• Title/Summary/Keyword: low porosity

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Site Investigation for Pilot Scale $CO_2$ Sequestration by Magnetotelluric Surveys in Uiseong, Korea (이산화탄소 지중저장 Pilot 부지 선정을 위한 의성지역 MT 탐사)

  • Lee, Tae-Jong;Han, Nu-Ree;Ko, Kwang-Beom;Hwang, Se-Ho;Park, Kwon-Gyu;Kim, Hyung-Chan;Park, Yong-Chan
    • Geophysics and Geophysical Exploration
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    • v.12 no.4
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    • pp.299-308
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    • 2009
  • A magentotelluric (MT) survey at the Uiseong area has been performed for the site investigation of pilot scale $CO_2$ sequestration. The purpose of the MT survey is to delineate deeply extended fracture systems that can act as a leakage path of injected $CO_2$ Plume. Since the target area is extremely noisy in electromagentic sense, low frequency data below 1 Hz cannot be used for inversion. Two- and three-dimensional interpretation of the MT data showed a very clear conductive anomaly, which has the direction of $N55\sim65^{\circ}W$ and is extended roughly down to 1.6 km. It have the same direction with the strike-slip faults, the Gaeum and Geumcheon Faults. On the contrary, the eastern part of the survey area shows relatively homogeneous to the depth of 2 km though some small fractures at shallow depths can be found. Test drilling and high-definition borehole surveys should be followed at the eastern part of the survey area and hydraulic fracturing is required for injection of $CO_2$, because mean porosity of the sedimetary rock in the area is only 1.47%.

The Effect of Popped Rice Hulls Compost Application on Soil Chemical and Physical Properties in Fluvio-marine plain paddy soils (퇴화염토지 논에서 팽화왕겨 퇴비시용이 토양이화학성에 미치는 영향)

  • Yoo, Chul-Hyun;Yang, Chang-Hyu;Kim, Taek-Kyum;Ryu, Jin-Hee;Kim, Byung-Su;Kim, Jae-Duk;Jung, Kwang-Yong
    • Korean Journal of Soil Science and Fertilizer
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    • v.39 no.6
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    • pp.403-408
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    • 2006
  • Fluvio-marine paddy soils in Korea consist of high silt content and have the hardpan located below 20~30 cm from surface soil. This properties cause poor rice rhizosphere conditions such as low permeability and porosity, high bulk density and hardness. The aims of this study was to investigate the effect of popped rice hulls compost(PRHC) on soil fertility changes in the Fluvio-marine plain paddy soils. Total nitrogen content and nitrogen mineralization rate of PRHC were 1.17 and 33.5, respectively, and its C/N ratio was 35.4. Application of PRHC increased the content of organic matter and exchangeable potassium and improved the bulk density and porosity. The content of $NH_4-N$ in soil was high in the PRHC plot until maximum tillering stage. An uptake amount of fertilized nitrogen was greater in standard fertilization plot at early growth stage, however, it was greater more in PRHC plots at the ripening period than in standard fertilization plot. Among the PRHC treated plots, uptake amount was the greatest in 50% PRHC plot during the all growth period. Nitrogen efficiencies were higher in PRHC plot during the all growth period. Rice yields in all PRHC plots were lower than in standard fertilization, however, the yield of 40% PRHC plot was similar with that of standard.

Strength Characteristics of Sedimentary Rock in Daegu-Gyungbuk Area Followed by Saturation and Crack Initiation (대구경북지역 퇴적암의 포화 및 균열 유발에 따른 강도 특성)

  • Park, Sung-Sik;Kim, Seong-Heon;Bae, Do-Han
    • Journal of the Korean Geotechnical Society
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    • v.34 no.12
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    • pp.29-42
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    • 2018
  • Shale and mudstone in Daegu-Gyungbuk area have low strength and resistance to weathering compared to other rocks. Therefore, it is necessary to evaluate their strength depending on the degree of saturation and crack development. In this study, shales and mudstones were collected from several construction sites in Daegu-Gyungbuk area. Their basic material properties such as porosity, SEM, chemical component, and durability were tested. A porosity (absorptivity) of mudstone was 31% (25%), which was 6 (8) times higher than that of shale. Some mudstone was easily disintegrated with water and it consisted of highly-active clay mineral such as smectite type. These rocks were prepared by small cube specimens for unconfined compression test. An unconfined compressive strength of dry rock was compared with saturated one. Microwave oven was operated step by step to stimulate void water within a saturated rock, which resulted into high temperature and micro crack initiation within rocks. A strength of microwaved rocks was compared with operation time and crack initiation. As a result, the average unconfined compressive strength of dry and saturated shale was 62 and 33 MPa, respectively. The strength of mudstone for each condition was 11 and 4 MPa. When a rock became saturated, its strength decreased by 47% and 64% for shale and mudstone at average. In addition to saturation, a rock was in the microwave for 15 secs, its strength decreased into 49% for shale and 52% for mudstone. When a microwave oven operated up to 20 sec, a rock was crushed into several pieces and its temperature was approximately 200 degrees.

Polyurea Cross-linked Silica Aerogel with Improved Mechanical Strength by Applying a Precursor Having a Plurality of Amino Groups (복수의 아민기를 가지는 전구체를 적용하여 기계적 강도를 향상시킨 폴리우레아 가교 실리카 에어로겔)

  • Lee, Wonjun;Kim, Taehee;Choi, Haryeong;Kim, Jiseung;Lee, Hong-Sub
    • Journal of the Microelectronics and Packaging Society
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    • v.29 no.4
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    • pp.15-20
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    • 2022
  • Aerogel is a material having a nanopore structure based on a high porosity. Due to this high porosity, it has excellent properties not found in conventional materials, but its application has been limited due to low mechanical strength. Therefore, to improve the mechanical strength of the aerogel, polyurea crosslinking was introduced and a precursor having an amine group essential for polyurea polymer formation was selected to synthesize a polyurea crosslinked aerogel composite. In addition, the crosslinking of polyurea was adjusted according to the number of amine groups present in aminosilane. It was confirmed through various analyses that the nanopore structure of the aerogel was maintained to have mesopores. The aerogel thus formed was able to improve the mechanical strength by about two times, and it was confirmed through field emission scanning electron microscope analysis that a one-dimensional polymer was formed on the silica aerogel surface through the introduction of ethylene diamine. The one-dimensional polymer thus formed has improved mechanical properties, resulting in securing an elastic modulus of about 2.66 MPa.

Effect of Processing Parameters on the Densification of Carbon/Carbon Composite by Isothermal Low-Pressure Chemical Vapor Infiltration (등온 저압화학기상침투법에 의한 탄소/탄소 복합재료의 치밀화에 대한 제조공정변수의 영향)

  • Park, H.D.;Ahn, C.W.;Cho, K.;Yoon, B.Y.;Kim, K.S.
    • Korean Journal of Materials Research
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    • v.4 no.3
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    • pp.259-267
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    • 1994
  • The effect of processing parameters, temperature, gas concentration, gas flow rate and pressure, were studied on the densification of carbon/carbon composites using a Robust design method in isothermal low-pressure chemical vapor infiltration with a gas system of $C_3H_8-N_2$ After one time of isothermal low-pressure chemical vapor infiltrat.ion, the bulk density of carbon/carbon composites in creased up to 1-9% and apparent porosity of the composites decreased down to 20-50%. ANOVA analysis of the experiment.al data revealed that the important parameters of isothermal lowpressure chemical vapor infiltration were temperature, gas concentration and gas flnw rate. 'There was almost no ~ f f e c t on densification by pressure and interaction between each parameters. In t, he present experimental conditions, the highest bulk density was obtained at $1100^{\circ}C$ temperature, 100% $C_3H_8$, concentration, 100 SCCM flow rate and 5 torr pressure.

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Effect of Changes in Condition of Ammonia Gas Addition on the Surface Layer Microstructure and Porosity during Austenitic Nitriding of Low Carbon Steels (저 탄소강의 오스테나이트 질화 시 암모니아 가스첨가 조건변화가 표면층 조직 및 기공변화에 미치는 영향)

  • Lee, Jewon;Roh, Y.S.;Sung, J.H.;Lim, S.G.
    • Journal of the Korean Society for Heat Treatment
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    • v.32 no.5
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    • pp.201-211
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    • 2019
  • Low carbon steel (S20C steel) and SPCC steel sheet have been austenitic nitrided at $700^{\circ}C$ in a closed pit type furnace by changing the flow rate of ammonia gas and heat treating time. When the flow rate of ammonia gas was low, the concentration of residual ammonia appeared low and the hardness value of transformed surface layer was high. The depth of the surface layer, however, was shallow. With increasing the concentration of residual ammonia by raising up the ammonia gas flow, both the depth of the surface layer and the pore depth increased, while the maximum hardness of the surface layer decreased. By introducing a large amount of ammonia gas in a short time, a deep surface layer with minimal pores on the outermost surface was obtained. In this experiment, while maintaining 10~12% of residual ammonia, the flow rate of inlet ammonia gas, 7 liter/min, was introduced at $700^{\circ}C$ for 1 hour. In this condition, the thickness of the surface layer without pores appeared about $60{\mu}m$ in S20C steel and $30{\mu}m$ in SPCC steel plate. Injecting additional methane gas (carburizing gas) to this condition played a deteriorating effect due to promoting the formation of vertical pores in the surface layer. For $1^{st}$ transformed surface layer for S20C steel, maintaining 10~12% residual ammonia condition via austenitic nitriding process resulted in ${\varepsilon}$ phase with relatively high nitrogen concentration (just below 4.23 wt.%N) among the mixed phases of ${\varepsilon}+{\gamma}$. The ${\varepsilon}$ phase was formed a specific orientation perpendicular to the surface. For $2^{nd}$ transformed layer for S20C steel, ${\gamma}$ phase was rather dominant (just above 2.63 wt.%N). For SPCC steel sheet, there appeared three phases, ${\gamma}$, ${\alpha}(M)$ and weak ${\varepsilon}$ phase. The nitrogen concentration would be approximately 2.6 wt.% in these phases condition.

Interpretation of Limestone Provenance, Materials and Making Characteristics for Lime-Soil Mixture on Tomb Barrier of the Yesan Mokri Site in Joseon Dynasty (조선시대 예산 목리유적 회격묘의 재질 및 제작특성과 석회의 산지 해석)

  • Lee, Chan Hee;Cho, Ji Hyun;Kim, Jiyoung
    • Journal of Conservation Science
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    • v.32 no.4
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    • pp.471-490
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    • 2016
  • This study investigated provenance of raw materials and making technique of lime-based materials used in the tomb barriers of the Yesan Mokri tombs from Joseon dynasty on the basis of analysis to material characteristics and physical properties. In the barrier materials, dry density and porosity are the highest value ($1.82g/cm^3$) and the lowest value (25.20%) in the south wall of No. 1 tomb, respectively. Dry density and porosity are inversely proportional in all barrier materials, but unconfined compressive strength, which is the highest value of $182.36kg/cm^2$ in the No. 2 tomb, does not show an interrelation with porosity and density. Mineral components in the lime-soil mixtures of the tomb barrier are mainly quartz, feldspar, mica and calcite about 200 to $600{\mu}m$ size with yellowish brown matrix. Hydrotalcite and portlandite are detected in the lime mixture, and kaolinite in the soils. The lime materials of the tomb barrier occurred in large quantities weight loss and variable endothermic peaks caused by decarbonization reaction of $CaCO_3$ in the range from 600 to $800^{\circ}C$ in thermal analysis. Making temperature of lime for the tomb barrier is presumed approximately about $800^{\circ}C$ based on the occurrences, compositions and thermal analysis. The tomb barriers are revealed to very wide composition ranges of major elements and loss-on-ignition (22.5 to 33.6 wt.%) owing to mixture of the three materials (lime, sand and clay). It is interpreted that low quality construction technique was applied as the limes are very heterogeneous mixture with aggregates, and curing of the lime was poorly processed in the tomb barriers. Possible limestone sources are distributed in many areas around the Mokri site where limestone conformation and quarries for commercial production are found within Yesan and Hongseong areas. Therefore, we estimated that raw materials were possibly supplied from the local mines near the Mokri site.

Preparation of Low Density Ceramic Supporter from Fly Ash with Borax and Glass Powder (붕사 및 유리분말을 첨가한 석탄회로부터 저밀도 세라믹 담체의 제조)

  • Hwang, Yeon;Lee, Hyo-Sook;Lee, Woo-Chul;Bae, Kwang-Hyun;Jeong, Yong-Dae;Lee, Won-Kwon
    • Resources Recycling
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    • v.9 no.2
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    • pp.40-45
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    • 2000
  • Low density ceramic supporter was prepared by using fly ash as a starting mterial with borax or glass powders. Also the wheat powders were used by 30 wt% to increase the initial porosity of the supporter. The density of the supporter decreased as the amount of borax increased. The bulk density of $0.79g/\textrm{cm}^3$ and the apparent density of $1.10g/\textrm{cm}^3$ were obtained when the fly ash with 15% of borax was sintered at $1160^{\circ}C$ for 15 minutes. The density also decreased as the plate glass powders past through $212\mu\textrm{m}$ size were mixed. When the fly ash with 12% of glass powder was sintered at $1280^{\circ}C$ for 10 minutes, the bulk and apparent density were $0.90g/\textrm{cm}^3$ and $1.00g/\textrm{cm}^3$, respectively.

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An Analysis of Archaeological Chemistry on the Low-grade Celadons Excavated at Noksan dong, Busan in Korea (부산 녹산동 조질청자의 고고화학적 분석)

  • Nam, Kyung Min;Kim, Gyu-Ho
    • Journal of Conservation Science
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    • v.34 no.5
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    • pp.345-358
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    • 2018
  • The purpose of this study is to analyze the characteristics of low-grade 12th-century celadons, which were excavated from a kiln site in Noksan-dong, Busan. The physical and chemical properties of the body and the glaze are evaluated through scientific analyses. All the selected celadon shards have a similar body color, regardless of the kiln from which they originated. The celadon shards from 2 3 kilns are brighter than those from 4 5 kilns, and there are two saturations, namely gray and brown. The brightness of the glaze shows a high contribution of red and yellow. The porosity of the selected shards is 8.8% in the gray saturation and 16.1% in the brown saturation. The major chemical compositions of the body and glaze are in the typical chemical composition of the celadon, but the $TiO_2$ flux contents are different. The visible characteristic difference between the 2 3 kilns and the 4 5 kilns can be attributed to the mixing and the firing process rather than the raw materials used. The difference in the $Fe_2O_3$ and $K_2O$ flux between the 2 3 and 4 5 kilns can be attributed to changes in the ingredient combination during the process. In conclusion, Noksan-dong celadon could not be easier vitrification due to the manufacturing process that primary burning process, It is highly likely that there were process differences in kilns to produce high quality celadon.

Additive Effects on Sintering of Si/SiC Mixtures (Si/SiC 혼합물의 소결특성에 미치는 첨가제의 영향)

  • Kim, Soo Ryong;Kwon, Woo Teck;Kim, Younghee;Kim, Jong Il;Lee, Yoon Joo;Lee, Hyun Jae;Oh, Sea Cheon
    • Korean Journal of Materials Research
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    • v.22 no.12
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    • pp.701-705
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    • 2012
  • The effects of clay, aluminum hydroxide, and carbon powder on the sintering of a Si/SiC mixture from photovoltaic silicon-wafer production were investigated. Sintering temperature was fixed at $1,350^{\circ}C$ and the sintered bodies were characterized by SEM and XRD to analyze the microstructure and to measure the apparent porosity, absorptivity, and apparent density. The XRD peak intensity of SiC in the sintered body was increased by adding 5% carbon to the Si/SiC mixture. From this result, it is confirmed that Si in the Si/SiC mixture had reacted with the added carbon. Addition of aluminum hydroxide decreased the cristobalite phase and increased the stable mullite phase. The measurement of the physical properties indicates that adding carbon to the Si/SiC mixture enables us to obtain a dense sintered body that has high apparent density and low absorptivity. The sintered body produced from the Si/SiC mixture with aluminum hydroxide and carbon powder as sintering additives can be applied to diesel particulate filters or to heat storage materials, etc., since it possesses high thermal conductivity, and anticorrosion and antioxidation properties.