• Macromolecular Research
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• 제11권5호
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• pp.357-367
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• 2003

The linear low density polyethylene (LLDPE)/zeolite composite using novel inorganic filler, zeolite, is prepared by a conventional compounding procedure using a twin-screw extruder. The observed scanning electron microscopic (SEM) morphology shows a good dispersion and adhesion of zeolite in the LLDPE matrix. The mechanical properties in terms of the Young's modulus, the yield stress, the impact strength, and the elongation at break were enhanced with a successive increment of zeolite content up to 40 wt%. The X-ray diffraction measurement is of supportive for the improved mechanical properties and the complex melt viscosity is as well. Upon applying a certain level of strain on the composites, the dewetting, the air hole formation and its growth are characterized. The dewetting originates around the filler particles at low strain and induces elliptical micropores upon further stretching. The microporosity such as the aspect ratio, the number and the total area of the air holes is also characterized. Thus, the composites loaded 40 % zeolite and 300 % elongation may be applicable for breathable microporous films with improved modulus, impact and yield stress, elongation at break, microporosity and air hole properties.

• 한국안전학회지
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• 제14권2호
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• pp.77-82
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• 1999

In this paper, physical properties and electrical conductivity of electron beam irradiated low density polyethylene are studied. The specimens of thickness 100 $\mu\textrm{m}$ irradiated as each 1 Mrad, 2 Mrad, 4 Mrad, 8 Mrad, 16 Mrad and virgin are used in this experiment. FTIR analysis shows strong absorptions by methyl groups in wavenumbers 720 $cm^{-1}$ and 1463 $cm^{-1}$, and did not show any evidences of the presence of residual carbonyl groups. From the DSC analysis, the crystalline melting point of electron beam irradiated specimen is lower than that of virgin specimen. 1 Mrad irradiated sample shows the stable electrical conductivity characteristics with both temperature and electric field.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1998년도 추계학술대회 논문집
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• pp.195-198
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• 1998

In this paper, the physical and the volume resistivity properties due to linear low density polyethylene(LLDPE)/ethylene vinyl acetate(EVA) blends are studied. In order to measure the volume resistivity properties. the micro electrometer is used, the range of temperature and applying voltage are 25 to 120[$^{\circ}C$], form 100 to 1000[V] respectively. From FT-IR spectrum, LLDPE blended with EVA shows an absence of carbonyl and ether groups. From the experimental result of the volume resistivity properties, it is confirmed that the volume resistivity is decreased, which was attributed to the increase of molecular motions with the increase of temperature.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1996년도 추계학술대회 논문집
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• pp.82-85
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• 1996

It is considered that the effect of radiation aging, such as electron beam due to the ultra-high voltage for transmission, on the physical properties and electrical characteristics of electrital insulating materials. Low-density polyethylene(thickness 100[${\mu}{\textrm}{m}$]) is selected as an experimental specimen. Fourier transform infra-red spectrum, X-ray diffraction, differential scanning calorimetry and scanning electron microscopy is used so as to analysis the physical properties, the morphological changes and the crystallinity of LDPE. And it is made an experiments of dielectric characteristics in the temperature range of 20[$^{\circ}C$]~120[$^{\circ}C$], in the frequency range of 30[Hz]~1.5$\times$10$^{5}$ [Hz] and in the applied voltage range of 300[mV]~1500[mV].

• 한국약용작물학회지
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• 제26권4호
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• pp.296-301
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• 2018

Background: The objective of this study was to investigate the effect of packaging material on the growth of rootstock of Liriope platyphylla. Methods and Results: This study examined the effects of two types of packaging material, LDPE (low density polyethylene) and functional film on the growth of the tubers of L. platyphylla, at $5^{\circ}C$. During the 16-weeks of storage period, the ratio of loss and decay of the tubers was examined at intervals of 4, 8, and 16 weeks to detect the quality of the plant. After 16 weeks of storage, the treated tubers were own. Subsequently, plant height and the number of leaves were recorded. The results revealed that functional film at $5^{\circ}C$ was the ideal material for the storage of L. platyphylla tubers. The rate of loss was the highest (57.42%) with a onion net and the lowest (22.12%) with a functional film. Similarly, the rate of tuber decay was highest (8.20%) using onion net and the least (4.60%) when the functional film was used. Conclusions: Thus, the use of the functional film proved to be the most effective in the storage of L. platyphylla tubers when compared with the LDPE.

• 공업화학
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• 제21권3호
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• pp.343-348
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• 2010

저밀도 폴리에틸렌(low density polyethylene, LDPE) 필름의 표면을 다양한 반응 조건하에서 함산소불소화하여 hydroperoxide 관능기를 도입시켜 표면특성을 변화시켰다. 또한 생성된 hydroperoxide 관능기를 반응 개시제로 친수성 그룹을 가지는 단량체인 acryl amide (AM)와 소수성 그룹을 가지는 단량체인 methyl methacrylate (MMA)를 그라프트 중합시켜 LDPE 필름의 표면을 2차 개질하였다. 또한 LDPE, 함산소불소화 된 LDPE (OFPE), AM 및 MMA 단량체가 그라프트 된 OFPE 필름의 표면특성은 1,1-diphenyl-2-picrylhydrazyl (DPPH), 감쇠전반사 분광법, 시차주사 열량분석기 및 접촉각 측정법 등으로 분석하였다. DPPH 라디칼 분석법의 결과로부터, OFPE의 hydroperoxide 관능기의 양은 함산소불소화 총압력과 F2 가스의 부분압이 증가함에 따라 증가함을 알 수 있었다. 접촉각 및 표면 자유에너지 분석결과로부터, 함산소불소화에 의해서 생성된 hydroperoxide 관능기와 AM과 같은 친수성 그룹을 가지는 단량체의 그라프트 중합은 LDPE 필름 표면에서 물과 같은 친수성 용매의 접촉각을 감소시키고, MMA와 같은 소수성 그룹을 가지는 단량체의 경우는 LDPE 필름 표면에서 methylene diiodide와 같은 비극성 용매의 표면 접촉각을 감소시켰다. 이는 AM 및 MMA 단량체의 그라프트 중합에 의한 것으로, LDPE 필름 표면은 친수성 및 소수성 용매에 대한 젖음성이 향상되었다.

• Food Science and Biotechnology
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• 제16권1호
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• pp.62-66
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• 2007

Four different biopolyester films, two aliphatic polyesters including polylactides (PLA) and poly(3-hydroxy-butyrate-co-3-hydroxyvalerate (PHBV), and two aliphatic-aromatic copolyesters including Ecoplex and Biomax, were prepared using by thermo-compression, and their tensile and water barrier properties were determined. Among the films tested, PLA film was the most transparent (T: 95.8%), strongest, and stiffest (TS, 40.98 MPa; E, 1916 MPa), however it was rather brittle. In contrast, Ecoplex film was translucent while being the most flexible and resilient (EB, 766.8%). Biomax film was semitransparent and was the most brittle film tested (EB, 0.03%). All biopolyester films were water resistant exhibiting very low water solubility (WS) values ranging from 0.0.3 to 0.36%. PHBV film showed the lowest water vapor permeability (WVP) value ($1.26{\times}10^{-11}\;g{\cdot}m/m^2{\cdot}sec{\cdot}Pa$) followed by Biomax, PLA, and Ecoflex films, respectively. The water vapor barrier properties of each film were approximately 100 times higher than those of carbohydrate or protein-based films, but about 100 times lower than those of commodity polyolefin films such as low-density polyethylene (LDPE) or polypropylene (PP).

• 대한전기학회:학술대회논문집
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• 대한전기학회 1999년도 하계학술대회 논문집 D
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• pp.1667-1670
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• 1999

In this paper, We are studied the electrical properties of thin film mixed with LLDPE and EVA, and the specimen is selected as Low Linear Density Polyethylene and Ethylene Vinyl Acetate produced by mixture ratio of 50:50, 60:40, 70:30 and 80:20. (thickness $100[{\mu}m],\;70[{\mu}m],\;50[{\mu}m],\;30[{\mu}m]$). As the electrical properties. one is electrical conduction characteristics of the due to mixture ratio of linear low density polyethylene (LLDPE) and ethylene vinyl acetate(EVA), the other is AC breakdown of specimens due to variation of the thickness. From the result of XRD, it is confirmed that specimen of 80 : 20 and virgin LLDPE have high peaks at $2\theta=21.4[^{\circ}]$ and the peak by the contribution of amorphous at $2{\theta}=19.5[^{\circ}]$ is constant with no relation to mixture ratio, but virgin EVA is somewhat lower.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1996년도 추계학술대회 논문집
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• pp.164-168
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• 1996

The relation between crystallinity and thermal history in low density polyethylene thin films and their effect on electric conduction phenomena and dielectric breakdown was studied. The low density polythylene thin films obtained by the solution growth method heat-treated at 140[$^{\circ}C$] for 2 h and subsequently cooling to various ways. The degree of crystallinity was estimated by the X-ray diffraction measurement for the specimen of slowly cooling, ICE quenching and liquid nitrogen quenching. The result shows that the crystallinity decreases become faster as the cooling speed increased, and that conduction phenomenon is governed by the space charge limited current in high field. It was found that the dielectric breakdown field increases with an increase in cooling speed and test number in self-healing breakdown method.

• Elastomers and Composites
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• 제57권4호
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• pp.157-164
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• 2022

Representative bulletproof materials, such as aramid or ultra-high molecular weight polyethylene(UHMWPE), have excellent strength and modulus in the plane direction but are very vulnerable to forces applied in the thickness direction. This paper reports a study on the effects of reinforcement in the thickness direction when bulletproof composite fabrics are prepared to improve their performance. Aramid and UHMWPE fabrics were combined using the film-bonding, needle-punching, or stitching methods and then subjected to low-velocity projectile and ball-drop impact tests. The results of the low-velocity projectile test indicated that the backface signature(BFS) decreased by up to 29.2% in fabrics obtained via the film-bonding method. However, the weight of the film-bonded fabric increased by approximately 23% compared with that obtained by simple lamination, and the fabric stiffened on account of the binder. Flexibility, light weight for wearability, and excellent bulletproof performance are very important factors in the development of bulletproof materials. When the needle-punching method was used, the BFS increased as the fibers sustained damage by the needle. When the composite fabrics were combined by stitching, no significant difference in weight and thickness was observed, and the BFS showed similar results. When a diagonal stitching pattern was employed, the BFS decreased as the stitching density increased. By contrast, when a diamond stitching pattern was used, the fabric fibers were damaged and the BFS increased as the stitching density increased.