WMA is similar the result of previous works dealt with HMA mixtures. CONCLUSIONS : Even though there is some differences by materials used, the WMA concretes showed a significantly lower DTC damage than HMA concrete at low temperature at ${\alpha}$=0.05 level.

배연탈질을 위한 저온 SCR 기술 도입에 따른 시나리오별 경제성 분석 (A Study on the Economic Analysis of Low-Temperature SCR Technology for NOx Reduction by Scenarios)

  • 홍성준;이유아;정순관
    • 에너지공학
    • /
    • 제29권2호
    • /
    • pp.10-22
    • /
    • 2020
  • 미세먼지 문제 해결에 대한 국민적 요구가 높아짐에 따라 정부에서는 강도 높은 미세먼지 관련 대책을 발표하고 있다. 그래서 최근에 미세먼지의 전구체 중에서 질소산화물을 제거하기 위한 배연탈질기술로서 선택적 촉매환원법(SCR)이 주목받고 있다. 본 연구에서는 미세먼지 관련 정부정책과 시장 및 기술개발 현황을 조사하고, SCR 기술이 산업체에 적용되는 경우를 Case별로 구분하여 시나리오별 경제성 분석을 실시하였다. 시나리오별 경제성 분석의 결과는 NPV로 산출하였으며, 탈질설비가 구축되어 있지 않은 기업(Case 1)이 일반 SCR 기술을 신규로 도입하는 경우(Scenario 1-1)와 저온 SCR 기술을 신규로 도입하는 경우(Scenario 1-2)를 분석하였다. 그리고 탈질설비가 이미 구축되어 있는 기업(Case 2)이 일반 SCR 기술을 그대로 사용하는 경우(Scenario 2-1)와 저온 SCR 기술로 대체하는 경우(Scenario 2-2)로 구분하여 분석하였으며, 모든 시나리오별 NPV 결과를 바탕으로 비교 분석을 실시하였다.

Oxidative Etching of Imprinted Nanopatterns by Combination of Vacuum Annealing and Plasma Treatment

  • Park, Dae Keun;Kang, Aeyeon;Jeong, Mira;Lee, Jae-Jong;Yun, Wan Soo
    • 한국진공학회:학술대회논문집
    • /
    • 한국진공학회 2013년도 제45회 하계 정기학술대회 초록집
    • /
    • pp.251.1-251.1
    • /
    • 2013
  • Combination of oxidative vacuum annealing and oxygen plasma treatment can serve as a simple and efficient method of line-width modification of imprinted nanopatterns. Since the vacuum annealing and oxygen plasma could lead mass loss of polymeric materials, either one of the process can yield a narrowed patterns. However, the vacuum annealing process usually demands quite high temperatures (${\geq}300^{\circ}C$) and extended annealing time to get appreciable line-width reduction. Although the plasma treatment may be considered as an effective low temperature rapid process for the line-width reduction, it is also suffering for the lowered controllability on application to very fine patterns. We have found that the vacuum annealing temperature can be lowered by introducing the oxygen in the vacuum process and that the combination of oxygen plasma treatment with the vacuum annealing could yield the best result in the line-with reduction of the imprinted polymeric nanopatterns. Well-defined line width reduction by more than 50% was successfully demonstrated at relatively low temperatures. Furthermore, it was verified that this process was applicable to the nanopatterns of different shapes and materials.

  • PDF

Investigating meso-scale low-temperature fracture mechanisms of recycled asphalt concrete (RAC) via peridynamics

  • Yuanjie Xiao;Ke Hou;Wenjun Hua;Zehan Shen;Yuliang Chen;Fanwei Meng;Zuen Zheng
    • Computers and Concrete
    • /
    • 제33권5호
    • /
    • pp.605-619
    • /
    • 2024
  • The increase of reclaimed asphalt pavement (RAP) content in recycled asphalt concrete (RAC) is accompanied by the degradation of low-temperature cracking resistance, which has become an obstacle to the development of RAC. This paper aims to reveal the meso-scale mechanisms of the low-temperature fracture behavior of RAC and provide a theoretical basis for the economical recycling of RAP. For this purpose, micromechanical heterogeneous peridynamic model of RAC was established and validated by comparing three-point bending (TPB) test results against corresponding numerical simulation results of RAC with 50% RAP content. Furthermore, the models with different aggregate shapes (i.e., average aggregates circularity (${\bar{C_r}}=1.00$, 0.75, and 0.50) and RAP content (i.e., 0%, 15%, 30%, 50%, 75%, and 100%) were constructed to investigate the effect of aggregate shape and RAP content on the low-temperature cracking resistance. The results show that peridynamic models can accurately simulate the low-temperature fracture behavior of RAC, with only 2.9% and 13.9% differences from the TPB test in flexural strength and failure strain, respectively. On the meso-scale, the damage in the RAC is mainly controlled by horizontal tensile stress and the stress concentration appears in the interface transition zone (ITZ). Aggregate shape has a significant effect on the low-temperature fracture resistance, i.e., higher aggregate circularity leads to better low-temperature performance. The large number of microcracks generated during the damage evolution process for the peridynamic model with circular aggregates contributes to slowing down the fracture, whereas the severe stress concentration at the corners leads to the fracture of the aggregates with low circularity under lower stress levels. The effect of RAP content below 30% or above 50% is not significant, but a substantial reduction (16.9% in flexural strength and 16.4% in failure strain) is observed between the RAP content of 30% and 50%. This reduction is mainly attributed to the fact that the damage in the ITZ region transfers significantly to the aggregates, especially the RAP aggregates, when the RAP content ranges from 30% to 50%.

저압 SCR을 위한 디젤발전기 배기가스 온도 변화 (Temperature Variation of Exhaust Gas in Diesel Generator for Low Pressure SCR)

  • 홍철현;이창민;이상득
    • 해양환경안전학회지
    • /
    • 제27권2호
    • /
    • pp.355-362
    • /
    • 2021
  • L.P SCR의 촉매 반응을 위해 선박의 발전기용 4행정 디젤엔진의 배기가스 온도를 높게 설계 할 수밖에 없었다. 본 연구의 목적은 밸브개폐시기와 연료분사시기를 조정을 통한 배기가스의 온도 감소가 L.P SCR의 운전조건을 만족시키고 고온으로 인한 발전기 엔진의 사고를 예방하기 위함이었다. 배기가스 온도를 하강시키기 위해 캠샤프트의 각도를 조정하고 연료분사펌프의 Shim을 추가하였다. 그 결과 최대폭발압력은 12.8 bar 증가하였고 터보차저 출구온도 평균값은 13.3 ℃ 하강하였다. 터보차저 출구에서 SCR 입구까지의 열손실을 감안하더라도 L.P SCR 운전조건인 SCR 챔버 입구 온도인 290 ℃를 만족하였다. 배기가스 온도 하강을 통해 디젤발전기의 안전운전이 가능하게 한 연구였다.

고체산화물 연료전지용 $YSZ/La_0.85S_r0.15MnO_3$계 복합전극의 개발 (Development of $YSZ/La_0.85S_r0.15MnO_3$ Composite Electrodes for Solid Oxide Fuel Cells)

  • 윤성필;현상훈;김승구;남석우;홍성안
    • 한국세라믹학회지
    • /
    • 제36권9호
    • /
    • pp.982-990
    • /
    • 1999
  • YSZ/LSM composite cathode was fabricated by dip-coating of YSZ sol on the internal pore surface of a LSM cathode followed by sintering at low temperature (800-100$0^{\circ}C$) The YSZ coating significantly increased the TPB(Triple Phase Boundary) where the gas the electrode and the electrolyte were in contact with each other. Sinter the formation of resistive materials such as La2Zr2O7 or SrZrO3 was prevented due to the low processing temperature and TPB was increased due to the YSZ film coating the electrode resistance (Rel) was reduced about 100 times compared to non-modified cathode. From the analysis of a.c impedance it was shown that microstructural change of the cathode caused by YSZ film coating affected the oxygen reduction reaction. In the case of non-modified cathode the RDS (rate determining step) was electrode reactions rather than mass transfer or the oxygen gas diffusion in the experimental conditions employed in this study ($600^{\circ}C$-100$0^{\circ}C$ and 0,01-1 atm of Po2) for the YSZ film coated cathode however the RDS involved the oxygen diffusion through micropores of YSZ film at high temperature of 950-100$0^{\circ}C$ and low oxygen partial pressure of 0.01-0.03 atm.

  • PDF

산화-환원 싸이클 조업에 의한 고순도 수소생성 (High Purity Hydrogen Production by Redox Cycle Operation)

  • 전법주;박지훈
    • 한국수소및신에너지학회논문집
    • /
    • 제21권5호
    • /
    • pp.355-363
    • /
    • 2010
  • High purity hydrogen, 97-99 vol.%, with CO at just ppm levels was obtained in a fixed bed of iron oxide employing the steam-iron cycle operation with reduction at 823K and oxidation in a steam-$N_2$ mixture at 773K TGA experiments indicated that temperature of the reduction step as well as its duration are important for preventing carbon build-up in iron and the intrusion of $CO_2$ into the hydrogen product. At a reduction temperature of 823K, oxide reduction by $H_2$ was considerably faster than reduction by CO. If the length of the reduction step exceeds optimal value, low levels of methane gas appeared in the off-gas. Furthermore, with longer durations of the reduction step and CO levels in the reducing gas greater than 10 vol.%, carbidization of the iron and/or carbon deposition in the bed exhibited the increasing pressure drop over the bed, eventually rendering the reactor inoperable. Reduction using a reducing gas containing 10 vol.% CO and a optimal reduction duration gave constant $H_2$ flow rates and off-gas composition over 10 redox reaction cycles.

한방병원에 요통, 하지방사통으로 내원한 환자 236명에서 MRI상 추간판 탈출증과 적외선 체열 검사(DITI)와의 연관성 분석 (Correlation Analysis between HIVD of L-spine MRI and Digital Infrared Thermal Image (DITI) on the Patients of LBP Who Visit Korean Medicine Hospital)

  • 김길환;권옥준;주영국;송승배;김두리;최영준;신수지
    • 한방재활의학과학회지
    • /
    • 제27권3호
    • /
    • pp.107-115
    • /
    • 2017
  • Objectives This study is planned to classify correlation between HIVD of L-spine MRI and Digital Infrared Thermal Image (DITI). Methods We measured the temperature of both leg whose 120 men and 116 women patients with lumbar pain in Bucheon Jaseng Korean Medicine Hospital. And We use Magnetic Resonance Imaging (MRI) for classifying the patients who has lumbar intervertebral disc or not. Results 1) There was no statistical relation between difference of both leg's temperature and gender (p>0.05). 2) There was meaningful statistical relation between difference of both leg's temperature and age (p<0.05). 3) There was meaningful statistical relation between direction of HIVD of L-spine and direction of temperature reduction. 4) There was meaningful statistical relation between the severity of HIVD of L5/S1 and degree of temperature reduction. But there was no statistical relation between the severity of HIVD of L3/4, L4/5 and degree of temperature reduction. Conclusions We can use Digital Infrared thermal image (DITI) on low back pain patients for diagnosis. But we should not use DITI alone. DITI has limit in diagnosis.