• 제목/요약/키워드: loss modulus

검색결과 371건 처리시간 0.027초

Effect of Phenyl Vinyl Methyl Silicone (PVMQ) on Low Temperature Sealing Performance of Fluorosilicone Composites

  • Lee, Jin Hyok;Bae, Jong Woo;Choi, Myoung Chan;Yun, Yu-Mi;Jo, Nam-Ju
    • Elastomers and Composites
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    • 제56권4호
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    • pp.209-216
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    • 2021
  • In this study, we observed the mechanical properties, thermal stability, and low temperature sealing performance of fluorosilicone elastic composites. When the blend ratio of Phenyl vinyl methyl silicone (PVMQ) was increased, the tensile strength, modulus at 100%, and compression set were decreased. The thermal stability of fluorosilicone elastic composites showed a similar tendency. These were caused by poorer green strength of PVMQ than Fluorosilicone rubber (FVMQ). The change in the tensile strength and elongation at -40℃ showed a decreasing tendency with increasing PVMQ blend ratio. By increasing the PVMQ blend ratio, low-temperature performance was improved. The Dynamic mechanical analysis (DMA) results showed that Tg was decreased and low-temperature performance was improved with increasing PVMQ blend ratio. However tanδ was decreased becaused of the poor green strength and elasticity of PVMQ. From a hysteresis loss at -40℃, the hysteresis loss value was increased and fluorosilicone elastic composites showed the decreasing tendency of elasticity with increasing PVMQ blend ratio. From the TR test, TR10 was decreased with increasing PVMQ blend ratio. FS-4 (45% PVMQ blended composites) showed a TR10 of -68.0℃ that was 5℃ lower than that of FS-1 (100% FVMQ). The gas leakage temperature was decreased with increasing PVMQ blend ratio. The gas leakage temperature of FS-4 was -69.2℃ that was 5℃ lower than that of FS-1. Caused by the polymer chain started to transfer from a glassy state to a rubbery state and had a mobility of chain under Tg, the gas leakage temperature showed a lower value than Tg. The sealing performance at low temperature was dominated by Tg that directly affected the mobility of the polymer chain.

Vibroacoustic response of thin power law indexed functionally graded plates

  • Baij Nath Singh;Vinayak Ranjan;R.N. Hota
    • Steel and Composite Structures
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    • 제50권3호
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    • pp.299-318
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    • 2024
  • The main objective of this paper is to compute the far-field acoustic radiation (sound radiation) of functionally graded plates (FGM) loaded by sinusoidally varying point load subjected to the arbitrary boundary condition is carried out. The governing differential equations for thin functionally graded plates (FGM) are derived using classical plate theory (CPT) and Rayleigh integral using the elemental radiator approach. Four cases, segregated on power-law index k=0,1,5,10, are studied. A novel approach is illustrated to compute sound fields of vibrating FGM plates using the physical neutral surface with an elemental radiator approach. The material properties of the FGM plate for all cases are calculated considering the power law indexes. An in-house MATLAB code is written to compute the natural frequencies, normal surface velocities, and sound radiation fields are analytically calculated using semi-analytical formulation. Ansys is used to validate the computed sound power level. The parametric effects of the power law index, modulus ratios, different constituent of FGM plates, boundary conditions, damping loss factor on the sound power level, and radiation efficiency is illustrated. This work is the benchmark approach that clearly explains how to calculate acoustic fields using a solid layered FGM model in ANSYS ACT. It shows that it is possible to asymptotically stabilize the structure by controlling the intermittent layers' stiffness. It is found that sound fields radiated by the elemental radiators approach in MATLAB, ANSYS and literatures are in good agreement. The main novelty of this research is that the FGM plate is analyzed in the low-frequency range, where the stiffness-controlled region governs the whole analysis. It is concluded that a clamped mono-ceramic FGM plate radiates a lesser sound power level and higher radiation efficiency than a mono-metallic or metal-rich FGM plate due to higher stiffness. It is found that change in damping loss factor does not affect the same constituents of FGM plates but has significant effects on the different constituents of FGM plates.

4종의 간접법용 복합 레진의 기계적 특성 비교 (COMPARISON OF MECHANICAL PROPERTIES IN 4 INDIRECT COMPOSITE RESIN)

  • 김길수;윤태호;송광엽;안승근
    • 대한치과보철학회지
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    • 제45권1호
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    • pp.21-33
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    • 2007
  • Statement of problem: The esthetic component of dental care has become increasingly more important, while new tooth-colored materials are continually marketed. Various new indirect composite materials have been developed with required advantages. The most recent development in the indirect composites has been the introduction of the second-generation laboratory composite or poly-glass materials. They are processed by different laboratory techniques based on combinations of heat, pressure, vacuum and light polymerization. Although, second generation products became available in 1995, their characteristics and clinical performance have not been adequately investigated. Purpose: The aim of this study was to measure the mechanical properties of the second generation indirect resin system and compare these with an existing universal direct composite resin. Material and method: In this study four indirect composite material (Adoro LC, BelleGlass HP, Tescera, Synfony) were tested for flexural strength, wear resistance, hardness and their degree of conversion against Z250, a light cure direct composite. Results: Within the limitations of this study, the following conclusions were drawn: 1. From the abrasion wear result, Adoro showed the least volume loss while Synfony showed the greatest volume loss. Z250 and BelleGlass HP didn't show significant difference (p>0.05), but they showed significant difference with other groups (p<0.05). From the attrition wear, BelleGlass HP showed the least volume loss and it didn’t show significant difference with Tescera (p>0.05). While Synfony showed the greatest volume loss that it showed significant difference with other groups (p>0.05). 2. Mean values of flexural strength by means of three point bending test was in the order of Z250, Adoro, Belleglass HP, Tescera and Synfony. Mean elastic modulus was in the order of Z250, BelleGlass HP, Tescera, Adoro and Synfony. 3. The result of Vicker‘s microhardness value showed that significantly higher value in Z250 (p<0.05), and is in the order of BelleGlass HP, Tescera, Adoro and Synfony. 4. The degree of conversion measured by FT-IR showed significantly higher value in BelleGlass HP (p<0.05), and is in the order of Adoro, Synfony, Tescera and Z250. Conclusion: Significant differences were found in the flexural strength, wear resistance, hardness and their degree of conversion.

Improved Thermal, Structural and Electrical Properties of Elastic-Epoxy Blends System

  • Lee, Kyoung-Yong;Lee, Kwan-Woo;Choi, Yong-Sung;Park, Dae-Hee
    • KIEE International Transactions on Electrophysics and Applications
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    • 제4C권5호
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    • pp.230-235
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    • 2004
  • In this paper, epoxy elasticity factors were investigated by TMA (Thermomechanical Analysis), DMTA (Dynamic Mechanical Thermal Analysis) and FESEM (Field Emission Scanning Electron Microscope) to improve toughness and reduce brittleness of existing epoxy resin. Dumbbell shaped specimens were made and tested at rates of 0, 20 and 35phr (part per hundred resins). TMA temperatures ranged from -2$0^{\circ}C$ to 20$0^{\circ}C$. Tg (glass transition temperature) of elastic epoxy was measured by thermal analysis. Also investigated were thermal expansion coefficient ($\alpha$), modulus and Tan$\delta$ (loss factor). And we analyzed structure through FESEM, could find elastic-factors of elastic epoxy that is not existing-epoxy. In addition, we measured permittivity and Tan$\delta$ for investigation of the electrical properties of elastic epoxy. Permittivity and Tan$\delta$ depend on elastomer composition. Namely, permittivity and Tan$\delta$ increase according to the elastomer contents. For experimental analysis results, 20phr was considered an excellent specimen.

Rheological Behavior of Sweet Potato Starch-Glucose Composites

  • Cho, Sun-A;Yoo, Byoung-Seung
    • Food Science and Biotechnology
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    • 제17권2호
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    • pp.417-420
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    • 2008
  • Rheological properties of sweet potato starch (SPS)-glucose composites (5%, w/w) at different concentrations (0, 10, 20, and 30%, w/w) of glucose were investigated in steady and dynamic shear. The steady shear rheological properties of SPS-glucose composites were determined from rheological parameters for power law and Casson flow models. At $25^{\circ}C$ all the samples showed a pronounced shear-thinning behaviors (n=0.29-0.37) with high Casson yield stress. In general, the presence of glucose resulted in the decrease in consistence index (K), apparent viscosity (${\eta}_{a,100}$), and yield stress (${\sigma}_{oc}$). Storage (G') and loss (G") moduli increased with an increase in frequency ($\omega$), while complex viscosity (${\eta}*$) decreased. Dynamic moduli (G', G", and ${\eta}*$) of the SPS-glucose composites at higher glucose concentrations (20 and 30%) were higher than those of the control (0% glucose) and also increased with increasing glucose concentration from 10 to 30%. The effect of glucose on steady and dynamic shear rheological properties of the SPS pastes appears to greatly depend on glucose concentration in the range of 10-30%.

Effect of fabrication processes on mechanical properties of glass fiber reinforced polymer composites for 49 meter (160 foot) recreational yachts

  • Kim, Dave Dae-Wook;Hennigan, Daniel John;Beavers, Kevin Daniel
    • International Journal of Naval Architecture and Ocean Engineering
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    • 제2권1호
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    • pp.45-56
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    • 2010
  • Polymer composite materials offer high strength and stiffness to weight ratio, corrosion resistance, and total life cost reductions that appeal to the marine industry. The advantages of composite construction have led to their incorporation in U.S. yacht hull structures over 46 meters (150 feet) in length. In order to construct even larger hull structures, higher quality composites with lower cost production techniques need to be developed. In this study, the effect of composite hull fabrication processes on mechanical properties of glass fiber reinforced plastic (GFRP) composites is presented. Fabrication techniques investigated during this study are hand lay-up (HL), vacuum infusion (VI), and hybrid (HL+VI) processes. Mechanical property testing includes: tensile, compressive, and ignition loss sample analysis. Results demonstrate that the vacuum pressure implemented dining composite fabrication has an effect on mechanical properties. The VI processed GFRP yields improved mechanical properties in tension/compression strengths and tensile modulus. The hybrid GFRP composites, however, failed in a sequential manor, due to dissimilar failure modes in the HL and VI processed sides. Fractography analysis was conducted to validate the mechanical property testing results.

Time-dependent properties of lightweight concrete using sedimentary lightweight aggregate and its application in prestressed concrete beams

  • Chen, How-Ji;Tsai, Wen-Po;Tang, Chao-Wei;Liu, Te-Hung
    • Structural Engineering and Mechanics
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    • 제39권6호
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    • pp.833-847
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    • 2011
  • We have developed a lightweight aggregate (LWA) concrete made by expanding fine sediments dredged from the Shihmen Reservoir (Taiwan) with high heat. In this study, the performance of the concrete and of prestressed concrete beams made of the sedimentary LWA were tested and compared with those made of normal-weight concrete (NC). The test results show that the lightweight concrete (LWAC) exhibited comparable time-dependent properties (i.e., compressive strength, elastic modulus, drying shrinkage, and creep) as compared with the NC samples. In addition, the LWAC beams exhibited a smaller percentage of prestress loss compared with the NC beams. Moreover, on average, the LWAC beams could resist loading up to 96% of that of the NC beams, and the experimental strengths were greater than the nominal strengths calculated by the ACI Code method. This investigation thus established that sedimentary LWA can be recommended for structural concrete applications.

Probabilistic analysis of spectral displacement by NSA and NDA

  • Devandiran, P.;Kamatchi, P.;Rao, K. Balaji;Ravisankar, K.;Iyer, Nagesh R.
    • Earthquakes and Structures
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    • 제5권4호
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    • pp.439-459
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    • 2013
  • Main objective of the present study is to determine the statistical properties and suitable probability distribution functions of spectral displacements from nonlinear static and nonlinear dynamic analysis within the frame work of Monte Carlo simulation for typical low rise and high rise RC framed buildings located in zone III and zone V and designed as per Indian seismic codes. Probabilistic analysis of spectral displacement is useful for strength assessment and loss estimation. To the author's knowledge, no study is reported in literature on comparison of spectral displacement including the uncertainties in capacity and demand in Indian context. In the present study, uncertainties in capacity of the building is modeled by choosing cross sectional dimensions of beams and columns, density and compressive strength of concrete, yield strength and elastic modulus of steel and, live load as random variables. Uncertainty in demand is modeled by choosing peak ground acceleration (PGA) as a random variable. Nonlinear static analysis (NSA) and nonlinear dynamic analysis (NDA) are carried out for typical low rise and high rise reinforced concrete framed buildings using IDARC 2D computer program with the random sample input parameters. Statistical properties are obtained for spectral displacements corresponding to performance point from NSA and maximum absolute roof displacement from NDA and suitable probability distribution functions viz., normal, Weibull, lognormal are examined for goodness-of-fit. From the hypothesis test for goodness-of-fit, lognormal function is found to be suitable to represent the statistical variation of spectral displacement obtained from NSA and NDA.

건조 스트레스에 따른 황칠나무 유묘의 광합성과 수분특성인자 변화 (Changes in Photosynthetic Performance and Water Relation Parameters in the Seedlings of Korean Dendropanax Subjected to Drought Stress)

  • 이경철
    • 한국약용작물학회지
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    • 제26권2호
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    • pp.181-187
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    • 2018
  • Background: This study aimed to investigate out the influence of drought stress on the physiological responses of Dendropanax morbifera seedlings. Methods and Results: Drought stress was induced by discontinuing water supply for 30 days. Under drought stress, photosynthetic activity was significantly reduced with decreasing soil water content (SWC), as revealed by the parameters such as Fv/Fm, maximum photosynthetic rate ($P_{N\;max}$), stomatal conductance ($g_s$), stomatal transpiration rate (E), and intercellular $CO_2$ concentration (Ci). However, water use efficiency (WUE) was increased by 2.5 times because of the decrease in $g_s$ to reduce transpiration. Particularly, E and $g_s$ were remarkably decreased when water was withheld for 21 days at 6.2% of SWC. Dendropanax morbifera leaves showed osmotic adjustment of -0.30 MPa at full turgor and -0.13 MPa at zero turgor. In contrast, the maximum bulk modulus of elasticity ($E_{max}$) did not change significantly. Thus, Dendropanax morbifera seedlings could tolerate drought stress via osmotic adjustment. Conclusions: Drought avoidance mechanisms of D. morbifera involve reduction in water loss from plants, through the control of stomatal transpiration, and reduction in cellular osmotic potential. Notably photosynthetic activity was remarkably reduced, to approximately 6% of the SWC.

붕규산유리 및 비정질 붕소강 섬유를 혼입한 콘크리트의 역학적 성능 및 중성자 차폐성능 평가 (Mechanical Properties and Neutron Shielding Rate of Concrete with Borosilicate-Glasses and Amorphous Boron Steel Fiber)

  • 이준철
    • 한국건설순환자원학회논문집
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    • 제4권3호
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    • pp.269-275
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    • 2016
  • 본 연구에서는 붕규산 유리와 비정질 붕소강 섬유를 혼입한 콘크리트의 역학적 성능 및 중성자 차폐성능을 평가하였다. 잔골재를 붕규산 유리로 치환한 콘크리트와 비정질 붕소강 섬유를 보강한 콘크리트를 제조하여 압축강도, 정탄성계수, 압축인성, 휨강도, 휨인성, 중성자 차폐성능을 평가하였다. 실험결과, Plain 콘크리트와 대비하여 붕규산 유리를 혼입한 콘크리트의 경우 압축강도 및 휨강도는 저하되었으나, 중성자 차폐성능은 향상되는 것으로 나타났다. 비정질 붕소강 섬유를 혼입한 콘크리트의 경우 Plain 콘크리트와 대비하여 압축인성 및 휨인성이 증진되었으며 중성자 차폐성능도 향상되는 것으로 나타났다.