• 제목/요약/키워드: low porosity

검색결과 529건 처리시간 0.024초

Influence of the SPS heating rate on the optical and mechanical properties of Y2O3-MgO nanocomposites

  • Yong, Seok-Min;Choi, Doo Hyun;Lee, Kisu;Ko, Seok-Young;Cheong, Dong-Ik
    • Journal of Ceramic Processing Research
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    • 제20권1호
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    • pp.59-62
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    • 2019
  • Y2O3-MgO nanocomposites are promising materials for hypersonic infrared windows and domes due to their excellent midIR transmittance and mechanical properties. In this work, influence of SPS heating rate on the microstructure, IR transmittance, and mechanical properties of Y2O3-MgO nanocomposites was investigated. It was found that the average grain size decreases with a decreasing heating rate, which can be attributed to high defect concentration by rapid heating and deformation during densification. Also, the residual porosity decreases with a decreasing heating rate, which is ascribed to the enhancement of grain boundary diffusion by a large grain-boundary area (a small grain size). Consequently, high transmittance and hardness were attained by the low heating rate. On the other hand, the mechanical strength showed little difference with the heating rate change, which is somewhat different from the general knowledge on ceramics and will be discussed in this letter.

Experimental and numerical investigation of a surface-fixed horizontal porous wave barrier

  • Poguluri, Sunny Kumar;Kim, Jeongrok;George, Arun;Cho, I.H.
    • Ocean Systems Engineering
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    • 제11권1호
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    • pp.1-16
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    • 2021
  • Experimental and numerical investigations were conducted to study the performance of a surface-fixed horizontal porous wave barrier in regular waves. The characteristics of the reflection and transmission coefficients, energy dissipation, and vertical wave force were examined versus different porosities of the barrier. Numerical simulations based on 3D Reynolds Averaged Navier-Stokes equations with standard low-Re k-ε turbulent closure and volume of fluid approach were accomplished and compared with the experimental results conducted in a 2D wave tank. Experimental measurements and numerical simulations were shown to be in satisfactory agreement. The qualitative wave behavior propagating over a horizontal porous barrier such as wave run-up, wave breaking, air entrapment, jet flow, and vortex generation was reproduced by CFD computation. Through the discrete harmonic decomposition of the vertical wave force on a wave barrier, the nonlinear characteristics were revealed quantitatively. It was concluded that the surface-fixed horizontal barrier is more effective in dissipating wave energy in the short wave period region and more energy conversion was observed from the first harmonic to higher harmonics with the increase of porosity. The present numerical approach will provide a predictive tool for an accurate and efficient design of the surface-fixed horizontal porous wave barrier.

Comparative study on bearing characteristics of pervious concrete piles in silt and clay foundations

  • Cai, Jun;Du, Guangyin;Xia, Han;Sun, Changshen
    • Geomechanics and Engineering
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    • 제27권6호
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    • pp.595-604
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    • 2021
  • With the advantages of high permeability and strength, pervious concrete piles can be suitable for ground improvement with high water content and low bearing capacity. By comparing the strength and permeability of pervious concrete with different aggregate sizes (3-5 mm and 4-6 mm) and porosities (20%, 25%, 30% and 35%), the recommended aggregate size (3-5 mm) and porosity (30%) can be achieved. The model tests of the pervious concrete piles in soft soil (silt and clay) foundations were conducted to evaluate the bearing characteristics, results show that, for the higher consolidation efficiency of the silty foundation, the bearing capacity of the silty foundation is 16% higher, and the pile-soil stress ratio is smaller. But when it is the ultimate load for the piles, they will penetrate into the underlying layer, which reduces the pile-soil stress ratios. With higher skin friction of the pile in the silty foundation, the pile penetration is smaller, so the decrease of the pile axial force can be less. For the difference in consolidation efficiency, the skin friction of pile in silt is more affected by the effective stress of soil, while the skin friction of pile in clay is more affected by the lateral stress. When the load reaches 4400 N, the skin friction of the pile in the silty foundation is about 35% higher than that of the clay foundation.

A novel method for predicting the swelling potential of clay-bearing rocks

  • Moosavi, Mahdi;Ghadernejad, Saleh
    • Geomechanics and Engineering
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    • 제27권6호
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    • pp.615-626
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    • 2021
  • The main objective of this study is to present a fast and reliable approach to predict the swelling potential of clay-bearing rocks. Investigations showed that there is a good correlation between the swelling potential of a rock and its desire to absorb water due to its clay content which could be measured using the "Contact Angle" test as one of the most common ways to determine the wettability. In this test, the angle between a water drop and the flat rock surface on which it rests is measured. The present method is very fast and returns repeatable results and requires minimal sample preparation. Only having a saw-cut surface of a sample with any shape is all one needs to perform this test. The logic behind this approach is that the swelling potential of a rock is a function of its mineral content and molecular structure, which are not only distributed in the bulk of the sample but also reflected on its surface. Therefore, to evaluate swelling behavior, it is not necessary to wait for a sample to get wet all the way to its "internal structure" (which, due to the low permeability of clay-bearing rocks, is very slow and time-consuming). Instead, one can have a good sense of swelling potential by studying its surface. Parametric studies on the effect of moisture content, porosity, and surface roughness on the contact angle measurements showed that using a saw-cut oven-dried sample is a convenient way to evaluate the swelling potential by this method.

소결첨가재에 의한 텅스텐의 기계적 특성평가 (Evaluation on Mechanical Properties of Tungsten by Sintering Additive Content)

  • 이상필;이진경
    • 한국산업융합학회 논문집
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    • 제25권4_2호
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    • pp.621-626
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    • 2022
  • Tungsten is a high melting point metal unlike other steel materials, and it is difficult to manufacture because of its high melting temperature. In this study, pressure sintering process method was applied to manufacture the tungsten materials at low temperature. Therefore, it is necessary to densify the sintered material by using a sintering additive. Studies have been conducted on how the amount of titanium for sintering tungsten affects the mechanical properties of tungsten in this study. In order to secure the densification mechanism of tungsten powder during the sintering process, the characteristics of the sintered tungsten material according to the change of titanium content were evaluated. It was investigated the relationship between sintering parameters and mechanical properties for densification of microstructures. The sintered tungsten materials according to sintering additive content showed high sintered density (about 16.31g/cm3) and flexural strength (about 584 MPa) when the content of sintering additive was 3 wt%. However, as the content of the sintering additive increases, mechanical property of flexural strength is decreased, and the porosity is increased due to the heterogeneous sintering around titanium.

2D-Covalent organic frameworks for bioimaging and therapeutic applications

  • Chanho Park;Dong Wook Kim
    • 대한방사성의약품학회지
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    • 제6권2호
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    • pp.171-176
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    • 2020
  • Covalent organic frameworks (COFs) are porous crystalline polymers in which organic units are linked by covalent bonds and have a regular arrangement at the atomic level. Recently, the COFs have been much attention in bio-medical area such as bio-imaging, drug delivery, and therapeutics. These 2D nanoparticles are proving their value in nanomedicine due to their large surface area, functionalization through functional groups exposed on the surface, chemical stability due to covalent bonding, and high biocompatibility. The high ω-electron density and crystallinity of COFs makes it a promising candidate for bioimaging probes, and its porosity and large surface area make it possible to be utilized as a drug delivery vehicle. However, the low dispersibility in water, the cytotoxicity problems of COFs are still challenged to be solved in the future. In this regard, several efforts that increase the degree of dispersion through functionalization on the surface of COFs for the application to the biomedical field have been reported. In this review, we would like to describe the advantages and limitations of COFs for bio-imaging and anti-cancer treatment.

CO2 고정화된 CFBC 석탄재를 활용한 저강도 고유동 채움재의 특성평가 (Characterization of Controlled Low-Strength Materials Utilizing CO2-Solidified CFBC Coal Ash)

  • 조용광;남성영;이용무;김춘식;서신석;조성현;이형우;안지환
    • 한국환경과학회지
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    • 제26권11호
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    • pp.1267-1274
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    • 2017
  • A Controlled Low-Strength Materials (CLSM) is suitable for mine backfilling because it does not require compaction owing to it high fluidity and can be installed quickly. Therefore, a CLSM utilizing $CO_2$-solidified Circulating Fluidzed Bed Combustion (CFBC) coal ash was developed and it's properties were investigated, since. $CO_2$-solidification of CFBC coal ash can inhibit exudation of heavy metals. The chemical composition and specific surface area of Pulverized coal Combustion fly ash and CFBC fly ash were analyzed. The water ratio, compressive strength and length change ratio of CLSM were confirmed. The water ratios differed with the specific surface area of the CLSM. It was confirmed that the porosity of CLSM affected its compressive strength and length change ratio.

도전성 ${\beta}-SiC-TiB_2$ 복합체의 특성 (Properties of Electro-Conductive SiC-TiB2 Composites)

  • 신용덕;박미림;송준태;임승혁
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2000년도 춘계학술대회 논문집 전자세라믹스 센서 및 박막재료 반도체재료 일렉트렛트 및 응용기술
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    • pp.72-75
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    • 2000
  • The effect of $Al_2O_3+Y_2O_3$ additives on fracture toughness of ${\beta}-SiC-TiB_2$ composites by hot-pressed sintering were investigated, The ${\beta}-SiC-TiB_2$ ceramic composites were hot-presse sintered and annealed by adding 4, 8, 12wt% $Al_2O_3+Y_2O_3$(6 : 4wt%) powder as a liquid forming additives at low temperature($1800^{\circ}C$) for 4h. In this microstructures, the relative density is over 97% of the theoretical density and the porosity increased with increasing $Al_2O_3+Y_2O_3$ contents because of the increasing tendency of pore formation. But the fracture toughness showed the highest of $7.0MPa{\cdot}m^{1/2}$ for composites added with 12wt% $Al_2O_3+Y_2O_3$ additives at room temperature. The electrical resistivity showed the lowest of $1.59\times10^{-3}\Omega{\cdot}cm$ for composite added with 8wt% $Al_2O_3+Y_2O_3$ additives at room temperature and is all positive temperature coefficient resistance(PTCR} against temperature up to $700^{\circ}C$.

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저온하에서의 온도 및 함수 조건에 따른 암석의 모드 I 파괴인성 측정 (Measurement of Mode I Fracture Toughness of Rocks with Temperature and Moisture Conditions at Low Temperature)

  • 정용복;박찬;신중호;이희근
    • 터널과지하공간
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    • 제11권4호
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    • pp.352-361
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    • 2001
  • 저온 냉각상태 및 냉각 후 상온 해빙 상태에서 암석의 모드 I 파괴인성을 BDT와 CCNBD시험편을 사용하여 구하였다. 실험 온도 범위는 상온($25^{\circ}C$)에서 -16$0^{\circ}C$로 설정하였으며 건조 및 포화된 화강암과 사암을 사용하여 파괴인성에 대한 공극수와 공극률의 영향 정도를 조사하고자 하였다. 또한 냉각 과정에서 발생할 수 있는 열균열을 조사하기 위해서 SEM 이미지 분석도 실시하였다. 냉각된 암석의 파괴인성은 온도가 하강함에 따라 증가하였다. 이러한 증가경향은 포화시료에서 더 크게 나타났으며, 포화 시료의 경우 화강암의 증가율이 사암에 비해 크게 나타났다. 냉각 후 상온 해빙 상태에서 구한 파괴인성의 경우, 냉각을 거 치지 않은 상온 상태의 파괴인성 값의 15% 이내에서 결정되었다. 냉각-해빙을 거친 시료에 대한 SEM 분석결과 화강암의 경우 조암광물간의 열팽창 차이에 의한 열균열을 확인할 수 있었으며 냉각온도가 낮을수록 균열밀도가 증가하였다.

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냉간금형용 합금공구강 분말 및 적층조형체의 미세조직 (Microstructures of Powders and Additively Manufactured Objects of an Alloy Tool Steel for Cold-Work Dies)

  • 강전연;윤재철;김호영;김병환;최중호;양상선;유지훈;김용진
    • 한국분말재료학회지
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    • 제24권3호
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    • pp.202-209
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    • 2017
  • A cold-work tool steel powder is used to fabricate 3-dimensional objects by selective laser melting using a high-pressure gas atomization process. The spherical powder particles form continuous carbide networks among the austenite matrix and its decomposition products. The carbides comprise Nb-rich MC and Mo-rich $M_2C$. In the SLM process, the process parameters such as the laser power (90 W), layer thickness ($25{\mu}m$), and hatch spacing ($80{\mu}m$) are kept fixed, while the scan speed is changed from 50 mm/s to 4000 mm/s. At a low scan speed of 50 mm/s, spherical cavities develop due to over melting, while they are substantially reduced on increasing the speed to 2000 mm/s. The carbide network spacing decreases with increasing speed. At an excessively high speed of 4000 mm/s, long and irregularly shaped cavities are developed due to incomplete melting. The influence of the scan pattern is examined, for which $1{\times}1 mm^2$ blocks constituting a processing layer are irradiated in a random sequence. This island-type pattern exhibits the same effect as that of a low scan speed. Post processing of an object using hot isostatic pressing leads to a great reduction in the porosity but causes coarsening of the microstructure.