• Title/Summary/Keyword: low temperature fluidity

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An Experimental Study on the Properties of UHPC with Different Types of Cements (시멘트 종류에 따른 초고성능 콘크리트의 특성에 관한 실험적 연구)

  • Park, Jung-Jun;Kang, Su-Tae;Ryu, Gum-Sung;Koh, Gyung-Taek;Kim, Sung-Wook;Lee, Jang-Hwa
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.11a
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    • pp.345-348
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    • 2008
  • A Cement account for the most amount than other materials in the material composition of ultra-high-performance concrete. If we especially consider the effect of high temperature curing on the cement hydration and the problems of autogenous shrinkage, heat of hydration we need selection of proper cement type by grasping influence of cement in the properties of UHPC. Therefore, in this paper we examined properties of fluidity, compressive strength and elastic modulus of UHPC due to domestic portland cement types. In results, we could get a result that the low heat cement increase fluidity, compressive strength in UHPC compare with high early strength cement and ordinary portland cement. we are systematically going to examination on the influence of UHPC by domestic portland cement types.

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Improvement of Low Temperature Property of Biodiesel from Palm Oil and Beef Tallow Via Urea Complexation (요소 착물형성에 의한 포화지방산 고함유 팜유 및 우지 유래 바이오디젤의 저온유동성 개선효과 연구)

  • Lee, Yong-Hwa;Shin, Jung-Ah;Zhang, Hua;Lee, Ki-Teak;Kim, Kwang-Soo;Jang, Young-Seok;Park, Kwang-Geun
    • New & Renewable Energy
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    • v.8 no.4
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    • pp.38-43
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    • 2012
  • Biodiesel is non-petroleum based fuel produced from vegetable oils or animal fats through transesterification. The compositions of saturated and unsaturated fatty acids in the feedstocks are important factors for biodiesel quality in terms of low-temperature fluidity and oxidative stability. The goal of this study is to improve the cold flow property of biodiesel from vegetable and animal origin containing highly saturated methyl esters (approx. 50%). In this purpose poly-saturated methyl esters in palm and tallow biodiesel were removed via urea-based fractionation and then the recovered fractions (enriched unsaturated fatty acid methyl esters) were supplemented with cold flow improvers. The highest concentration of unsaturated fatty acid methyl esters (93.8%) was obtained using a urea/fatty acid ratio of 3:1 at the crystallization temperature of $0^{\circ}C$ for 17 hours in incubation, with recovery of 71% and the addition of cold flow improver (Flozol$^{(R)}$ 515, 3,000 ppm) to the enriched poly-unsaturated fatty acid methyl esters reduced the CFPP(cold filter plugging point) of palm biodiesel from $12^{\circ}C$ to $-42^{\circ}C$. In tallow biodiesel both the enrichment of unsaturated fatty acid methyl esters (93.71%) and the addition of cold flow improver (Infineum R408, 3,000ppm) reduced the CFPP from $10^{\circ}C$ to $-32^{\circ}C$.

Compressive Strength and Fluidity of Low Temperature Curable Mortar Using High Early Strength Cement According to Types of Anti-freezer, Accelerator for Freeze Protection and Water Reducing Agent (조강형시멘트를 사용한 저온경화형 모르타르의 압축강도 및 유동특성에 미치는 방동제, 내한촉진제 및 감수제의 영향)

  • Park, Jung-Hoon;Ki, Kyoung-Kuk;Lee, Han-Seung;Kim, Hyeong-Cheol;Choi, Hyun-Kuk;Min, Tae-Beom
    • Journal of the Korea Institute of Building Construction
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    • v.16 no.5
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    • pp.405-412
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    • 2016
  • In order to examine the possibility of practical use of concrete at low-temperature environment using high early strength cement with cold resistance admixture, an experimental study on workability, freezing temperature and compressive strength of the mortar with different types of anti-freezer, water reducing agent and accelerator for freeze protection at low-temperature were evaluated. Compressive strength was increased in use of anti-freezer, especially SN anti-freezer was higher than CN anti-freezer. 0min flow was increased, the 20min flow was decreased. And 20min flow was improved in use of FR, RT water reducing agent. CF, LS accelerator for freeze protection, regardless of the type of water reducing agent, compressive strength was increased.

Phase Morphology and Foaming of Polypropylene/Ethylene-octene Copolymer Blends (폴리프로필렌/에틸렌옥텐 공중합체 블렌드의 상분리 구조 및 발포 특성)

  • 서관호;임정철
    • Polymer(Korea)
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    • v.25 no.5
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    • pp.707-718
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    • 2001
  • Polypropylene (PP) exhibits many beneficial properties such as low density high thermal stability, chemical resistance, good processability and recyclability. However, only limited research has been done on expanded polypropylene (EPP). In this study, we were trying to prepare EPP with chemical blowing agent. Ethylene-octene copolymer (mPE) was melt blended with PP to enhance melt fluidity of PP at processing temperature and to make more flexible foamed material. Prior to foaming, phase morphology of PP/mPE blends were investigated to examine the effect of phase morphology on the foaming ratio and cell structure of foams. Phase morphology of PP/mPE blends were affected by the content of mPE and mixing torque ratio. At the same composition, it was affected by mixing rpm. High blowing ratio and stable cell structure were obtained in the blend which has the continuous PP matrix with dispersed droplets of mPE.

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Development of Variable Deposition Manufacturing for Ethylene Vinyl Acetatecopolymer (EVA를 이용한 가변 용착 쾌속 조형 공정 개발)

  • 이상호;신보성;정준호;안동규;양동열
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2000.05a
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    • pp.771-774
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    • 2000
  • RP techniques have inherent disadvantages caused by their working principles: stair-stepped surface of parts due to layer-by-layer stacking of layers, low build speed caused by line-by-line solidification to finish one layer, and post processing to improve surface finish, etc. The objective of this study is to propose a new RP technique, variable deposition manufacturing (VDM), which can make up for the disadvantages of the existing RP techniques, and to develop an apparatus to implement the technique. The proposed process can greatly reduce the building time and improve the surface finish of parts generated. The experiments are carried out to obtain the range of temperature of molten material to maintain its fluidity and to investigate the effect of gas cooling on the preservation of the slopes. Based on the results, some simple shapes such as a line-shape. an S-shape, and a circle-shape were fabricated from Ethylene Vinyl Acetatecopolymer (EVA). In order to examine the applicability of VDM to more general shapes, a tensile specimen and a yo-yo shape were manufactured by the proposed RP method using EVA material as the first trial approach. The present basic study has shown the possibility of a practicable utilization of the proposed VDM process to prototyping of a general three-dimensional shape.

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An Experimental Study on the Effect of Reduced Slag and Gypsum on Concrete at Low Temperature(-5℃) (저온(-5℃)에서의 환원슬래그 및 석고가 콘크리트에 미치는 영향에 관한 실험적 연구)

  • Kim, Hyeong-Cheol;Choi, Hyun-Kuk;Min, Tae-Beom;An, Dong-Hee;Choi, Si-Hyun;Lee, Han-Seung
    • Journal of the Korea Institute of Building Construction
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    • v.17 no.3
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    • pp.279-285
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    • 2017
  • In this study, the development of concrete preventing initial frost damage and durability about that were evaluated by using anti-aging agent and admixture(reduced slag). As a result of experiment, initial hydration heat was increased by $C_{12}A_7$ of reduced slag components but it was not effective to development of strength. Also fluidity decreased with increasing replacement of reduced slag. This suggested that fluidity was low by rapid setting due to absent of gypsum in reduced slag components. In case of CR2G specimen that added 4% gypsum, the flow ability was higher than plain. It is considered that concrete developed using reduced slag should use $SO_3$. Result of durability experiments, the durability decreased with increasing replacement amount of reduced slag.

Changes in Cell Membrane Fatty Acid Composition of Streptococcus thermophilus in Response to Gradually Increasing Heat Temperature

  • Min, Bonggyu;Kim, Kkotnim;Li, Vladimir;Cho, Seoae;Kim, Heebal
    • Journal of Microbiology and Biotechnology
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    • v.30 no.5
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    • pp.739-748
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    • 2020
  • In this study, a method of heat adaptation was implemented in an attempt to increase the upper thermal threshold of two Streptococcus thermophilus found in South Korea and identified the alterations in membrane fatty acid composition to adaptive response to heat. In order to develop heat tolerant lactic acid bacteria, heat treatment was continuously applied to bacteria by increasing temperature from 60℃ until the point that no surviving cell was detected. Our results indicated significant increase in heat tolerance of heat-adapted strains compared to the wild type (WT) strains. In particular, the survival ratio of basically low heat-tolerant strain increased even more. In addition, the strains with improved heat tolerance acquired cross protection, which improved their survival ratio in acid, bile salts and osmotic conditions. A relation between heat tolerance and membrane fatty acid composition was identified. As a result of heat adaptation, the ratio of unsaturated to saturated fatty acids (UFA/SFA) and C18:1 relative concentration were decreased. C6:0 in only heat-adapted strains and C22:0 in only the naturally high heat tolerant strain were detected. These results support the hypothesis, that the consequent increase of SFA ratio is a cellular response to environmental stresses such as high temperatures, and it is able to protect the cells from acid, bile salts and osmotic conditions via cross protection. This study demonstrated that the increase in heat tolerance can be utilized as a mean to improve bacterial tolerance against various environmental stresses.

Highly filled AIN/epoxy composites for microelectronic encapsulation (반도체 봉지용 고충진 AIN/Epoxy 복합재료)

  • 배종우;김원호;황영훈
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2000.04a
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    • pp.131-134
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    • 2000
  • Increased temperature adversely affects the reliability of a device. So, package material should have high thermal diffusion, i.e., high thermal conductivity. And, there are several other physical properties of polymeric materials that are important to microelectronics packaging, some of which are a low dielectric constant, a low coefficient of thermal expansion (CTE), and a high flexural strength. In this study, to get practical maximum packing fraction of AIN (granular type) filled EMC, the properties such as the spiral flow, thermal conductivity, CTE, and water resistance of AIN-filled EMC (65-vol%) were evaluated according to the size of AIN and the filler-size distribution. Also, physical properties of AIN filled EMC above 65-vol% were evaluated according to increasing AIN content at the point of maximum packing fraction (highly loading condition). The high loading conditions of EMC were set $D_L/D_S$=12 and $X_S$=0.25 like as filler of sphere shape and the AIN filled EMC in this conditions can be obtained satisfactory fluidity up to 70-vol%. As a result, the AIN filled EMC (70-vol%) at high loading condition showed improved thermal conductivity (about 6 W/m-K), dielectric constant (2.0~3.0), CTE(less than 14 ppm/$^{\circ}C$) and water resistance. So, the AIN filled EMC (70-vol%) at high loading condition meets the requirement fur advanced microelectronic packaging materials.

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A Study on the Fundamental Properties of Ultra Rapid Hardening Mortar using Coal-Ash (잔골재 대체재로서 석탄회를 이용한 초속경 보수모르타르의 기초적 특성에 관한 연구)

  • Lee, Gun-Cheol;Oh, Dong-Uk;Kim, Young-Geun;Cho, Chung-Ki
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.6 no.1
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    • pp.128-135
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    • 2011
  • In this study, in order to develop ultra rapid hardening mortar(URHM) for tunnel repairs using bottom ash of low recycle ratio and Admixture as Eco concept, fundamental properties of URHM on temperature condition of construction field were performed. Test result, URHM of three types for fluidity and setting time were as in the following : B > C > A. Those for low temperatures were later than the standard condition. Compressive, bending and bond strength were similar with three types as follow. In compressive strength, initial strength of the low were smaller than the standard but the low in the long-term were similar with the standard. On the contrary to this, bending strength were similar in initial strength but the low in the long-term were smaller than the standard. The low in bond strength was average 35% less than the standard. Length changes was as in the following : A > C > B. the low is two times much as the standard but the case using blast furnace slag particles noticeably reduced length changes. Water absorption coefficient and water vapor resistance were as in the following : C > A > B. In case of URHM added bottom ash, water absorption coefficient and water vapor resistance were increased because bottom ash is porous material.

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In vitro Effect of High Osmolality on Plasma Membrane Activities in the Spermatozoa (In Vitro 고삼투압이 정자 원형질막의 Protein Tyrosine Phosphorylation에 미치는 영향)

  • 오영근;장재호;최인호;정노팔;신형철;곽병주
    • Biomedical Science Letters
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    • v.6 no.4
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    • pp.237-244
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    • 2000
  • It has been reported that plasma membrane activity of the spermatozoa may be susceptible to be influenced by extracellular osmolality and such membranous changes involve infracellular molecular changes, special regard to the structure of membranous lipids, and the accompanying ion-channel of which are closely related with their fluidity of $Ca^{2+}$ and HCO$^{-}_{3}$. It is of common recognition that a certain kind of sterol acceptor player an important to induce lipid fluctuation of the sperm plasma membrane which have been influenced by BSA administration and came in effect to outflow of cholesterol from the spermatozoa and resulted in changes of ionic fluidity to facilitate adenylyl cyclase, and to induce protein tyrosine phosphorylation by increase of cAMP and activation of PKA. Thus it seems likely that an augmentation of the acrosomal reaction is closely related with protein tyrosine phosphorylation. The following experimental results were obtained in the present study; Under the high osmolality conditions, the spermatozoa motility declined significantly and the structural change of the plasma membrane diminished to confirm that the response degrees to the osmolality depended upon the water transfer volume through the plasma membrane and the changes of cellular volume. Those experimental results suggest that a physiological parameter such as low temperature condition played an important role for presentation of spermatozoa and that inducement of spermatozoa activation for reinforcement of protein tyrosine phosphorylation. On the other hand, it seemed likely that the BSA administration as one of sterol accepters might represent a key role also under the high osmolality condition and their result also suggests that osmolality change, special regard to high osmolality condition may play an important role also in the processes of signal transmission.

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