• 제목/요약/키워드: low conductivity

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양자성, 비양자성 이온성 액체와 새롭게 합성된 낮은 밴드갭을 갖는 고분자와의 상호작용에 의한 전기적,광학적 특성 연구 (Electrical and Optical Properties of Newly Synthesised Low Bandgap Polymer with Protic and Aprotic Ionic Liquids)

  • 김중일;김인태
    • 한국응용과학기술학회지
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    • 제30권3호
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    • pp.461-471
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    • 2013
  • Use of low bandgap polymers is the most suitable way to harvest a broader spectrum of solar radiations for solar cells. But, still there is lack of most efficient low bandgap polymer. In order to solve this problem, we have synthesised a new low bandgap polymer and investigated its interaction with the ILs to enhance its conductivity. ILs may undergo almost unlimited structural variations; these structural variations have attracted extensive attention in polymer studies. In addition to this, UV-Vis spectroscopy, confocal Raman spectroscopy and FT-IR spectroscopy results have revealed that all studied ILs (tributylmethylammonium methyl sulfate [$N_{1444}$][$MeSO_4$] from ammonium family) and 1-methylimidazolium chloride ([MIM]Cl, and 1-butyl-3-methylimidazolium chloride [Bmim]Cl from imidazolium family) has potential to interact with polymer. Further, protic ILs shows enhanced conductivity than aprotic ILs with low bandgap polymer. This study provides the combined effect of low bandgap polymer and ILs that may generate many theoretical and experimental opportunities.

Oxygen Permeability Measurement of $ZrO_2-TiO_2-YB_2O_3$ Mixed Conductor

  • Hitoshi Naito;Kim, Hitoshi ishima;Toru Takahashi;Hiroo Yugami
    • The Korean Journal of Ceramics
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    • 제6권2호
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    • pp.124-128
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    • 2000
  • Electrical properties of $ZrO_2-TiO_2Yb_2O_3$mixed conductor (Ti-YbSZ) were investigated. This mixed conductor can be applied as a membrane for gas separation at high temperatures. The total conductivity decreased with increasing the $TiO_2$concentration. At high temperatures, the rate of the conductivity degradation became smaller than that at low temperatures. From the oxygen partial pressure dependence of the total conductivity of Ti-YbSZ, the electronic conductivity increased with increasing $TiO_2$concentration at low oxygen partial pressures and at high temperatures. Both 15 and 20 mol% $TiO_2$doped YbSZ showed high oxygen permeability. Mixed conductors, which has high $TiO_2$concentration in YbSZ, are promising materials for using as a membrane for gas separation at high temperatures.

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고온초전도 선재의 극저온 열전도도 측정 및 특성평가 (Evaluation of thermal conductivity for High temperature superconductor tape at low temperature)

  • 김정호;장석헌;김규태;주진호;나완수;강형구;고태국
    • 한국초전도저온공학회:학술대회논문집
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    • 한국초전도저온공학회 2002년도 학술대회 논문집
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    • pp.153-155
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    • 2002
  • The thermal conductivity of Ag and Ag alloys at low temperature (10~110 K) were evaluated by direct measurement technique. It was observed that thermal conductivity decreased with increasing the content of alloying elements such as Mg and Cu. Thermal conductivity of pure Ag tape at 20 K was measured to be 2794 W/m$\cdot$K. On the other hand, the corresponding values of Ag/Al tape and Ag/Al/sus315L tape were 1235 and 352 W/m$\cdot$K, respectively, indicating 2 to 8 times lower than that of pure Ag tape.

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역해석기법을 이용한 불포화토 투수계수함수 산정에 관한 연구 (Evaluation of Hydraulic Conductivity Function in Unsaturated Soils using an Inverse Analysis)

  • 이준용;한진태
    • 한국농공학회논문집
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    • 제55권4호
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    • pp.1-11
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    • 2013
  • Unsaturated hydraulic conductivity function is one of key parameters to solve the flow phenomena in problems of landslide. Prediction models for hydraulic conductivity function related to soil-water retention curve equations in many geotechnical applications have been still used instead of direct measurement of the hydraulic conductivity function since prediction models from soil-water retention curve equations are attractive for their fast and easy use and low cost. However, many researchers found that prediction models for the hydraulic conductivity function can not predict the hydraulic conductivity exactly in comparison with experimental outputs. This research introduced an inverse analysis to evaluate the hydraulic conductivity function corresponding to experimental output from the flow pump system. Optimisation process was carried out to obtain the hydraulic conductivity function. This research showed that the inverse analysis with flow pump system was suitable to assess the hydraulic conductivity in unsaturated soil, and the prediction models for the hydraulic conductivity were led to the significant discrepancy from actual experimental outputs.

Thermal conductivity of PLA-bamboo fiber composites

  • Takagi, Hitoshi;Kako, Shuhei;Kusano, Koji;Ousaka, Akiharu
    • Advanced Composite Materials
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    • 제16권4호
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    • pp.377-384
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    • 2007
  • 'Green' composites were fabricated from poly lactic acid (PLA) and bamboo fibers by using a conventional hot pressing method. The insulating properties of the PLA-bamboo fiber 'green' composites were evaluated by determination of the thermal conductivity, which was measured using a hot-wire method. The thermal conductivity values were compared with theoretical estimations. It was demonstrated that thermal conductivity of PLA-bamboo fiber 'green' composites is smaller than that of conventional composites, such as glass fiber reinforced plastics (GFRPs) and carbon fiber reinforced plastics (CFRPs). The thermal conductivity of PLA-bamboo fiber 'green' composites was significantly influenced by their density, and was in fair agreement with theoretical predictions based on Russell's model. The PLA-bamboo fiber composites have low thermal conductivity comparable with that of woods.

고전도성 부품용 Mg-RE-Zn계 합금의 미세조직 및 특성 (Microstructure and Properties of Mg-RE-Zn Alloys for High Conductivity Parts)

  • 김정민;김남훈
    • 한국주조공학회지
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    • 제34권5호
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    • pp.151-155
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    • 2014
  • The relatively low conductivity of conventional Mg-Al alloys often limits their areas of application. Therefore, several attempts to develop new high-conductivity magnesium alloys have been made recently. In this research, A Ce-rich rare-earth (RE)material and zinc were added to magnesium which contained no aluminum. As the RE and Zn content were increased, both the hardness and tensile strength were gradually increased, despite the fact that the electrical conductivity decreased slightly. The effects of an aging treatment on the conductivity and mechanical properties of Mg-RE-Zn alloys were also investigated. The electrical conductivity did not change according to the heat treatment conditions; however, the mechanical properties could be enhanced by proper aging heat treatments.

고온-저습용 연료전지를 위한 SPAES/Silicate 복합막 (SPAES/Silicate Hybrid Membranes for High-Temperature and Low-Humidity Proton Exchange Membrane Fuel Cells)

  • 소순용;김태호;김성철;홍영택
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2010년도 춘계학술대회 초록집
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    • pp.147-147
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    • 2010
  • An electrolyte membranes for high temperature/low humidity is a demand for the proton exchange membrane fuel cells (PEMFCs). In this work, we prepared hybrid membranes, which have novel glass content in the hydrophilic and hydrophobic part of sulfonated poly(arylene ether sulfone) (SPAES) by in-situ sol-gel synthesis of various functional silane. The effect of silicate from functional silane content on the proton conductivity, water uptake of the hybrid membranes under high temperature and low humidity was quantitatively identified. The silicate content contributed to the enhancement of not only proton conductivity, but also water retention ability for PEMFCs operation.

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$TiO_2$ 반도체 용사피막의 광전극 특성에 미치는 용사조건의 영향 (Effects of Plasma Spray Conditions on Photoelectric Properties of Plasma Sprayed $TiO_2$ Semiconductor)

  • 박정식;박경채
    • Journal of Welding and Joining
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    • 제12권1호
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    • pp.94-101
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    • 1994
  • In this study, plasma spraying has been used to produce $TiO_2$ polycrystalline coatings from $TiO_2$ powders. The physical and chemical properties of plasma sprayed $TiO_2$ coatings depend greatly on plasma spraying conditions. The electrical resistivity, oxygen concentration, photocurrent and crystal structure of plasma sprayed $TiO_2$ coating has been studied. The results are as follows: 1. The oxygen loss and electrical conductivity of $TiO_2$ plasma sprayed coatings increased by low pressure and high amount of auxiliary gas, hydrogen in plasma spraying. 2. Oxygen loss increase electrical conductivity, and decrease photocurrent of $TiO_2$ plasma sprayed coatings. 3. Photocurrent of $TiO_2$ plasma sprayed coatings manufactured in atmospheric pressure is higher than that of low pressure.

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고온 소결형 그라비어 오프셋용 Ag 페이스트의 물성 연구 (A Study on Properties on High Temperature Sintering Gravure Off-set Ag Paste)

  • 박창원;황보혁;조정우;남수용
    • 한국인쇄학회지
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    • 제29권2호
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    • pp.71-82
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    • 2011
  • Electronic display markets has been developed. The cathode ray tube of brown form recently celebrated their 100th by first display. Also LCD of flat form recently celebrated their 25th by second display and it has advantage of small volume, lower consumption power. But FPD has problem that is property of brittle and noncarrying by glass substrate. Therefore the arrival of portable electronics devices has put an increasing premium on durable, lightweight and inexpensive display components. It is flexible display by third display. Also electronics field such as printed wiring board, RFID, membrane switch prefer flexible display. The conductive pattern can be used mostly in field of electronic displays and electronics. This manufacture of conductive pattern in present used is screen printing. The the conductive pattern. It has advantages of flexibility, high conductivity, drying in low temperature, good conductivity. screen printing has problem that is low productivity and use not flexible substrate because of high fire temperature. This study was developed novel method to form the conductive pattern. It has advantages of flexibility, high conductivity, drying in low temperature, good conductivity.

PVA 용액법을 통한 나노 Cu 분말합성 및 소결체의 열적 특성 (Synthesis of Nano-Sized Cu Powder by PVA Solution Method and Thermal Characteristics of Sintered Cu Powder Compacts)

  • 오복현;마충일;이상진
    • 한국재료학회지
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    • 제30권2호
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    • pp.93-98
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    • 2020
  • Effective control of the heat generated from electronics and semiconductor devices requires a high thermal conductivity and a low thermal expansion coefficient appropriate for devices or modules. A method of reducing the thermal expansion coefficient of Cu has been suggested wherein a ceramic filler having a low thermal expansion coefficient is applied to Cu, which has high thermal conductivity. In this study, using pressureless sintering rather than costly pressure sintering, a polymer solution synthesis method was used to make nano-sized Cu powder for application to Cu matrix with an AlN filler. Due to the low sinterability, the sintered Cu prepared from commercial Cu powder included large pores inside the sintered bodies. A sintered Cu body with Zn, as a liquid phase sintering agent, was prepared by the polymer solution synthesis method for exclusion of pores, which affect thermal conductivity and thermal expansion. The pressureless sintered Cu bodies including Zn showed higher thermal conductivity (180 W/m·K) and lower thermal expansion coefficient (15.8×10-6/℃) than did the monolithic synthesized Cu sintered body.