• Journal of the Korean Ceramic Society
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• v.38 no.9
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• pp.839-845
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• 2001

In order to vitrify the Ion-Exchange Resin(IER), Dry Active Waste(DAW), and borate concentrate generated from the commercial nuclear facilities, the glass formulation study based on the their compositions was performed. Two glasses named as RG-1 and DG-1 were formulated as the candidate glasses for the vitrification of hte IER and DAW, respectively. A glass named as MG-1 was also formulated as a candidate glass for the vitrification of the mixed wastes containing the IER, DAW, and borate concentrate. The process parameters, product qualities, and economics were evaluated for the candidate glasses and confirmed experimentally for the some properties. The glass viscosity and electrical conductivity as the process parameters were in the desired ranges. the product qualities such as glass density, chemical durability, phase stability, etc. were satisfactory. In case of vitrifying the wastes using our developed glass formulation study, the volume reduction factors for the IER, DAW and mixed wastes were evaluated as 21, 89 and 75, respectively.

• Membrane Journal
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• v.17 no.4
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• pp.294-301
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• 2007

To improve oxidative stability of non-fluorinated styrene-based polymer electrolyte membranes, copolymerized membranes were prepared using styrene derivatives such as p-methylstyrene, t-butylstyrene, and ${\alpha}-methylstyrene$ by monomer sorption method. Prepared membrane was characterized by measurement of weight gain ratio, water content, ion-exchange capacity, proton conductivity, and oxidative stability under the accelerated condition. It was found that each step of monomer sorption method including sorption, polymerization and sulfonation could be affected by the properties and the structures of styrenederivatives. Due to difficulty of polymerization, ${\alpha}$-methylstyrene was copolymerized with styrene or p-methylstyrene. Prepared membrane using ${\alpha}-methylstyrene$ and styrene showed higher performance and stability comparing to copolymerized membrane with styrene. However, copolymerized membranes with ${\alpha}-methylstyrene$ did not showed much improved oxidative stability comparing to styrene membrane due to their lower molecular weight. The t-butylstyrene membrane showed a low performance due to substituted bulky-butyl group which prevents sorption and sulfonation reaction. However, copolymerized t-butylstyrene membranes with p-methylstyrene showed good performance and much improved stability than the styrene membranes.

• Journal of Korean Society of Environmental Engineers
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• v.34 no.6
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• pp.430-437
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• 2012

In order to obtain information on the design parameters of the horizontal laterals in floodplain filtration, laboratory-scale sand-box experiments were performed where the head distributions on the laterals and the groundwater profiles were measured according to the change in parameters including lateral diameter, hydraulic conductivity of the sand, water level at the well and raw-water supply rate. Measured data were analyzed using a numerical code in order to identify the discharge intensity distribution along the laterals. It was observed from the result that the lowering of the water level at the well had minimal adverse effect on the performance of the floodplain filtration. Results also elucidated that the low conveyance of the laterals to transmit the filtrate was compensated and supplemented by a natural augmentation in horizontal conveyance through the aquifer when the raw-water supply rate exceeded the adequate recovery rate. With this mechanism, the water quality is expected to improve further since the travel distance through the aquifer is amplified. Based on these findings it can be suggested that the diameter of the lateral used in the floodplain filtration may be smaller than those in riverbank/bed filtration. It was also found that the ratio between the head loss occurring in a lateral and the total head loss in the floodplain filtration was proportional to the exit velocities of the laterals, which may be used to design and/or evaluate the lateral in floodplain filtration.

• Geophysics and Geophysical Exploration
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• v.5 no.1
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• pp.23-32
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• 2002

Capacitively-coupled resistivity (CCR) system is known to be very useful where galvanic contact to earth is impossible, such as the area covered with thick ice, snow, concrete or asphalt. This system injects current non-galvanically, i.e., capacitively to earth through line antenna and measures potential difference in a same manner. We derived geometric factor for two types of antenna configuration and presented the method of processing and converting the data obtained with CCR system suitable to conventional resistivity inversion analysis. The CCR system, however, has limitations on use at conductive area or electrically noisy area since it is very difficult to inject sufficient current to earth with this system as with conventional resistivity system. This causes low SM ratio when acquiring data with CCR system and great care must be taken in acquiring data with this system. Additionally the uniform contact between line antennas and earth is also crucial factor to obtain good S/N ratio data. The CCR method, however, enables one to perform continuous profiling over a survey line by dragging entire system and thus will be useful in rapid investigation of conductivity distribution in shallow subsurface.

• Journal of the Korean Chemical Society
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• v.25 no.2
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• pp.110-118
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• 1981

Kinetics and mechanism for the reaction of substituted phenacyl bromides with substituted pyridines have been determined at 25, 35 and $45^{\circ}C$ in methanol and dimethylformamide by the conductivity method. The rate constants for the reaction of various pyridines with phenacyl bromide shown that electron-donating substituents in the pyridine increase the rate, while electron-attracting one decrease in both solvents. The effect of substituents in substrate, the rate being increased by electron-attracting substituents. This is as expected for nucleophilic attack of amines on the carbon atom. Isokinetic and $Br{\psi}nsted$ linear relationship were shown in the reaction of phenacyl bromide with pyridines in both solvent in which isokinetic temperature were obtained 614, $202^{\circ}K$ and ${\beta}$ values were 0.29, 0.36 in methanol and dimethylformamide respectively. In the case of the reaction of substituted phenacyl bromide with pyridines, isokinetic temperature decreases with increasing electron-attracting ability of the substituents in the phenacyl bromide, while the ${\beta}$ values were reverse. From the above results, it can be inferred that N…C bond formation decreases progressively from p-chloro- to p-methoxyphenacyl bromide and the bond formation predominates in DMF than methanol. The ${\rho}$ values of Hammett equation of the reaction of phenacyl bromide with substituted pyridines are negative in both solvent, but its value was larger negative in DMF than methanol and the ${\rho}$ value of that of substitutted substrates with pyridine was 0.3, the low value is ascribed to direct $S_N2$ attack of the nitrogen atom in pyridine ring at the methylene carbon.

• Journal of the Korean Chemical Society
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• v.20 no.5
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• pp.323-332
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• 1976

The x or $x^0+x'$ values of the nonstoichiometric chemical formula $TiO_{2-x}$ or $Ti_{2-(x^0+x')}$ have been measured by a specially made magnetic quartz microbalance in a temperature range from 600 to $1300^{\circ}C$ under oxygen pressures of $1{\times}10^{-6} to 1 atm. The standard x or $x^0$ value of the rutile is 0.00148. The x values $under_xoxygen$ pressure of 1 atm decrease with temperatures and then the stoichiometric rutile (or x = 0) is formed at $1130^{\circ}C$. The x values varied between 0.00148 and 0.01719 at a temperature range from 600 to $1300^{\circ}C$ under $1{\times}10^{-9}{\sim}1{\times}10^{-2}$ atm oxygen pressures. The enthalpies of formation of the nonstoichiometric rutile, $H_f$, varied between 21.05 and 29.97 Kcal/mole under the above conditions. The 1/n values calculated from the plots of log X' vs. log $Po_2$ are -{\frac{1}{2}}{\sim}-{\frac{1}{4}} under low oxygen pressure range of $1{\times}10^{-6}\;to\;1{\times}10^{-4}$ atm. Many physical properties of the titanium dioxide, such as the stability of the rutile, Electrical conductivity, catalytic activity and defects, can be explained through the x values and the thermodynamic data calculated from the temperature and oxygen pressure dependences of the x' values.

• Journal of the Korean Electrochemical Society
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• v.23 no.4
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• pp.97-104
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• 2020

One of the main challenges of electrochemical water splitting technology is to develop a high performance, low cost oxygen-evolving electrode capable of substituting a noble metal catalyst, Ir or Ru based catalyst. In this work, CoFe₂O₄ nanoparticles with sub-44 nmsize of a inverse spinel structure for oxygen evolution reaction (OER) were synthesized by the injection of KNO₃ and NaOH solution to a preheated CoSO₄ and Fe(NO₃)₃ solution. The synthesis time of CoFe₂O₄ nanoparticles was controlled to control particle and crystallite size. When the synthesis time was 6 h, CoFe₂O₄ nanoparticles had high conductivity and electrochemical surface area. The overpotential at current denstiy of 10 mA/㎠ and Tafel slope of CoFe₂O₄ (6h) were 395 mV and 52 mV/dec, respectively. In addition, the catalyst showed excellent durability for 18 hours at 10 mA/㎠.

• Geophysics and Geophysical Exploration
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• v.6 no.3
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• pp.143-152
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• 2003

Among the various geophysical approaches to identify the leakage of leachate with conductivity variation, conventional electrical resistivity survey has been mainly used at waste landfill. We adopted small-loop electromagnetic (EM) survey using multi-frequencies in parallel with electrical resistivity survey to delineate the leakage of leachate through the shallow soil layer at a waste landfill in Jeju Island, and also with self-potential monitoring to detect the streaming potential produced by the movement of leachate. There were no evidences of leakage from waste landfill according to the results of the electrical resistivity survey and SP monitoring, and it was also true from the results of water quality analysis at stream around waste landfill periodically. On the other hand, the results of one-dimensional inversion of spatially-filtered small-loop EM survey data showed the anomalous zone of low resistivity with depth both around and inner waste landfill.

• Nuclear Engineering and Technology
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• v.13 no.2
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• pp.85-96
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• 1981

A preliminary study of the isotope hydrology of the Han River Valley is presented. This investigation is part of a project whose overall aim is to relate the levels of heavy metal ions to the dynamics of the groundwater movement in order to establish (i) whether there is any evidence for the deterioration in groundwater quality associated with the release of industrial effluents and (ii) if so, to determine the migration path-ways. Evidence is adduced that the recharge mechanism is principally determined by the degree of urbanisation. In the metropolitan area of Seoul, river recharge dominates probably due to the combined effects of reduced infiltration and increased pumpage. In the inter-urban region, the major source of recharge is local precipitation. During the spring sampling period when the river levels were low. evidence was obtained for appreciable groundwater infiltration in the vicinity of the upstream transect. No significant correlations were observed between the levels of heavy metals in the groundwater, and the recharge mechanism, the distance from the river or the electrical conductivity of the samples.

• Journal of Korea Water Resources Association
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• v.53 no.11
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• pp.985-997
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• 2020

SWAT (Soil and Water Assessment Tool)-MODFLOW (Modular Groundwater Flow) is a coupled model that linking semi-distributed watershed hydrology with fully-distributed groundwater behavior. In this study, the groundwater simulation results of SWAT and SWAT-MODFLOW were compared for Bokhacheon watershed in Namhan river basin. The models were calibrated and validated with 9 years (2009~2017) daily streamflow (Q) data of Heungcheon (HC) water level gauge station and the daily groundwater level observation data of Yulheon (YH). For SWAT, the groundwater parameters of GW_DELAY, GWQMN, and ALPHA_BF affecting baseflow and recession phase were treated. The SWAT results showed the coefficient of determination (R²) of 0.7 and Nash-Sutcliffe model efficiencies (NES_Q, NSE_inQ) for Q and 1/Q with 0.73 and -0.1 respectively. For SWAT-MODFLOW, the spatio-temporal aquifer hydraulic conductivity (K, m/day), specific storage (S_s, 1/m), and specific yield (S_y) were applied. The SWAT-MODFLOW showed R², NSE_Q, and NSE_inQ of 0.69, 0.74, and 0.51 respectively. The SWAT-MODFLOW considerably enhanced the low flow simulation with the help of aquifer physical information. The total streamflow of SWAT and SWAT-MODFLOW were 718.6 mm and 854.9 mm occupying baseflow of 342.9 mm and 423.5 mm respectively.