• Title/Summary/Keyword: low temperature reduction

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EVALUATION OF NOx REDUCTION CATALYST BY MODEL GAS FOR LEAN-BURN NATURAL GAS ENGINE

  • LEE C. H.;CHO B. C.
    • International Journal of Automotive Technology
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    • v.6 no.6
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    • pp.591-598
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    • 2005
  • A three-way catalyst system of a natural gas vehicle (NGV) has characteristics of higher fuel consumption and higher thermal load than a lean-bum catalyst system. To meet stringent emission standards in the future, NGV with the lean-bum engine may need a catalyst system to reduce the amounts of HC, CO and NOx emission, although natural gas system has low emission characteristics. We conducted experiments to evaluate the conversion efficiency of the NOx reduction catalyst for the lean-burn natural gas engine. The NOx reduction catalysts were prepared with the ${\gamma}-Al_{2}O_3$ washcoat including Ba based on Pt, Pd and Rh precious metal. In the experiments, effective parameters were space velocity, spike duration of the rich condition, and the temperature of flowing model gas. From the results of the experiments, we found that the temperature for maximum NOx reduction was around $450^{\circ}C$, and the space velocity for optimum NOx reduction was around $30,000\;h^{-1}$ And we developed an evaluation model of the NOx reduction catalyst to evaluate the conversion performance of each other catalysts.

Analysis of Energy Reduction of Free Cooling System with Regions of South Korea (지역별 프리쿨링 시스템의 에너지 절감 분석)

  • Yoon, Jung-In;Son, Chang-Hyo;Choi, Kwang-Hwan;Baek, Seung-Moon;Heo, Jeong-Ho;Kim, Young-Min
    • Journal of the Korean Solar Energy Society
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    • v.34 no.3
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    • pp.82-88
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    • 2014
  • Using low outdoor temperature, free cooling system is used in a data center or industrial air-conditioning for energy saving. Because use of IT equipment has increased in some office building recently, there is a growing trend towards using free cooing system. Free cooling system performance is influenced by outdoor temperature. Therefore the performance is different with regions. In this study, performance characteristic of free cooling system is analysed and energy reduction is compared with some regions. Selected regions are 4 cities; including Ulsan analyzed in preceding research, Seoul, ChunCheon and Daejeon. The Aspentech software HYSYS 8.0v was used to conduct the analysis of free cooling system based on temperature per hour of 4 cities in 2013, respectively. The main result is following as. Free cooing system in this study has energy saving effect when outdoor temperature below $7^{\circ}C$. Becuase temperature of Chuncheon is relatively low, using free cooling system can conserve most air-conditioning energy. Energy reduction amount of Seoul is 11%, Chuncheon is 17.5%, Deajeon is 15%, Ulsan is 14%. In case of large scale of air-conditioning, it is reasonable to use free cooling system although the system is used in Seoul.

Sulfur Redox Equilibrium in Mixed Alkali Silicate Glass Melts

  • Kim, Ki-Dong;Hwang, Jong-Hee
    • Journal of the Korean Ceramic Society
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    • v.48 no.3
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    • pp.205-210
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    • 2011
  • The dependence of sulfur redox behavior and its diffusivity on temperature and composition was studied in mixed alkali silicate melts by means of square wave voltammetry (SWV) at different frequencies in a temperature range of $1000^{\circ}C$ to $1400^{\circ}C$. The voltammograms showed two reduction peaks at high frequency but only one peak at low frequency. Irrespective of $K_2O/(Na_2O+K_2O)$, each peak potential due to reduction of $S^{6+}$ to $S^{4+}$ and $S^{4+}$ to $S^0$ moved toward a negative direction with temperature decrease, and the peak current showed a strong dependence on frequency at a constant temperature. However, the compositional dependence of the peak potential showed an inconsistent behavior with an increase of $K_2O$. The mixed alkali effect was not observed in sulfur diffusion. This inconsistency of both peak potential and diffusion for compositional dependence may be derived from the strong volatilization of sulfur in melts.

A Study on Characteristic of NO Reduction by High Level O2Gas in Selective Non-Catalystic Reaction (High Level O2배가스중 NO 저감에 대한 선택적비촉매환원 반응특성에 관한 연구)

  • 이강우;정종현;오광중
    • Journal of Environmental Science International
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    • v.11 no.6
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    • pp.577-582
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    • 2002
  • Selective catalytic reduction and selective non-catalytic reduction processes are mainly used to treat nitrogen oxidants generated from fossil-fuel combustion. Especially, the selective non-catalytic reduction process can be operated more economical and designed more simply than the selective catalytic reduction. For this reason, many researchers carried out to increase the removal efficiency of nitrogen oxidants in the condition of low oxygen concentration by using the selective non-catalytic reduction process. However, this study was flue gas contained high oxygen concentration of 20(v/v%) with ammonia as a reducing agent. Moreover, it carried out experiment with many factors that are reaction temperature, retention time, initial NO concentration, NSR(normalized stoichiometric ratio). It was determined optimal operating conditions to improve NO removal efficiency with SNCR process. The De-NOx efficiency was increased with NSR, initial NO concentration and retention time increasement. This study has NO removal efficiency over 80% in the high oxygen concentration as well as low oxygen concentration. The injection of reducing agent may be considered for SNCR process and facility operation in 850$\^{C}$ of optimal condition.

Equilibria and Kinetics of Cr(VI) Reduction (심층 지하에서의 육가 크롬 환원)

  • 현재혁
    • The Journal of Engineering Geology
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    • v.3 no.2
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    • pp.191-201
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    • 1993
  • Reduction is one of the important mechanisrns in decreasing the amount of Cr(VI) in wastewater and this reaction is quite dependent on pH and temperature. Either soil organic materials, or a high inorganic salt concentration with elevated temperature and low pH will provide a good condition for the reduction of Cr(VI) to Cr(III) in deep well injection zones. Chromate reduction by soil organic materials and chloride ion in various environment conditions is investigated. Aquifer and aquitard formation samples have been obtained from a deep well in St. Bernard Parish, and St. Charles Parish, LA, U.S.A., respectively. For this study, pH ranging from -0.81 to 2.0, temperature $50^{\circ}C{\;}and{\;}70^{\circ}C$, and cliloride concentration 0 M, 0.26 M and 0.52 M are used to represent the actual conditions in deep well injection zones.

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Effect of Heat-treatment Atmosphere on Photoluminescence of Eu-doped Li-Al-O System (열처리 분위기가 Eu 이온이 첨가된 Li-Al-O계 형광체 특성에 미치는 영향)

  • Kim, Jeong Seog;Cheon, Chae Il;Chae, Ki-Woong
    • Journal of the Korean Ceramic Society
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    • v.51 no.1
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    • pp.25-31
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    • 2014
  • New green phosphor is synthesized by reducing $LiAlO_2:xEu^{3+}$ phosphors in a low pressure $H_2$ atmosphere. The $LiAlO_2:xEu^{3+}$ prepared by a solid state reaction method is reported as red phosphor. The effect of the reduction treatment on the $LiAlO_2:xEu^{3+}$ on the crystalline phase change and photoluminescence (PL) property are characterized. The reduced phosphor had a broad green light spectrum centered at 524 nm. The PL intensity of the reduced phosphor increased to a maximum at the reduction temperature of $1100^{\circ}C$. The PL intensity decreased with a further increase in the reduction temperature. The crystalline phase constituting the reduced phosphor varied with the temperature. A new crystalline phase $Li_2Al_4O_7$ was observed at $1100^{\circ}C$. The origin of the green-light emission is discussed in relation to the crystalline phase change.

A Design Process for Reduction of Pressure Drop of Air-cooled Condenser for Waste Heat Recovery System (폐열 회수 시스템용 공랭식 응축기의 압력 손실 저감 설계)

  • Bae, Sukjung;Heo, Hyungseok;Park, Jeongsang;Lee, Hongyeol;Kim, Charnjung
    • Transactions of the Korean Society of Automotive Engineers
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    • v.21 no.6
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    • pp.81-91
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    • 2013
  • A novel design process of a parallel multi-flow type air-cooled condenser of a dual-loop waste heat recovery system with Rankine steam cycles for improving the fuel efficiency of gasoline automobiles has been investigated focusing on reduction of the pressure drop inside the micro-tubes. The low temperature condenser plays a role to dissipate heat from the system by condensing the low temperature loop working fluid sufficiently. However, the refrigerant has low evaporation temperature enough to recover the waste from engine coolant of about $100^{\circ}C$ but has small saturation enthalpy so that excessive mass flow rate of the LT working fluid, e.g., over 150 g/s, causes enormously large pressure drop of the working fluid to maintain the heat dissipation performance of more than 20 kW. This paper has dealt with the scheme to design the low temperature condenser that has reduced pressure drop while ensuring the required thermal performance. The number of pass, the arrangement of the tubes of each pass, and the positions of the inlet and outlet ports on the header are most critical parameters affecting the flow uniformity through all the tubes of the condenser. For the purpose of the performance predictions and the parametric study for the LT condenser, we have developed a 1-dimensional user-friendly performance prediction program that calculates feasibly the phase change of the working fluid in the tubes. An example is presented through the proposed design process and compared with an experiment.

Fundamental characteristics of high early strength low heat concrete according to mineral binder and high early strength material combination (광물질 결합재 및 조강형 재료 조합에 따른 조강형 저발열 콘크리트의 기초적 특성)

  • Kim, Kyoungmin;Son, Hojung
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.24 no.1
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    • pp.27-32
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    • 2014
  • This study analyzed the fundamental characteristics of concrete according to a ternary system mixing in order to reduce hydration heat of mass concrete and to improve early age strength. The results are as follows. The fluidity of unconsolidated concrete satisfied the target scope regardless of the binder conditions. When the replacement ratio between FA and BS increased, the slump of low heat-A mix and low heat-B mix increased, and air content was not affected by the change of binders. As for setting time, low heat cement mix had the fastest regardless of W/B, and high early strength low heat mix achieved 6 hours' reduction compared with low heat-B mix at initial set, and 12 hours' reduction at the final set respectively. As for the simple hydration heat, the low mix peak temperature was the highest and low heat-B mix had the lowest temperature. And high early strength low heat mix was similar with that of low heat-B. The compressive strength of hardened concrete had similar strength scope in all mixes except for low heat-B mix at early ages, and had unexceptionally similar one without huge differences at long-term ages.

Characterization of NOx Reduction on Filter Bag Support System at Low Temperature using Powder Type MnOx and V2O2/TiO2 Catalysts (분말형 MnOx와 V2O2/TiO2 촉매를 이용한 저온영역의 백필터 공정에서 질소산화물 제거 특성)

  • Kim, Byung-Hwan;Kim, Jeong-Heon;Kang, Pil-Sun;Yoo, Seung-Kwan
    • Journal of Korean Society for Atmospheric Environment
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    • v.26 no.1
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    • pp.1-9
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    • 2010
  • In this study, the selective catalytic reduction of $NO_x$ with ammonia was carried out in a filter bag support reactor. The experiments were performed by powder type $MnO_x$ and $V_2O_5$/$TiO_2$ catalyst at low temperature between 130 and $250^{\circ}C$. Also, the effect of $SO_2$ and $H_2O$ on the NO conversion was investigated under our test conditions. The powder type catalysts were analyzed by X-ray photoelectron spectrum (XPS), X-ray diffraction(XRD), scanning electron microscopy (SEM) and thermal gravimetric analysis (TGA). It was observed that NO removal efficiency of the powder type $V_2O_5$/$TiO_2$ catalyst was 85% at low temperature($200^{\circ}C$) under presence of oxygen and that of $MnO_x$ was 50% at the same condition. The powder type $V_2O_5$/$TiO_2$ catalyst, in conclusion, was found to be available for SCR reaction in a filter bag support system.

Performance Evaluation of Interlocking Block Pavement for Low Speed Highway (인터로킹 블록포장의 저속도로 적용성 평가)

  • Lin, Wuguang;Ryu, SungWoo;Lee, ByeongTae;Cho, Yoon-Ho
    • International Journal of Highway Engineering
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    • v.16 no.2
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    • pp.1-9
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    • 2014
  • PURPOSES : This study aims to evaluate the performance of interlocking block pavement system for low speed highway. METHODS : Through on-site monitoring, environmental impact assessment of interlocking block pavement such as heat island reduction, traffic safety, noise pollution were evaluated as compared with asphalt pavement. Also the pavement condition and roughness were evaluated according to performance period. RESULTS : Surface temperature of interlocking block pavement was about 7 degree lower than asphalt pavement in midsummer. Compared to asphalt pavement, vehicle speed reduction effect of interlocking block pavement was about 2kph. For low speed driving, the noise pollution was measured at a similar level for both asphalt and interlocking block pavement. After 42month service period, the breakage of block was only 0.24% for the whole surveyed area. IRI of interlock block pavement was estimated within the range of 5~8m/km. CONCLUSIONS : Depending on the performance monitoring results such as heat island reduction, providing traffic safety and keeping a good pavement condition for a long service period, it assures that interlocking block pavement was applicable for low speed road.