• Title/Summary/Keyword: low porosity

Search Result 533, Processing Time 0.025 seconds

The Effect of Processing Variables and Composition on the Nitridation Behavior of Silicon Powder Compact

  • Park, Young-Jo;Lim, Hyung-Woo;Choi, Eugene;Kim, Hai-Doo
    • Journal of the Korean Ceramic Society
    • /
    • v.43 no.8 s.291
    • /
    • pp.472-478
    • /
    • 2006
  • The effect of compositional and processing variables on a nitriding reaction of silicon powder compact and subsequent post sintering of RBSN (Reaction-Bonded Silicon Nitride) was investigated. The addition of a nitriding agent enhanced nitridation rate substantially at low temperatures, while the formation of a liquid phase between the nitriding agent and the sintering additives at a high temperature caused a negative catalyst effect resulting in a decreased nitridation rate. A liquid phase formed by solely an additive, however, was found to have no effect on nitridation for the additive amount used in this research. The original site of a decomposing pore former was loosely filled by a reaction product ($Si_3N_4$), which provided a specimen with nitriding gas passage. For SRBSN (Sintered RBSN) specimens of high porosity, only a marginal dimensional change was measured after post sintering. Its engineering implication for near-net shaping ability is discussed.

Electrochemical Evaluation of Si-Incorporated Diamond-Like Carbon (DLC) Coatings Deposited on STS 316L and Ti Alloy for Biomedical Applications

  • Kim, Jung-Gu;Lee, Kwang-Ryeol;Kim, Young-Sik;Hwang, Woon-Suk
    • Corrosion Science and Technology
    • /
    • v.6 no.1
    • /
    • pp.18-23
    • /
    • 2007
  • DLC coatings have been deposited onto substrate of STS 316L and Ti alloy using r.f. PACVD (plasma-assisted chemical vapor deposition) with a mixture of $C_{6}H_{6}$ and $SiH_{4}$ as the process gases. Corrosion performance of DLC coatings was investigated by electrochemical techniques (potentiodynamic polarization test and electrochemical impedance spectroscopy) and surface analysis (scanning electron microscopy). The electrolyte used in this test was a 0.89% NaCl solution of pH 7.4 at temperature $37^{\circ}C$. The porosity and protective efficiency of DLC coatings were obtained using potentiodynamic polarization test. Moreover, the delamination area and volume fraction of water uptake of DLC coatings as a function of immersion time were calculated using electrochemical impedance spectroscopy. This study provides the reliable and quantitative data for assessment of the effect of substrate on corrosion performance of Si-DLC coatings. The results showed that Si-DLC coating on Ti alloy could improve corrosion resistance more than that on STS 316L in the simulated body fluid environment. This could be attributed to the formation of a dense and low-porosity coating, which impedes the penetration of water and ions.

Characteristics and Microstructure of Matrix Retaining Electrolyte in Phosphoric Acid Fuel Cell Prepared by Tape Casting (Tape Casting법으로 제조한 인산형 연료전지 전해질 매트릭스의 미세구조 및 특성)

  • 윤기현;허재호;장재혁;김창수
    • Journal of the Korean Ceramic Society
    • /
    • v.31 no.4
    • /
    • pp.375-380
    • /
    • 1994
  • Matrices retaining electrolyte in phosphoric acid fuel cell were prepared with SiC to SiC whisker mixing ratios of 1:0.5, 1:1, 1:1.5, 1:2, 1:3 by tape casting method. When viscosity of the slurry was 5.9 poise and the SiC to SiC whisker mixing ratios were 1:1, 1:1.5, 1:2, the ranges of porosity, acid absorbency and bubble pressure were 80~90%, 2.5~6 and 700~2200 mmH2O, respectively. Those ranges are acceptable for a practical electrolyte-retaining matrix. With increasing the mixing ratio of SiC whisker to SiC, the porosity and the vol.% of large pores in the main pore size distribution which is between 1 and 10 ${\mu}{\textrm}{m}$, increased rapidly. Impedance spectroscopy was measured to know characteristics of matrix inside and contact region of matrix to catalyst layer. When the SiC to SiC whisker mixing ratio was 1:2, hydrogen ions were transported in the matrix most effectively because of high ionic conductivity and low activation energy due to high acid absorbency in spite of high interfacial resistance. The cell current density of the cell made using the matrix was 220 mA/$\textrm{cm}^2$ at 0.7 V.

  • PDF

DETAILED EXAMINATION OF INVERSE-ANALYSIS PARAMETERS FOR PARTICLE TRAPPING IN SINGLE CHANNEL DIESEL PARTICULATE FILTER

  • Jung, S.C.;Park, J.S.;Yoon, W.S.
    • International Journal of Automotive Technology
    • /
    • v.8 no.2
    • /
    • pp.165-177
    • /
    • 2007
  • Predictions of diesel particulate filtration are typically made by modeling of a particle collection, and providing particle trapping levels in terms of a pressure drop. In the present study, a series of single channel diesel particulate filter (DPF) experiments are conducted, the pressure traces are inversely analyzed and essential filtration parameters are deducted for model closure. A DPF filtration model is formulated with a non-linear description of soot cake regression. Dependence of soot cake porosity, packing density, permeability, and soot density in filter walls on convective-diffusive particle transportation is examined. Sensitivity analysis was conducted on model parameters, relevant to the mode of transition. Soot cake porosity and soot packing density show low degrees of dispersion with respect to the Peclet number and have asymptotes at 0.97 and $70\;kg/m^3$, respectively, at high Peclet number. Soot density in the filter wall, which is inversely proportional to filter wall Peclet number, controls the filtration mode transition but exerts no influence on termination pressure drop. The percolation constant greatly alters the extent of pressure drop, but is insensitive to volumetric flow rate or temperature of exhaust gas at fixed operation mode.

A study on the Continuous Elimination of Inclusions in Al Alloy by Electromagnetic Force (전자기력을 이용한 알루미늄 합금중 개재물의 연속적 제거에 관한 연구)

  • Yoon, Eui-Pak
    • Journal of Korea Foundry Society
    • /
    • v.22 no.3
    • /
    • pp.130-136
    • /
    • 2002
  • The growing use of aluminum for castings over the past decade has brought with it the increased scrutiny of component properties. One area that has received much attention is the effect of in inclusions - or impurities particles held in the metal - on casting properties. A new method of electromagnetic separation for removal of inclusions in aluminum alloy melts is proposed. The principle is that as the electromagnetic force induced in metal acts on inclusions due to low electric conductivity, they are moved to the direction opposite to electromagnetic force and can be separated and removed from the melt. Experiments were carried out on A356 melt mixed alumina particles and commercial Al alloys of ADC 10 and 12. In the experiment using A356, it was proved that $Al_2O_3$ particles was separated and removed continuously from matrix melt by electromagnetic force. Based on these results, the continuous separation experiment that used ADC 10, 12 was carried and the cleanliness of melt was assessed by the amount of porosity, hydrogen contents, PoDFA and mechanical properties through tensile test. As the results of analyses, the amount of porosity and hydrogen contents decreased without variation of chemical composition in the specimen that passed the electromagnetic continuous separator. In addition, tensile strength and elongation of this specimen increased by $20{\sim}30%$ because of reduction of inclusions.

A Study on the Creation of Porosity in Al Alloy(AA2014) Large Rod Preforms by Spray Forming (분무성형법에 의한 Al 합금(AA2014) 대형봉상성형체 제조시 기공발생에 관한 연구)

  • Shin, Don-Soo;Yoon, Eui-Park
    • Journal of Korea Foundry Society
    • /
    • v.17 no.5
    • /
    • pp.494-501
    • /
    • 1997
  • In order to manufacture large rod preforms of 2014 Al alloy with a good mechanical property by spray forming method, it was spray-formed at a droplet temperature of $715^{\circ}C$, a droplet flight distance of 400mm, and a spraying angle of $35^{\circ}$. The rod preforms were extruded at $397^{\circ}C$ with the die temperature of $420^{\circ}C$ under the hot extrusion ratio 21:1 and T6 heat treatment was performed. The 2014 Al alloys cast by hot top process were also extruded and heat-treated at the same condition as a reference material. Microstructural observation and tensile test were carried out to investigate the effects of extrusion on microstructure and mechanical property of spray-formed Al alloy. Spray-formed Al alloys had many porosities due to inappropriate process conditions such as long droplet flight distance and low droplet temperature but have fine equiaxed grain. These porosities were reduced with decreasing in grain size by hot extrusion. Ultimate tensile strength and yield strength of spray formed-extruded 2014 Al alloy were inferior to those of the normal cast-extruded 2014 Al alloy, but elongations were superior. The control of porosity was important to get spray formed preform with a good mechanical property.

  • PDF

Effects of Strain Rate and Water Saturation on the Tensile Strength of Rocks (변형률 속도 및 수분포화가 암석의 인장강도에 미치는 영향)

  • Jung, Woo-Jin
    • Tunnel and Underground Space
    • /
    • v.20 no.2
    • /
    • pp.119-124
    • /
    • 2010
  • Hopkinson's effect tests were carried out for various strain rates on three different types of rock in both saturated and dry states in order to examine the effects of strain rate and water saturation on tensile strength. The tensile strength increased with the increase of the strain rate not only in dry state but also in saturated state. It was also especially recognizable that the dynamic tensile strength of rock in the dry state was proportional to approximately a one-third multiple of strain rate no matter what the type of rock. It was found that water saturation decreased tensile strength in the dry state of sandstone and tuff, both with high porosity, but no significant difference could be recognized between the dry and the saturated states of granite, which has a low porosity of 0.49%.

Cellular Automaton Models Revealing Effects of Initial Bacterial Distribution on Biofilm Growth (생물막 성장에 대한 세균의 초기 분포영향을 나타내는 셀룰라오토마톤 모델)

  • Lee, Sang-Hee;Choi, Kyung-Hee;Chon, Tae-Soo
    • Korean Journal of Ecology and Environment
    • /
    • v.37 no.3 s.108
    • /
    • pp.297-303
    • /
    • 2004
  • Two dimensional cellular automaton (CA) models were developed to investigate growth of biofilms in aquatic ecosystems. Simple local rules on CA were applied to governing growth of bacterial populations in relation to different nutrient concentrations. Initial bacterial distribution played an important role in determining population size and morphology of biofilm at low concentrations of nutrition. With clumped distribution, population size increased slowly compared with uniform and random distributions, while the porosity tented to be higher with uniform distribution compared with other initial distributions.

Process Development of Red Ginseng Production by Microwave-assisted Low Temperature Vacuum Dry and Characteristics of Products (마이크로파 저온진공건조 기술을 이용한 홍삼제조공정 개발 및 제품특성에 관한 연구)

  • Lee, Sang-Ho;Ji, Joong-Gu
    • Journal of the Korean Applied Science and Technology
    • /
    • v.34 no.2
    • /
    • pp.305-314
    • /
    • 2017
  • The purpose of this study was to develop the high efficiency of ginseng by using microwave low temperature vacuum drying technology. In red ginseng manufacturing processes, the study results compared the hot-air drying red ginseng dried during 24hours in $60-70^{\circ}C$ and redried during 72hours in $40^{\circ}C$ after the steaming ginseng with the red ginseng dried in microwave low temperature vacuum dryer on condition that 900 watt, 2.45 MHz, 50 mmHg during 5 hours and redried during 2 hours on 750 mmHg after the steaming ginseng about observation of tissue, sensory evaluation and a change of ginsenoside and crude saponin content. As a result, the red ginseng in microwave low temperature vacuum was had high brightness, the surface turned into porosity tissue and added more flavor, decreased bitterness highly on the contrary increased sweetness at the same time that elevated the comprehensive preference. Moreover, In a short time, the content of ginsenosides $Rg_1$ and $Rb_1$ increased about sixfold, eightfold in one time zone but there were no wide difference in content of $Rg_3$ as compared to the hot-air drying red ginseng. Finally, content of crude saponin was increased widely at 10-20 minutes and stayed high crude saponin content consistently. Therefore, this result indicated that the red ginseng in microwave low temperature vacuum increased extraction yields of the ginsenosides and crude saponin through a change of porosity tissue and improved flavor and texture compare with the general hot air dried red ginseng in a short time. According to these results, that provided that could increase the preference about red ginseng.

[ $CO_2$ ] Laser Weldability and Formability of High Strength Steels for Tailored Blanks Applications (TWB용 고강도 박판 강재의 $CO_2$ 레이저 용접성 및 성형성)

  • Lee, Won-Beom;Park, Seong-Ho
    • Proceedings of the Korean Society for Technology of Plasticity Conference
    • /
    • 2004.05a
    • /
    • pp.365-372
    • /
    • 2004
  • The laser welding and its analysis were carried out using high power 6kW $CO_2$ laser for high strength steels such as DP, TRIP and conventional high strength steels. Bead on plate welding of thin sheet was examined to investigate the effect of weld variables of laser welding, and to obtain optimum welding condition. In order to investigate the formability of welded high strength steels, LDH test was added on this work. At high welding speed, the partial penetration was obtained by low heat input. Meanwhile, porosity was formed in the bead at low weld speed because of extremely higher heat input. The optimum welding condition of welding was derived from bead width, penetration and hardness property. It was shown that the DP steels had lower porosity level and smooth bead shape, therefore better laser weldability than TRIP steels and conventional high strength steels. In addition, LDH test shows that the welded DP steels have about $90\%$ formability value of base metal, although TRIP steel and conventional high strength steels have about $80\%$ formability value of its base metal.

  • PDF