• Korean Chemical Engineering Research
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• v.57 no.4
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• pp.539-546
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• 2019

Global warming has mentioned as one of the international problems and these researches have conducted. Carbon Capture, Utilization and Storage (CCUS) technology has improved due to increasing importance of reducing emission of carbon dioxide. Among of various CCUS technologies, mineral carbonation can converted $CO_2$ into high-cost materials with low energy. Existing researches has been used ions extracted solid wastes for mineral carbonation but the procedure is complicated. However, the procedure using seawater is simple because it contained high concentration of metal cation. This research is a basic study using seawater-based wastewater for mineral carbonation. 3 M Monoethanolamine (MEA) was used as $CO_2$ absorbent. Making various concentrations of seawater solution, simulated seawater powder was used. Precipitated metal carbonate salts were produced by mixing seawater solutions and $rich-CO_2$ absorbent solution. They were analyzed by X-ray Diffraction (XRD), Scanning Electron Microscope (SEM), and Thermogravimetric Analysis (TGA) and studied characteristic of producing precipitated metal carbonate and possibility of reusing absorbent.

• Clean Technology
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• v.25 no.1
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• pp.19-32
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• 2019

As regional air pollution gets worse by the sulfur oxides emitted from various types of vessels passing through the many countries, the International Maritime Organization establishes the emission control areas and regulates sulfur dioxide in those areas. In order to satisfy these regional regulations, the fuel selection method and the exhaust gas post-treatment device are applied to the ships. Due to the economic reasons, the post-treatment method of exhaust gas for reducing the amount of sulfur oxides discharged is mainly preferred. The scrubber which is dominantly used in the ships are the spray type system where the sprayed liquid drops used for capturing the soluble sulfur dioxides in the exhaust gas. The performance of the spray type system depends on the size distribution of the sprayed droplets. In order to evaluate this performance, we designed counterflow type scrubber and cyclone scrubber and evaluated the desulfurization efficiency and the amount of droplet evaporation according to the size of each droplet by using computational fluid dynamics. The Eulerian-Eulerian analysis method was used because the scrubber had a gas-liquid two-phase flow inside the scrubber. When the diameter of the droplet was $100{\mu}m$, $300{\mu}m$, $500{\mu}m$ and $700{\mu}m$. As a result, both of scrubbers showed high desulfurization efficiency and low evaporation amount at $500{\mu}m$ and $700{\mu}m$.

• Journal of Climate Change Research
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• v.6 no.1
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• pp.1-10
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• 2015

Climate change lead to environmental pollution caused by the radical economic growth and development of industry. The amount of damage from abnormal climate is increasing rapidly for this reason in Korea. In particular, the cities is a lot of carbon emission quantity from the radical growth. Thus the government present "low carbon green growth" for eco-friendly city planning. As one of the important factors effecting climate change, active researches on land use change is performed. In this study, we knew land use change of each scenarios using land use equilibrium model which is kind of predictive model of land use in Japan. First, we selected study area to Jeju lsland. For this study, indicators for input data were selected and spatial data for input data were established using GIS program. Second, we established future scenarios based in 2040s. There are 2 future scenarios: dispersion scenario, compact scenario. Third, we compared with residential area of current and residential area for future scenarios. Results showed that residential area of the difference between current and dispersion scenario were 1,230 ha and residential area of the difference between current and compact scenario were 1,515 ha. Finally, for comparing carbon dioxide absorption volume between dispersion scenarios and compact scenarios, we calculated carbon dioxide absorption volume according to residential area decreased of each future scenarios. Results showed that carbon dioxide absorption volume in dispersion scenario was 477,878 ton and carbon dioxide absorption volume in compact scenario was 588,606 ton. Therefore, the study showed that land use equilibrium model is expected to put to use for future enhancement in creating data for climate change stabilization. And it is also expected to be utilized for city planning research in Korea.

• Safety and Health at Work
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• v.10 no.2
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• pp.229-236
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• 2019

Background: Emerging reports suggest the potential for adverse health effects from exposure to emissions from some additive manufacturing (AM) processes. There is a paucity of real-world data on emissions from AM machines in industrial workplaces and personal exposures among AM operators. Methods: Airborne particle and organic chemical emissions and personal exposures were characterized using real-time and time-integrated sampling techniques in four manufacturing facilities using industrial-scale material extrusion and material jetting AM processes. Results: Using a condensation nuclei counter, number-based particle emission rates (ERs) (number/min) from material extrusion AM machines ranged from $4.1{\times}10^{10}$ (Ultem filament) to $2.2{\times}10^{11}$ [acrylonitrile butadiene styrene and polycarbonate filaments). For these same machines, total volatile organic compound ERs (${\mu}g/min$) ranged from $1.9{\times}10^4$ (acrylonitrile butadiene styrene and polycarbonate) to $9.4{\times}10^4$ (Ultem). For the material jetting machines, the number-based particle ER was higher when the lid was open ($2.3{\times}10^{10}number/min$) than when the lid was closed ($1.5-5.5{\times}10^9number/min$); total volatile organic compound ERs were similar regardless of the lid position. Low levels of acetone, benzene, toluene, and m,p-xylene were common to both AM processes. Carbonyl compounds were detected; however, none were specifically attributed to the AM processes. Personal exposures to metals (aluminum and iron) and eight volatile organic compounds were all below National Institute for Occupational Safety and Health (NIOSH)-recommended exposure levels. Conclusion: Industrial-scale AM machines using thermoplastics and resins released particles and organic vapors into workplace air. More research is needed to understand factors influencing real-world industrial-scale AM process emissions and exposures.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.29 no.2
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• pp.61-70
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• 2019

Geopolymer is an eco-friendly construction material that has various advantages such as reduced $CO_2$ emission, fire resistance and low thermal conductivity compared to cement. However, it has not been many studies on the thermal behavior of the surface of the geopolymer panel when flame is applied to the surface. In this study, surface characteristics of hardened geopolymer on flame exposure was investigated to observe its characteristics as heat-resistant architectural materials. External structure changes and crack due to the heat shock were not observed during the exposure on flame. According to the residue of calcite and halo pattern of aluminosilicate gel, decarboxylation and dehydration were extremely limited to the surface and, therefore, it is thought that durability of hardened geopolymer was sustained. Gehlenite and calcium silicate portion was inversely proportional to quartz and calcite and significantly directly proportional to BFS replacement ratio. Microstructure changes due to the thermal shock caused decarboxylation and dehydration of crystallization and it was developed the pore and new crystalline phase like calcium silicate and gehlenite. It is thought that those crystalline phase worked as a densification and strengthening mechanism on geopolymer panel surface.

• Korean Journal of Construction Engineering and Management
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• v.22 no.2
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• pp.53-62
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• 2021

PC component allocation and loading plan can contribute to reductions in carbon dioxide emission and energy use of vehicles and total project costs with increased utilization of vehicle loading space. The study derived 18 considerations that PC construction plant managers and site managers take into account when they plan allocation and loading of PC components. Then, IPA (Importance and Performance Analysis) was performed to assess importance and performance of the 18 considerations. Results show that in the PC component allocation planning, considerations regarding the number of vehicles and existence of yard for storing PC components have not been taken into account well by the managers. In the PC component loading planning, PC component loading direction has not been reflected well by the managers although it is considered important by them. Recently, ill-planning issues of PC component transportation, such as inefficient use of vehicle space and loading with low stability, are frequent due to various types of PC components produced. In this context, if the results of this study are reflected in the development of component allocation and loading planning, vehicle management of PC projects would be more efficient, thereby leading to economic project management.

• Journal of Environmental Impact Assessment
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• v.30 no.4
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• pp.237-246
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• 2021

The similarity of hourly PM₁₀ and PM_2.5 concentration profiles of the atmospheric monitoring stations in Gyeonggi-do was evaluated through the multilateral analysis between stations. The existing category for most stations in the regions shows relatively low Pearson correlation values of 0.68 and 0.7 for PM₁₀ and PM_2.5 on average respectively, and some monitoring stations revealed high relationships over 0.8 to other regions. Since the current regions are mainly categorized by cluster analysis based on the number of occurrence of high concentration events and geological factors, it is necessary to reclassify them by concentration characteristics for precise fine dust management. In accordance, multi-dimensional scaling being able to visualize could categorize the regions based on regional emission contribution rate and hourly fine dust concentration. As a result of the current analysis, PM₁₀ and PM_2.5 could be reclassified into five regions and fourregions, respectively.

• Applied Chemistry for Engineering
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• v.33 no.3
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• pp.309-314
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• 2022

Carbon dots (CDs) are few nanometer-sized carbon-based nanoparticles and emerging candidate materials in various fields such as biosensors and bioimaging due to their excellent optical properties and high biocompatibility. However, most CDs, emitting blue light, have limited their application in biomedical fields due to the low penetration of short-wavelength lights into the biological system. Therefore, there has been enormous need to develop long-wavelength emitting CDs. In this study, red-emitting CDs were successfully synthesized through the hydrothermal reaction of p-phenylenediamine with hydrochloric acid. In addition, the effect of the amount of hydrochloric acid on the formation of carbon dots, resulting in the variation of the chemical structures of CDs, were investigated, which was confirmed with the intensive structural analyses using infrared and X-ray photoelectron spectroscopy. It was found that the chemical structure of CDs governed their optical properties and quantum yield. Therefore, this study provides an insight into the role of acid in forming red-emitting CDs as the optimal probe for biomedical application.

• Journal of the Korean Recycled Construction Resources Institute
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• v.10 no.3
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• pp.204-210
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• 2022

Cement is pointed out as the main cause of carbon dioxide emission in the construction industry. Many researchs are underway to use blast furnace slag, an industrial by-product, as a substitute for cement to reduce carbon dioxide emitted during the manufacturing the cement. When blast furnace slag is used as a substitute for cement, it has advantages such as long-term strength and chemical resistance improvement. However, blast furnace slag has a problem that makes initial strength low. This is due to the impermeable film on the surface created during the production of blast furnace slag. The created film is known to be destroyed in an alkaline environment, and based on this, previous studies have suggested a solution using various alkali activators. But, alkali activator is dangerous product since it is a strong alkaline material. And it has the disadvantage in price competitiveness. In this study, an experiment was conducted to improve the initial hydration reactivity of the blast furnace slag to secure the initial strength of the mortar substituted with the blast furnace slag and to check whether the carbonation resistance was increased. As a result of the experiment, it was confirmed that the mortar using alkaline water showed higher strength than the mortar using tap water, and there were more hydration products generated inside. In addition, it was confirmed that the mortar using alkaline water as a compounding water had high carbonation resistance.

• KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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• v.28 no.1
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• pp.15-21
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• 2022

The purpose of our study was to investigate the migration level of lead (Pb), cadmium (Cd), and barium (Ba) from glassware into a food simulant and to evaluate the exposure of each element. The test articles were glassware, including tableware, pots, and other containers. Pb, Cd, and Ba were analysed by Inductively Coupled Plasma Optical Emission Spectrometry (ICP-OES). The analytical performance of the method was validated in terms of its linearity, limit of detection (LOD), limit of quantification (LOQ), recovery, precision, and uncertainty. The monitoring was performed for 110 samples such as glass cups, containers, pots, and bottles. a food simulant. Migration test was conducted at 25? for 24 hours in a dark place using 4% acetic acid as a food simulant. Based on the data; exposure assessment was carried out to compare the estimated daily intake (EDI) to the human safety criteria. The risk levels of Pb and Ba determined in this study were approximately 1.9% and 0.3% of the provisional tolerable weekly intake (PTWI) and tolerable daily intake (TDI) value, respectively, thereby indicating a low exposure to the population.