• Restorative Dentistry and Endodontics
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• 제10권1호
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• pp.71-83
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• 1984

The purpose of this study was to evaluate the transmission spectrum of the set calcium hydroxide dental cement (Dycal, L.D. Caulk Co. Milford, Del.) Cement was prepared for A T R spectra at a low powder-to-liquid ratio of 3.0gm/ml in order to retard the reaction and facilitate the manipulation of loading the cement into the cell. Spectra were recorded on an I R Spectrophotometer (MX-1, FT) at an agle of incidence of 55. The A T R cell was a RIIc Model TR5 with a hemisperical KRS-5 (Thallium-Bromide-Iodide). A spectrum was recorded within 3 minutes. Further spectra were recorded after 5,10,30 minutes and 1,5,24, 72 hours. The results were as follows; 1. The setting reaction between acid paste and base past would take place fastly within 10 minutes after mix, and that would be slow until 72 hours after mix. 2. In the set cements, some methyl salicylate and calcium hydroxide remained unreacted until 72 hours after mix. 3. The setting reaction and the reaction rate occuring at the surface and in the bulk cements were similar. 4. The chelates were bound together between calcium hydroxide and methyl salicylate.

• 한국지반공학회:학술대회논문집
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• 한국지반공학회 2002년도 봄 학술발표회 논문집
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• pp.297-304
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• 2002

This study is about penetrability of Micro Cement(MC) used for ground improvement. In this study, the characteristics of chemical grouting such as solidification, penetrability were analyzed experimentally by changing permeability of ground, grain size and relative density of grout material. For evaluating applicability of grout material, solidification test and penetrability test were performed. From the results of the tests, effective solidification ratio and penetrability ratio of MC was each 75%, 86% to be excellent when ground permeability was in the range of 10$^{-2}$ and 10$^{-4}$ cm/sec. Otherwise, those of Ordinary Portland Cement(OPC) were both lower than 50% to be poor. When penetrability of grout material is needed for improvement of dam foundation and soft ground, application of MC Is much superior to that of the other materials. The results of the grouting tests in the water flowing ground show that solidification effect of long gel-time grout material is excellent as injection pressure increases when groundwater velocity is relatively low. But when groundwater velocity is relatively high, solidification effect of long gel-time grout material is very poor because most grout materials are outflowed. Therefore, as groundwater velocity is high, effective solidification ratio of long gel-time grout material is better than that of short gel-time grout material, also penetration distance of long gel-time grout material is longer than that of short gel-time grout material.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2013년도 추계 학술논문 발표대회
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• pp.68-71
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• 2013

Reactive Powder Concrete (RPC) is an ultra high strength and high ductility cement-based composite material and has shown some promise as a new generation concrete in construction field. It is characterized by a silica fume-cement mixture with very low water-binder (w/b) ratio and very dense microstructure, which is formed using various powders such as cement, silica fume and very fine quartz sand (0.15~0.4mm) instead of ordinary coarse aggregate. However, the unit weight of cement in RPC is as high as 900~1,000 kg/㎥ due to the use of very fine sand instead of coarse aggregate, and a large volume of relatively expensive silica fume as a high reactivity pozzolan is also used, which is not produced in Korea and thus must be imported. Since the density of RPC has a heavy weight at 2.5~3.0 g/㎤. In this study, the modified RPC was made by the combination of ternary pozzolanic materials such as blast furnace slag and fly ash, silica fume in order to economically and practically feasible for Korea's situation. The fire resistance and structural behavior of the modified RPC exposed to high temperature were investigated.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2008년도 추계 학술발표회 제20권2호
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• pp.637-640
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• 2008

본 연구에서는 플라이애쉬가 다량 치환된 콘크리트 강도 발현과 수화열 특성에 대하여 연구를 수행하였다. 3수준의 W/B와 4수준의 플라이애쉬 치환률 및 2수준의 실리카흄 치환율을 실험 변수로 선택하였다. 콘크리트 배합에서 단위수량은 125kg/m$^3$으로 고정하였다. 결과로서 초기 재령에서는플라이애쉬 치환율이 증가하면서 재령 91일까지 압축강도가 점진적으로 감소하는 경향을 나타내었다. 그런데 강도를 고려하면, 적절한 플라이애쉬 치환율은 20%인 것으로 나타났는데, 이는 제 1종시멘트의 경우에 비하여 낮은 값이다. 콘크리트의 인장강도는 압축강도의 0.72승에 비례하는 것으로 나타났다. 그리고 콘크리트 표준 시방서에 제시되어 있는 인장 강도 식은 압축강도가 낮은 경우에과대평가하고, 압축강도가 높은 경우에 과소평가하는 것으로 나타났다.

• Computers and Concrete
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• 제30권6호
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• pp.393-407
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• 2022

Due to the enormous cement content, pozzolanic materials, and the use of different aggregates, sustainable controlled low-strength material (CLSM) has a higher material cost than conventional concrete and sustainable construction issues. However, by selecting appropriate materials and formulations, as well as cement and aggregate content, whitethorn costs can be reduced while having a positive environmental impact. This research explores the desire to optimize plastic properties and 28-day unconfined compressive strength (UCS) of CLSM containing powder content from unprocessed-fly ash (u-FA) and recycled fine aggregate (RFA). The mixtures' input parameters consist of water-to-cementitious material ratio (W/CM), fly ash-to-cementitious materials (FA/CM), and paste volume percentage (PV%), while flowability, bleeding, segregation index, and 28-day UCS were the desired responses. The central composite design (CCD) notion was used to produce twenty CLSM mixes and was experimentally validated using MATLAB by an Artificial Neural Network (ANN). Variance analysis (ANOVA) was used for the determination of statistical models. Results revealed that the plastic properties of CLSM improve with the FA/CM rise when the strength declines for 28 days-with an increase in FA/CM, the diameter of the flowability and bleeding decreased. Meanwhile, the u-FA's rise strengthens the CLSM's segregation resistance and raises its strength over 28 days. Using calcareous powder as a substitute for cement has a detrimental effect on bleeding, and 28-day UCS increases segregation resistance. The response surface method (RSM) can establish high correlations between responses and the constituent materials of sustainable CLSM, and the optimal values of variables can be measured to achieve the desired response properties.

• 한국지반공학회논문집
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• 제26권1호
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• pp.75-83
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• 2010

저강도고유동화재는 다짐이 필요 없고 유동성이 큰 물질로 일반적으로 시멘트, 비회, 잔골재, 물, 혼화제 등을 혼합하여 만들어진다. 기존의 CLSM은 잔골재로 모래를 사용하고 있으나 때문에 모래가 점점 구하기 어려워지는 현재 우리나라 실정에서는 그대로 사용하기 곤란하다. 본 연구에서는 모래대신 매립회를 이용하여 매립회, 비회, 시멘트, 물의 혼합물로 만들어진 CLSM의 강도특성을 조사하여 사용가능성을 제시하고자 한다. 일축압축강도실험결과 기준 일축압축강도(0.5MPa~1.0MPa)를 만족하는 배합비는 매립회와 비회의 혼합비 0:100~70:30, 시멘트비 3.0~5.0%, 함수비 31~34%로 나타났다. 플로우시험 결과 매립회와 비회를 혼합하여 사용하는 모든 경우(매립회와 비회의 비 30:70~70:30)에서 기준 플로우값(0.2m)를 만족하였다.

• Environmental Engineering Research
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• 제14권4호
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• pp.212-219
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• 2009

Emission characteristics of air pollutants from three commercially operating cement kilns co-burning waste were investigated. The major heavy metals emitted were mercury (Hg), zinc (Zn), nickel (Ni), chromium (Cr), lead (Pb), cadmium (Cd), and arsenic (As) Removal efficiency of the bag filter was above 98.5% for heavy metals (except Hg), and above 60% for Hg. Higher fractions of heavy metals entering the bag filter were speciated to cement kiln dust. On average, 3.3% of the -heavy metals of medium and low toxicity (Pb, Ni, and Cr) entering the bag filter were released into the atmosphere. Among highly toxic heavy metals, 0.14% of Cd, 0.01% of As, and 40% of Hg entering the bag filter were released into the atmosphere. In passing through the bag filter, the proportion of oxidized Hg in all cases increased. Emission variations of hazardous air pollutants in cement kilns tested were related to raw materials, fuel, waste feed and operating conditions. Volatile organic compounds detected in gas emissions were toluene, acrylonitrile benzene, styrene, 1,3-butadiene, and methylene chloride. Although hazardous air pollutants in emissions from cement kilns co-burning waste were within the existing emission limit, efforts are required to minimize their levels.

• 한국구조물진단유지관리공학회 논문집
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• 제27권6호
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• pp.130-137
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• 2023

본 연구는 XRF 장비를 활용하여 고온조건에 노출된 시멘트 페이스트의 화학적 특성변화에 대한 연구를 진행하였다. 고온조건은 전기가열로를 이용하여 상온에서 1000도까지 총 11개의 목표온도를 계획하여 진행하였고, Geo-quant basic 표준 라이브러리를 이용하여 Ca, Si, Al, Fe, S, Mg, Ti, Sr, P, Mn, Zn, K 등 12종의 원소를 분석 대상으로 하였다. 실험 결과 피해온도가 증가할수록 시멘트페이스트를 구성하고 있는 각 원소의 비율이 증가하는 것으로 나타났다. 극히 일부의 미량 원소를 제외하고, 대부분의 원소 구성비율은 피해온도와 높은 상관성을 나타냈는데, R-squared 값 0.98 이상을 나타내었다. 본 연구에서는 100% 정규화 기능을 사용하지 않고 XRF 장비를 이용하여 일반환경과 고온 환경에 노출된 시멘트페이스트를 비교 분석하였는데, 결과의 차이가 발생한 이유에 대해서 일반 시멘트 원재료와 시멘트페이스트를 비교하였을 때 차이가 발생한 이유와 동일한 측면에서 설명하였다. 또한, 이를 통해 XRF 장비를 활용하여 시멘트페이스트를 분석할 때 잠재적으로 가장 중요한 영향인자에 대해 논의하였다.

• 한국건축시공학회지
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• 제7권1호
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• pp.71-77
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• 2007

This paper is to investigate the effect of the curing temperature on strength development of concrete incorporating cement kiln dust(CKD) and blast furnace slag (BS) quantitatively. Estimation of the compressive strength of the concrete was conducted using the equivalent age equation and the rate constant model proposed by Carino. Correction of Carino model was studied to secure the accuracy of strength development estimation by introducing correction factors regarding rate constant and age. An increasing curing temperature results in an increase in strength at early age, but with the elapse of age, strength development at high curing temperature decreases compared with that at low curing temperature. Especially, the use of BS has a remarkable strength development at early age and even at later age, high strength is maintained due to accelerated pozzolanic activity resulting from high temperature. Whereas, at low curing temperature, the use of BS leads to a decrease in compressive strength. Accordingly, much attention should be paid to prevent strength loss at low temperature. Based on the strength development estimation using equivalent age equation, good agreements between measured strength and calculated strength are obtained.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2010년도 춘계 학술논문 발표대회 1부
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• pp.37-39
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• 2010

In this study, with new office construction site of S Construction company as subject, to solve all the problems according to reduced hydration heat and temperature crack of mass concrete used mat foundation and placing time difference, low heat combination of coarse particle cement and fly-ash and setting time difference applied AE water reducing agent, and to prevent the early frost damage caused by low outdoor temperature, a heat insulation method using double bubble sheet was conducted. As a result, it was found that hydration heat and setting time difference was reduced by applying a low heat combination and setting time difference construction method, and that the high insulation capability of the double bubble sheet was able to not only prevent the early frost damage but also reduce temperature difference between the central part and the upper part of mass concrete.