• Title/Summary/Keyword: loss on ignition

Search Result 260, Processing Time 0.026 seconds

Contaminant Assessment of Dredged Material by Leaching Test - focused on the impact assessment of the coastal environment - (용출시험에 의한 항만 준설토의 오염도 평가 -해양환경에 미치는 영향평가를 중심으로-)

  • Cho, Hong-Yeon;Choi, Kwang-Hee;Yoon, Gil-Lim
    • Journal of the Korean GEO-environmental Society
    • /
    • v.2 no.2
    • /
    • pp.5-12
    • /
    • 2001
  • The physical characteristics and contaminant level of the dredged material generated by the channel maintenance and water quality improvement was analysed in a series of the study of the beneficial uses of dredged material in harbor. Dredged materials were sampled at Kunsan, Kohyun, Samchunpo, and Pohang Harbors and tested in the laboratory(leaching Test). From the experimental results, the specific gravity does not shows large differences, while almost grains are composed of silts and oyster shells except Pohang harbor containing gravels. The COD release rate and ignition loss is high in Kunsan dredged materials because of the watershed pollutants loads. The nutrient release rate is also relatively high. The release concentration of the heavy metals shows the highest values on Zn, Pb, Cd, Cu constituents at Kohyun, Kunsan, Samchunpo, Kunsan, respectively.

  • PDF

A Study on Replay Experiments and Thermal Analysis for Autoignition Phenomenon of Shredded Waste Tires (폐타이어 분쇄물의 자연발화현상에 대한 재연실험 및 열분석에 관한 연구)

  • Koh, Jae Sun;Jang, Man Joon
    • Fire Science and Engineering
    • /
    • v.26 no.6
    • /
    • pp.99-108
    • /
    • 2012
  • These days, spontaneous ignition phenomena by oxidizing heat frequently occur in the circumstances of processing and storing waste tires. Therefore, to examine the phenomena, in this work, this researcher conducted the tests of fires of fragmented waste tires (shredded tire), closely investigated components of the fire residual materials collected in the processing and storing place, and analyzed the temperature of the starting of the ignition, weight loss, and heat of reaction. For the study, this researcher conducted fire tests with fragmented waste tires in the range of 2.5 mm to 15 mm, whose heat could be easily accumulated, and performed heat analysis through DSC and TGA, DTA, DTG, and GC/MS to give scientific probability to the possibility of spontaneous ignition. According to the tests, at the 48-hour storage, rapid increase in temperature ($178^{\circ}C$), Graphite phenomenon, smoking were observed. And the result from the DTA and DTG analysis showed that at $166.15^{\circ}C$, the minimum weight loss occurred. And, the result from the test on the waste tire analysis material 1 (Unburnt) through DSC and TGA analysis revealed that at $180^{\circ}C$ or so, thermal decomposition started. As a result, the starting temperature of ignition was considered to be $160^{\circ}C$ to $180^{\circ}C$. And, at $305^{\circ}C$, 10 % of the initial weight of the material reduced, and at $416.12^{\circ}C$, 50 % of the intial weight of the material decreased. The result from the test on oxidation and self-reaction through GC/MS and DSC analysis presented that oxidized components like 1,3 cyclopentnadiene were detected a lot. But according to the result from the heat analysis test on standard materials and fragmented waste tires, their heat value was lower than the basis value so that self-reaction was not found. Therefore, to prevent spontaneous ignition by oxidizing heat of waste tires, it is necessary to convert the conventional process into Cryogenic Process that has no or few heat accumulation at the time of fragmentation. And the current storing method in which broken and fragmented materials are stored into large burlap bags (500 kg) should be changed to the method in which they are stored into small burlap bags in order to prevent heat accumulation.

Study on Bottom Mud of Shellfish Farms in Jinhae Bay (진해만 패류양식장의 저질에 관한 연구)

  • CHO Chang-Hwan;YANG Han-Serb;PARK Kyung-Yang;YOUM Mal-Ku
    • Korean Journal of Fisheries and Aquatic Sciences
    • /
    • v.15 no.1
    • /
    • pp.35-41
    • /
    • 1982
  • Phaeophytin, COD, ignition loss and sulfide contents in the superficial bottom muds in Jinhae Bay, one of the most productive bays in the southern coastal waters of Korea, were measured in the summer season 1981 to investigate the eutrophication level and the origin of pollutants, Phaeophytin contents were $7.6-48.2{\mu}g/g$, COD 9.7-38.5 mg/g, ignition loss $8.1-14.2\%$ and sulfide 0.05-1.07 mg/g. Horizontal distributions in quantities of aforementioned four parameters were almost sane patterns; that is, the further from the mouth of the bay, the more quantities were found. The worst area was the western part of Gajo-do, where density of shellfish farms was the highest in the whole bay. COD and sulfide contents in the western part of Gajo-do were much more than maximum level of the eutrophicated zone, say 30 mg/g in COD and 0.2 mg/g in sulfide. Such great quantities of organic matters and sulfide in the innermost part of the bay would be mainly due to excrements from shellfishes and fouling organisms, but not owing to the influence of pollutants discharged from Masan, Jinhae harbour and its vicinity.

  • PDF

Availability Review of Tailings from the Sangdong Tungsten Mine as a Material for Construction (건설용 재료로서 상동광산광미의 활용성 검토)

  • Kim, Yong-Jic;Kim, Young-Jin;Choi, Yun-Wang;Kim, Sang-Chel
    • Journal of the Korean Recycled Construction Resources Institute
    • /
    • v.1 no.3
    • /
    • pp.204-210
    • /
    • 2013
  • This study has focused on the possibility for recycling tailings from the Sangdong tungsten mine (TA) as admixture for concrete. TA has been accumulating for several decades in Sangdong, a region in Korea, and there is a growing demand for alternative uses for this hazardous substance. In particular, the use must be in accordance with the hazardous materials stipulations under the Korean waste control act. This study showed that TA presented pH of 8.0-9.3, 18.7-22.0% of water content, 2.7% of maximum ignition loss. The chemical composition of TA showed minute differences from each depth of sampling that represented approximately 50% of $SiO_2$ and 13% of both $Al_2O_3$ and $Fe_2O_3$. The chemical composition of Cd, Cu, Zn and Pb from mortar incorporating TA showed lower levels of hazardous materials which met the specifications of the waste control act in Korea. The TA mortar also appeared very effective for stabilizing/solidifying heavy metals particularly when used in conjunction with SG.

Reaction Characteristics of Geopolymer Paste Incorporating Fly-ash and GGBS (플라이애쉬와 고로슬래그 미분말을 혼입한 지오폴리머 페이스트의 반응특성 분석)

  • Shin, Ki-Su;Park, Ki-Bong
    • Journal of the Korea Institute of Building Construction
    • /
    • v.20 no.4
    • /
    • pp.321-330
    • /
    • 2020
  • The addition of a limestone filler(LF) to fill into the voids between cement and aggregate particles can reduce the cementitious paste volume. In previous studies, it has been found that the addition of LF to reduce the cementitious paste volume would substantially increase the compressive strength, and reduce the heat generation. This paper aim to evaluate the influence of LF contents on the hydration kinetics and compressive strength. Hydration kinetics were evaluate using heat of hydration, ignition loss and thermal analysis. The heat of hydration was measured using Isothermal Calorimetry. The degree of hydration was measured using ignition loss. Hydration product analysis was carried out by Thermal Gravimetric and Differential Thermal Analysis. The results show that the addition of LF reduces not only the initial setting time and heat of hydration peak, also degree of hydration and rate of strength development at early age increase with the addition of LF. It can be concluded the LF fills the pore between cement particles due to formation of carboaluminate, which may accelerate the setting of cement pastes.

Distribution and Pollution of Heavy metals in Surface sediments from Nakdong River (낙동강 수계 표층 퇴적물의 중금속 분포와 오염도)

  • Kim, Shin;Kim, Jueon;Lee, Kwonchul;Lee, Kyuyeol;Jeon, Hyelyn;Yu, Jaejung;Lee, Injung;Ahn, Jungmin
    • Journal of Environmental Science International
    • /
    • v.24 no.8
    • /
    • pp.969-980
    • /
    • 2015
  • In order to certificate the distribution and pollution of heavy metal of surface sediments in Nakdong River were collected and analyzed for grain size, water content, ignition loss and heavy metal content. Surface sediments mainly composed of sand(avg. 94.6%) and water content and ignition loss were 20.46%, 1.53% on average. Grain size were relatively fine and organic matter content were relatively high in the Hoichun and Sunakdonggang. Most of heavy metal content(Zn > Cr > Pb > Ni > Cu > Hg) in the Deokcheongang and Sunakdonggang were higher than the other streams. The Igeo were non polluted(less than 0) in all streams and the EF were relatively high in the small stream and PLI were non polluted(less than 1). In addition, organic matter, heavy metal content and pollution were highly correlation with grain size. Surface sediments in study area, heavy metal pollution of the Sunakdonggang were relatively high compared to the other stream but these results were not serious pollution that exceed the sediment pollution evaluation standard of river and lake in Korea and pollution levels adversely affected the majority of benthos were not.

Eutrophication in the Namhae Coastal Sea 2. The Aspects of Eutrophication of Bottom Mud and Surface Seawater in the Namhae Coastal Seas (남해 연안해역의 부영양화 2. 남해 연안해역의 저질 및 수질의 부영양화 실태)

  • Kim, Sung-Jae
    • Journal of Wetlands Research
    • /
    • v.3 no.2
    • /
    • pp.107-118
    • /
    • 2001
  • The aim of this paper is to grasp eutrophication aspects in Namhae coastal seas, statistically analyzing existing data for their surface seawater and bottom mud. A pollution level(ignition loess) of bottom mud, on the whole, trended to increase as moving the coastal sea around Mokpo-Wando toward the east(Gyeongnam Namhae coastal seas). Especially, the pollution level(ignition loss=10.5%) of bottom mud for the coastal sea around Tongyeong-Keoje-Gosung was similar to that(10.3%) for the coastal sea around Masan-Jinhae, whose coastal marine pollution was the severest in Namhae coastal seas. It indicates that large amounts of pollutant from aqualculture facilities have been, thus far, accumulated on the coastal sea around Tongyeong-Keoje-Gosung, considering there was no significant inflow of sewage and industrial wastewater into this coastal sea. A COD, T-N, and T-P level of surface seawater, on the whole trended to increase as moving the coastal sea around Mokpo-Wando toward the east(Gyeongnam Namhae coastal seas). A COD level appeared to be the second grade of coastal water quality over the entire year throughout all Namhae coastal seas A T-N level exceeded the third grade of coastal water quality throughout all Namhae coastal seas except the coastal sea around Mokpo-Wando. Especially, a T-N level exceeded as many as three and six times over the third grade of coastal water quality in the coastal sea around Tongyeong-Keoje-Gosung and Masan-Jinhae, respectively. A T-P level appeared to be the second grade of coastal water quality in the coastal sea around Mokpo-Wando and the third grade of coastal water quality in the coastal sea around Yosu-Narnhae and Tongyeong-Keoje-Gosung, while it exceeded as many as two times over the third grade of coastal water quality. A degree of eutrophication of the surface seawater was 1.5 in the coastal sea around Mokpo-Wando and 11.9 In the coastal sea around Tongyeong-Keoje-Gosung, gradually increasing as moving toward the east(Gyeongnam Narnhae coastal seas). It sharply increased to 146.1 in the coastal sea around Masan-Jinhae. Because the degree of eutrophication throughout all Namhae coastal seas exceeded 1, a red tide organism could pose a possibility of proliferation at any place of Namhae coastal seas if other requirements were satisfied. It indicates that a red tide may move to another place once a red tide breaks out at a place of Namhae coastal seas.

  • PDF

Study on Explosion Behavior of Air-born Rice Bran Dusts according to Ignition Energy (점화에너지 변화에 따른 쌀겨분진의 폭발 거동에 관한 연구)

  • 김정환;김현우;현성호;백동현
    • Fire Science and Engineering
    • /
    • v.13 no.2
    • /
    • pp.26-32
    • /
    • 1999
  • We had investigated combustion pro야$\pi$ies of rice bran dusts. Decomposition of rice bran d dusts with temperature were investigated using DSC and the weight loss according to t temperature using TGA in order to find the thermal hazard of rice bran dusts, and the p properties of dust explosion in variation of their dust with the same particle size. Using H Hartman's dust explosion apparatus which estimate dust explosion by electric ignition after m making dust disperse by compressed air, dust explosion experiments have been conducted by v varying concen$\sigma$ation and size of rice br뻐 dust. According to the results for thermodynamic stability of rice bran dust, there are little change of initiation temperature of heat generation 때d heating value for used particle size. But i initiation temperature of heat generation decreased with high heating rate whereas d decomposition heat increased with particle size. Also, the explosion pressure was increased as t the ignition energy increased and average maximum explosion pressure was 13.5 kgv'cnt for 5 BJ/60 mesh and 1.5 뼈Ie미 dust concentration.

  • PDF

A Study on Factory Building Fire Risk Reduction Management (공장건물의 화재리스크 경감방안에 관한 연구)

  • Chung, Eui-Soo;Kang, Kyung-Sik
    • Journal of the Korea Safety Management & Science
    • /
    • v.10 no.3
    • /
    • pp.43-53
    • /
    • 2008
  • This study is carried out for the fire safety of the factory building, the fire risk reduction measure in compliance with an example approached in fire risk reduction systematically, contribute to reduce the fire risk. The analytical fire risk process of discovering, identifying, estimating and evaluating risk and control measure as risk reduction measures are core concept, applies loss prevention with loss control techniques. The painting process in the workplace where the fire hazard and death accident accompanies coexists. Loss prevention problem of creation prevention of dangerous atmosphere at workplace is health and human services problem of normal circumstances, must be inspected with problem of combustible gases at the time of fire explosion. Static electricity measure accomplished the risk control process thoroughly as the fire risk reduction process model with the ignition sources measure which is presented. Fire risk from within organizing will be able to classify with each field by detailedly but risk treatment process will be able to apply basically all the same concept. Consequently about risk management example from before, this study is proposed risk management techniques that standardized rightly in the actual condition of organization with one plan, with discovery of fire risk, the feedback process in compliance with a fire risk reduction and the review which control the result is joint responsibility of engineer, technical expert and manager as part of safety management to practice with the fact must be supervised.

A mechanistic analysis of H2O and CO2 diluent effect on hydrogen flammability limit considering flame extinction mechanism

  • Jeon, Joongoo;Kim, Yeon Soo;Jung, Hoichul;Kim, Sung Joong
    • Nuclear Engineering and Technology
    • /
    • v.53 no.10
    • /
    • pp.3286-3297
    • /
    • 2021
  • The released hydrogen can be ignited even with weak ignition sources. This emphasizes the importance of the hydrogen flammability evaluation to prevent catastrophic failure in hydrogen related facilities including a nuclear power plant. Historically numerous attempts have been made to determine the flammability limit of hydrogen mixtures including several diluents. However, no analytical model has been developed to accurately predict the limit concentration for mixtures containing radiating gases. In this study, the effect of H2O and CO2 on flammability limit was investigated through a numerical simulation of lean limit hydrogen flames. The previous flammability limit model was improved based on the mechanistic investigation, with which the amount of indirect radiation heat loss could be estimated by the optically thin approximation. As a result, the sharp increase in limit concentration by H2O could be explained by high thermal diffusivity and radiation rate. Despite the high radiation rate, however, CO2 with the lower thermal diffusivity than the threshold cannot produce a noticeable increase in heat loss and ultimately limit concentration. We concluded that the proposed mechanistic analysis successfully explained the experimental results even including radiating gases. The accuracy of the improved model was verified through several flammability experiments for H2-air-diluent.