• Title/Summary/Keyword: loss on ignition

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A Study on Noxious Gases Analysis of Polyurethane foams (Polyurethane foam의 유해가스 분석에 관한 연구)

  • 이창우;김정환;현성호
    • Fire Science and Engineering
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    • v.14 no.2
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    • pp.7-13
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    • 2000
  • We had investigated thermal stability, Ignition temperature and fire gas for polyurethane foams used for manikin, cushion and interior finishing material. Decomposition of polyurethane foams with temperature was investigated using a DSC and the weight loss with temperature increase using a TGA in order to find the thermal hazard of polyurethane foams, and the ignition temperature of polyurethane foams according to species. We studied constant temperature among ignition temperature measuring methods. In addition, noxious gases for polyurethane foams according to combustion condition were analyzed using gas analyzer and GASTEC. As results, initial decomposition temperature of polyurethane foam used for interior finishing material was lower than those for manikin and cushion, and exothermic energy was higher. Ignition temperature of polyurethane foam of interior finishing material was $420^{\circ}$. All of combustion forms at $427^{\circ}$ and under were smoldering combustion, and it was combustion at $500^{\circ}$. As furnace temperature was increased, concentration of noxious gases such as carbon oxide, carbon dioxide, and hydrogen cyanide was increased. And nitrogen oxide at combustion condition($500^{\circ}$) was over 10 ppm.

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A Study on the Quality of the Domestic Fly Ash as an Additive for Concrete (콘크리트용 혼화재(混和材)로서 국산 플라이애쉬의 품질에 관한 실험적 연구)

  • Moon, Han Young;Seo, Joung Woo
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.7 no.3
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    • pp.213-221
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    • 1987
  • To use fly ash as an additive for concrete, authors collected 15 kinds of domestic fly ashes and tested the chemical compositions and physical properties of the fly ashes. Fluidity of the fly ash paste was also investigated. The result shows that the chemical compositions of the fly ashes were in the range of regulation of Korean Industrial Standards except ignition loss and the following relationships in fly ash were studied; specific surface and residue in standard sieve, specific surface and unit weight, residue in standard sieve and ignition loss. For the given flow properties, fly ash paste required higher water-binder ratio than cement paste.

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Fabrication of Activated Alumina Using Aluminum Hydroxide by a Hydrothermal Process (수산화알루미늄으로부터 수열법을 이용한 활성 알루미나 제조에 관한 연구)

  • Bae, Hyeon Cheol;Lee, Sang-Jin
    • Journal of the Korean Ceramic Society
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    • v.50 no.6
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    • pp.384-389
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    • 2013
  • Activated alumina was fabricated with aluminum hydroxide in this study. High-purity alumina gel and boehmite were prepared from aluminum hydroxide by a hydrothermal process and fired to activate alumina having a surface area of 380 ~ 480 $m^2/g$ with less loss of ignition. The aging and drying condition during the fabrication process affected the loss of ignition, the sedimentation time of the alumina suspension, as well as the surface area of the activated alumina. For pellet-type activated alumina, the pre-fired alumina gel and boehmite were press-formed and fired at $400^{\circ}C$ and $550^{\circ}C$ for 6 h, respectively. The fired pellets showed a low density of 2.0 ~ 2.2 $g/cm^3$ with 20% firing shrinkage and sufficient handling strength. In this study, a new fabrication process for high-quality activated alumina with aluminum hydroxide is introduced. The effects of the processing parameters on the activated alumina properties are also examined.

Effects of Perforated Throttle Valve on the Mixture Flow and Secondary Atomization of Fuel Spray (다공스로틀밸브가 혼합기 유동과 연료 분무의 2차 미립화에 미치는 영향)

  • Cho, B.O.;Cho, H.M.;Lee, C.S.
    • Journal of ILASS-Korea
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    • v.1 no.3
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    • pp.60-66
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    • 1996
  • Finely atomized fuel droplet and good mixed mixture plays very important in improving combustion efficiency in an spark ignition engine. And combustion efficiency has influence directly on the engine power, fuel consumption rate and pollutant emission. In this study, perforated throttle valve which has relatively low value of PR has been developed and studied for the purpose of improving those aims. As a result of this study, it has been verified that the perforated throttle valve makes droplet more finely, and also proved that has a function of contributing to form good mixed mixture, especially in mixture preparation system of carburetor or SPI type spark ignition engine.

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A Fundamental Study on the Estimation of Unit Cement Content in Hardened Concrete (Test Method by Sodium Gluconate) (경화 콘크리트의 단위 시멘트량 추정 방법에 관한 기초적 연구)

  • 김광서;유영호;박도경
    • Proceedings of the Korea Concrete Institute Conference
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    • 1996.04a
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    • pp.24-29
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    • 1996
  • The purpose of this study is to propose new estimation method of unit cement content in hardened concrete. In general, the quantity of cement in hardened concrete is tested by hydrochlonic acid dissolving cement paste, however, hydrochloric acid dissolves sea shell contained in sea sand and lime stone in concrete. Therefore, the tested cement content is apt to estimate greater than actual cement content. The sodium gluconate solution dissolves only cement in concrete, it is hard to dissolve sea shell and lime stone as CaCo3. The effects of the quantity, concentration and temperature of sodium gluconate solution, the ignition temperature, the ignition loss of cement on the cement content and the percentage of dissolution of cement were investigated to establish a test method. From the results of these tests, the fundamental test method for cement content of hardened concrete by sodium gluconate is proposed.

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Analysis of Energy Losses in a Natural Gas Spark Ignition Engine for Power Generation (천연가스 스파크점화 엔진 발전기에서의 에너지 손실 분석)

  • Park, Hyunwook;Lee, Junsun;Oh, Seungmook;Kim, Changup;Lee, Yongkyu;Kang, Kernyong
    • Journal of ILASS-Korea
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    • v.25 no.4
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    • pp.170-177
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    • 2020
  • Stoichiometric combustion in spark ignition (SI) engines has an advantage of meeting future stringent emission regulations. However, the drawback of the combustion is a lower thermal efficiency than that of lean burn. In this study, energy losses in a natural gas stoichiometric SI engine generator were analyzed to establish a strategy for improving the generating efficiency (GE). The energy losses were investigated based on dynamometer and load bank experiments. As the intake manifold pressure increased in the dynamometer experiment, the brake thermal efficiency (BTE) increased mainly due to the reduction in the pumping and mechanical losses. In the load bank experiment, the generating power and GE increased with the increased intake manifold pressure. The generating power and GE were lower than the brake power and BTE due to the cooling fan power and the losses in the generator.

A Study on the Minimum Ignition Limit Voltages for LPG-Air Mixtures by Discharge Sparks in Radio-frequency Circuits (고주파 전기회로의 개폐불꽃에 의한 LPG-공기 혼합가스의 최소점화한계전압에 관한 연구)

  • Lee Chun-ha;Kim Jae-ouk;Jee Sung-ouk;Song Hun-jik;Lee Gang-sik;Lee Dong-in
    • Journal of the Korean Institute of Gas
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    • v.2 no.4
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    • pp.79-84
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    • 1998
  • This paper describes the minimum ignition limit voltages for LPG-Air 5.25[Vol$\%$] mixture gas by discharge sparks in radio-frequency limits using RF power supply and IEC type ignition spark apparatus. As a result, the minimum ignition limit voltages is increased in proportional to the rate of increasing of frequency in LPG-Air mixture gas. Especially, the minimum ignition limit voltages increase remarkably between 3[KHz] and 10[KHz]. It is considered that ignition is caused by one discharge until 3[KHz] and, beyond 3[KHz] ignitiof is caused by more than two discharges. The reason is analyzed that energy loss is caused by existing pause interval between discharges. It is considered that the result can be used for not only data for researches and development of intrinsically safe explosion-proof RF machines which are applied tole-equipments and detectors used in dangerous areas but also for datum for its equipment tests.

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A Study on the Distributional Characteristic of Organic Matters on the Surface Sediments and Its Origin in Keogeum-sudo, Southern Part of Korean Peninsula (거금수도(居金水道) 표층퇴적물 중의 유기물 분포 및 기원에 관한 연구)

  • 윤양호
    • Journal of Environmental Science International
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    • v.9 no.2
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    • pp.137-144
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    • 2000
  • The observations on the seasonal fluctuation and distributional characteristic of organic matters on surface sediments and its origin were carried out at the 25 stations in Keogeum-sudo, southern coast of Korean Peninsula from February to October in 1993. I made an analysis on the environmental factors for surface sediments such as temperature, ignition loss, chemical oxygen demand, pheopigment, total sulphide, water content, mud content in grain size, COD/IL ratio and COD/sulphide ratio. The results are as follows ; 1) The range of temperature on the surface sediments was between 6.2${\circ}C$ and 24.6${\circ}C$. The highest mean temperatuer of mud was 24.0${\circ}C$ in summer, the lowest 6.6${\circ}C$ in winter. 2) Ignition loss(IL) fluctuated between 1.2% in winter and 16.8% in spring, that is to say, the seasons of increasing in temperature were very high ignition loss. 3) Chemical oxygen demand(COD) showed the highest mean value of 20.52 mg/g dry in summer within the range of 15/46~32.78 mg/g dry, while showed the lowest of 5.79 mg/g dry in winter within the range of 7.4~17.39 mg/g dry. 4) Pheopigment concentrations showed the highest mean value of 4.85 $\mu\textrm{g}$/g dry in autumn within the range of 0.84~9.21 $\mu\textrm{g}$/g dry, while it did the lowest mean value of 1.97 $\mu\textrm{g}$/g dry in summer within the range of 0.23~4.83 $\mu\textrm{g}$/g dry. 5) Total sulphide (H2S) fluctuated between no detect(ND) in spring, and 2.43 mg/g dry in sutumn. The highest mean value was 0.68 mg/g dry in sutumn, the lowest was 0.16 mg/g dry in spring. 6) Water content(WC) and mud content in grain size showed the mean value of 43.2% within the range of 26.5~59.7% and 91.0% within the range of 57.8~99.2%, respectively. 7) By the analytical results on the source of organic matter, it had been dumped from the seaweed farms in Keogeum-sudo coastal waters.

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A Study on the Development of Simulating Tool for Evaluation of Electrostatic Discharge (정전기 방전 평가를 위한 간이형 도구 개발에 관한 연구)

  • Choi, Sang-Won
    • Journal of the Korean Society of Safety
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    • v.26 no.3
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    • pp.15-22
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    • 2011
  • Explosion and fire cause about 30 reported industrial major accidents a year by ignition source which discharge of electrostatic generated to flammable gas, vapor, dust and mixtures. It brings economically and humanly very large loss that accident was caused by fire and explosion from electrostatic discharge. Thus, it is very important that electrostatic discharge energy is to be control below not to be igniting flammable mixtures. There are two kinds of analysis model for electrostatic discharge, human body model and machine model. Human body model is available the parameter of human's electrical equivalent that capacitance is 100 pF, resistance is $1.5k{\Omega}$. To simulate and visualize the electrostatic discharge from human body need a very expensive and high voltage simulator. In this paper, we measured the value of capacitance and resistance concerned with test materials and sizing of specimen and the value of charged voltage concerned with test specimen and distance to develop an electrostatic charge/discharge simulating tool for teaching with which concerned industrial employee and students. The result of experiments, we conformed that the minimum ignition energy of methane-oxygen mixtures meets well the equation $W=1/2CV^2$, and found out that the insulating material and sizing of equivalent value having human body mode are the poly ethylene of 200 mm and 300 mm of diameter. Developed electrostatic charge/discharge simulating tool has many merits; simple mechanism, low cost, no need of electric power and so on.

A Study on the Risk of Spontaneous ignition to Butadiene Popcorn Polymer (Butadiene Popcorn Polymer의 자연발화 위험성에 관한 연구)

  • Koo, Chae-Chil;Lee, Jung-Suk;Choi, Jae-Wook
    • Fire Science and Engineering
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    • v.33 no.2
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    • pp.1-8
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    • 2019
  • This study was conducted to investigate the possibility of spontaneous ignition in Butadiene popcorn polymer, which is used as raw material and product in a chemical plant. A component analysis, thermogravimetric analysis, thermal stability analysis, spontaneous ignition point measurement and accelerated velocity calorimetric analysis were performed. As a result of analysis, various kinds of flammable components were measured and thermogravimetric analysis showed a weight loss of 95.6% in air and 89.2% in nitrogen. As a result of the thermal stability analysis, heat generation started at $88^{\circ}C$ in the air atmosphere, and the heat generation rate increased sharply in the vicinity of the natural ignition point ($220^{\circ}C$). The heat generation started at about $70^{\circ}C$ in nitrogen atmosphere, and the two exothermic peak values were observed up to $450^{\circ}C$. As a result of accelerated rate calorimetry, there was no exothermic phenomenon, and the lowest ignition temperature was $211.7^{\circ}C$ as a result of analysis of natural ignition point. Based on the results obtained from the thermal stability evaluation, it is considered that the possibility of inducing the thermal deformation of the column by the heat of reaction is sufficient.