• Title/Summary/Keyword: low and high temperature

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Self-Cleaning and Photocatalytic Performance of TiO2 Coating Films Prepared by Peroxo Titanic Acid

  • Yadav, Hemraj M.;Kim, Jung-Sik
    • Korean Journal of Materials Research
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    • v.27 no.11
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    • pp.577-582
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    • 2017
  • Self-cleaning and photocatalytic $TiO_2$ thin films were prepared by a facile sol-gel method followed by spin coating using peroxo titanic acid as a precursor. The as-prepared thin films were heated at low temperature($110^{\circ}C$) and high temperature ($400^{\circ}C$). Thin films were characterized by X-ray diffraction(XRD), Field-emission scanning electron microscopy(FESEM), UV-Visible spectroscopy and water contact angle measurement. XRD analysis confirms the low crystallinity of thin films prepared at low temperature, while crystalline anatase phase was found the for high temperature thin film. The photocatalytic activity of thin films was studied by the photocatalytic degradation of methylene blue dye solution. Self-cleaning and photocatalytic performance of both low and high temperature thin films were compared.

Investigation of the Water Gas Shift from Reforming Gas for CO Removal (일산화탄소 저감을 위한 개질가스의 전이반응 연구)

  • Kim, Seong-Cheon;Youn, Moon-Jung;Chun, Young-Nam
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.31 no.10
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    • pp.855-859
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    • 2007
  • Hydrogen as an energy carrier in fuel cell offers perhaps the largest potential benefits of reduced emissions of pollutants and greenhouse gases. The generation of high-purity hydrogen from hydrocarbon fuels is essential for efficient operation of fuel cell. Reduction of carbon monoxide to an acceptable level of 10ppm involves high temperature and low temperature water gas shift (WGS), followed by selective oxidation of residual carbon monoxide. The WGS reactor was designed and tested in this study to produce hydrogen-rich gas with CO to less than 5000 ppm. In the water gas shift operation, gas emerges from the reformer is taken through a high temperature shift (HTS) catalyst to reduce the CO concentration to about $2{\sim}4%$ followed to about 5000 ppm via a low temperature shift (LTS) catalyst.

The Effect of an Aromatic Content on Exhaust Emissions in Low Temperature Diesel Combustion (저온 디젤 연소에서 연료의 방향족 성분이 배기가스에 미치는 영향)

  • Han, Man-Bae
    • Transactions of the Korean Society of Automotive Engineers
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    • v.19 no.3
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    • pp.106-112
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    • 2011
  • This study is to investigate the effect of an aromatic content in high cetane number (CN) fuels on exhaust emissions under low temperature diesel combustion, which expands the previous research about an aromatic content in low CN fuels. A 1.9L common rail direct injection diesel engine was run at 1500 rpm 2.6 bar BMEP with four fuel sets: an aromatic content of 20% (A20) or 45% (A45) with CN30, i.e. low CN fuels, and CN55, i.e. high CN fuels. Given experimental conditions, the trend of exhaust emissions in high CN fuels was inconsistent with that of low CN fuels which all produced nearly zero smoke but higher NOx for the high aromatic fuel (CN30-A45). For high CN fuels, however, the low aromatic fuel (CN55-A20) produced lower smoke than the high one (CN55-A45) while NOx was similar to each other. The cause of this discrepancy between high CN and low CN fuels is unclear whether it comes from that CN may be a dominant factor to govern exhaust emissions rather than an aromatic content or that the actual CN value of CN55-A45 is lower than CN55-A20. More decent fuel matrix should be prepared and further experiments are needed to confirm it.

A Preliminary Study of Low Temperature Condition by Heat Exchanger (열교환기를 이용한 저온 환경 구축에 대한 기초 연구)

  • Lee, Yang-Suk;Yang, Jae-Joon;Kim, Yoo;Ko, Young-Sung;Lim, Byeung-Jun
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2007.11a
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    • pp.23-26
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    • 2007
  • A preliminary, study of low temperature condition was performed to simulate high altitude condition. The mixed air temperature were investigated at various condition by experiments using cryogenic air by heat exchanger and normal temperature air. An experimental setup was constructed to simulate low temperature condition with liquid nitrogen. To control mass flow rate, orifice and pressure regulators were used. The experimental results show that the mixed air temperature increases linearly with mass flow rate of normal temperature air. Therefore it can be help to simulate a low temperature condition of high altitude.

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A Study on Adhesive Crosslinked in Low Temperature for High Temperature Aerospace Application (우주항공용 저온 경화 접착제의 고온 물성에 관한 연구)

  • Song, Jung Kun;Woo, Hyun Ryul;Lee, Geum Mi;Choi, Doo Hyun
    • Journal of the Korea Institute of Military Science and Technology
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    • v.22 no.2
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    • pp.215-223
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    • 2019
  • A high temperature adhesive development which is crosslinked in low temperature is necessary for aerospace application because of thermal expansion mismatches of various substrates. For this purpose, we have designed and fabricated several formulations with high temperature epoxy resins, crosslinkers and additives considering various working conditions and high service temperature. As a result, some formulations showed higher adhesive strengths than Hysol EA 9394/C2 which is widely used for aerospace applications. We also have studied and summarized the mechanical properties of the best development adhesive in both room and high temperatures.

pH- and Temperature-Sensitive Bifunctional Hydrogels of N-Isopropylacrylamide and Sulfadimethoxine Monomer

  • Lee, Jin-Woo;Lee, Doo-Sung;Kim, Sung-Wan
    • Macromolecular Research
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    • v.11 no.3
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    • pp.189-193
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    • 2003
  • pH- and temperature-sensitive bifunctional hydrogels composed of N-isopropylacrylamide (NiPAAm) and a sulfadimethoxine monomer (SDM) derived from sulfadimethoxine were prepared. These hydrogels exhibit simultaneous pH- and temperature-induced volume-phase transitions. The pH-induced volume-phase transition behavior is produced by the ionization/deionization of SDM and is very sharp. In the high pH region, the ionization of SDM induces swelling of the hydrogels. In the low pH region, the deionization of SDM induces deswelling of the hydrogels. The temperature-induced volume-phase transition behavior of the bifunctional hydrogels exhibits negative thermosensitivity because of the NiPAAm component. The hydrogels swell even at low pH as the temperature decreases. The hydrogels swell at low temperature and high pH, and deswell at high temperature and low pH. The volume of the hydrogels dependl on the balance of the swelling and deswelling produced by the two competing stimuli, pH and temperature.

Ground High/Low Temperature Test for FA-50 Aircraft (FA-50 경공격기 전기체 지상 고/저온시험)

  • Ahn, Jong Hoon;Kim, Tae Ho;Woo, Seung Cheol;Cho, Young Kyun;Kim, Do Wan
    • Journal of the Korean Society of Systems Engineering
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    • v.6 no.1
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    • pp.41-46
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    • 2010
  • The ground high/low temperature test objective is to check the normal ground operation of FA-50 aircraft in the extreme ground ambient conditions. The aircraft was exposed in climatic conditions of the basic climatic category according to the MIL-HDBK-310. For verified normal operation in the extreme high temperature, the high temperature test was performed in the hot regional type conditions and accentuated solar radiation heat. This test was performed at the test chamber in ADD where is in Haemi. This paper was described about the test procedure of FA-50 high/low temperature including preparation, testing and results.

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High Temperature Fatigue Behavior of A356 and A319 Heat Resistant Aluminum Alloys (A356 및 A319 내열 알루미늄 합금의 고온 피로 변형 거동)

  • Park, Jong-Soo;Sung, Si-Young;Han, Bum-Suck;Jung, Chang-Yeol;Lee, Kee-Ahn
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2009.10a
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    • pp.467-469
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    • 2009
  • In this study, fatigue samples were prepared from cylinder head parts that are actually used in domestic (A) and foreign (B) automobiles; high-temperature, high-cycle, and low-cycle fatigue characteristics were then evaluated and compared. A study on the correlation between the microstructural factor and high temperature fatigue characteristic was attempted. The chemical compositions of the heat resistant aluminum alloys above represented A356 (A) and A319 (B), respectively. The result of the tensile strength test on material B at $250^{\circ}C$ was higher by 30.8MPa compared to material A. On the other hand, elongation was 8.5% higher for material A. At $130{\circ}C$, material B exhibited high fatigue life given high cycle fatigue under high stress, whereas material A showed high fatigue life when stress was lowered. With regard to the low-cycle fatigue result ($250^{\circ}C$) showing higher fatigue life as ductility is increased, material A demonstrated higher fatigue life. Through the observation of the differences in microstructure and the fatigue fracture surface, an attempt to explain the high-temperature fatigue deformation behavior of the materials was made.

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Development of Ultra-high Capacitance MLCC through Low Temperature Sintering (저온소결을 통한 초고용량 MLCC 개발)

  • Sohn, Sung-Bum;Kim, Hyo-Sub;Song, Soon-Mo;Kim, Young-Tae;Hur, Kang-Heon
    • Journal of the Korean Ceramic Society
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    • v.46 no.2
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    • pp.146-154
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    • 2009
  • It is necessary to minimize the thickness of Ni inner electrode layer and to improve the coverage of inner electrode, for the purpose of developing the ultra high-capacity multi layered ceramic capacitor (MLCC). Thus, low temperature sintering of dielectric $BaTiO_3$ ceramic should be precedently investigated. In this work, the relationship between dielectric properties of MLCC and batch condition such as mixing and milling methods was investigated in the $BaTiO_3$(BT)-Dy-Mg-Ba system with borosilicate glass as a sintering agent. In addition, several chip properties of MLCC manufactured by low temperature sintering were compared with conventionally manufactured MLCC. It was found that low temperature sintered MLCC showed better DC-bias property and lower aging rate. It was also confirmed that the thickness of Ni inner electrode layer became thinner and the coverage of inner electrode was improved through low temperature sintering.

Low-Temperature Processable Charge Transporting Materials for the Flexible Perovskite Solar Cells

  • Jo, Jea Woong;Yoo, Yongseok;Jeong, Taehee;Ahn, SeJin;Ko, Min Jae
    • Electronic Materials Letters
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    • v.14 no.6
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    • pp.657-668
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    • 2018
  • Organic-inorganic hybrid lead halide perovskites have been extensively investigated for various optoelectronic applications. Particularly, owing to their ability to form highly crystalline and homogeneous films utilizing low-temperature solution processes (< $150^{\circ}C$), perovskites have become promising photoactive materials for realizing high-performance flexible solar cells. However, the current use of mesoporous $TiO_2$ scaff olds, which require high-temperature sintering processes (> $400^{\circ}C$), has limited the fabrication of perovskite solar cells on flexible substrates. Therefore, the development of a low-temperature processable charge-transporting layer has emerged as an urgent task for achieving flexible perovskite solar cells. This review summarizes the recent progress in low-temperature processable electron- and hole-transporting layer materials, which contribute to improved device performance in flexible perovskite solar cells.