• Applied Chemistry for Engineering
• /
• v.3 no.3
• /
• pp.422-429
• /
• 1992

The morphology and adhesion properties of rubber compounds containing resorcinol formaldehyde(RF) resin and hexamethoxymethylmelamine(HMMM) used in adhesion of rubber to brass-plated steel cord was investigated. The resins were spherical particles about $2000{\AA}$ diameter and distributed in rubber compounds homogeneously, and the cured compound with steel cord showed migration of resin to steel cord. Also, modulus was increased with increasing HMMM contents. The loss of adhesion between rubber and steel cord was likely to be at initial stages by thermal aging. Considering the physical properties, suability of adhesion layer and thermal aging property, optimum ratio of RF resin and HMMM was 1 : 0.9.

• Composites Research
• /
• v.32 no.2
• /
• pp.113-119
• /
• 2019

The objective of this research is to study the mechanical and vibration characteristics of vibration damping aluminum panels for automotive parts. For this purpose, the test and simulation results of aluminum-resin hybrid materials and aluminum sheet materials were compared. Tensile strength and elastic modulus of the hybrid material were approximately 10% lower than aluminum sheet. Also, it was showed that the hybrid material have lower natural frequency than aluminum sheet, and it was confirmed that loss factor increases as the thickness of resin increases. Finally, it is confirmed that the test results and the analysis results are similar with each other and the performance prediction of the materials are possible by FEA.

• Journal of Chest Surgery
• /
• v.54 no.2
• /
• pp.81-87
• /
• 2021

Background: Artificial grafts such as polyethylene terephthalate (Dacron) and expanded polytetrafluoroethylene (ePTFE) are used for various cardiovascular surgical procedures. The compliance properties of prosthetic grafts could affect hemodynamic energy, which can be measured using the energy-equivalent pressure (EEP) and surplus hemodynamic energy (SHE). We investigated changes in the hemodynamic energy of prosthetic grafts. Methods: In a simulation test, the changes in EEP for these grafts were estimated using COMSOL MULTIPHYSICS. The Young modulus, Poisson ratio, and density were used to analyze the grafts' material properties, and pre- and post-graft EEP values were obtained by computing the product of the pressure and velocity. In an in vivo study, Dacron and ePTFE grafts were anastomosed in an end-to-side fashion on the descending thoracic aorta of swine. The pulsatile pump flow was fixed at 2 L/min. Real-time flow and pressure were measured at the distal part of each graft, while clamping the other graft and the descending thoracic aorta. EEP and SHE were calculated and compared. Results: In the simulation test, the mean arterial pressure decreased by 39% for all simulations. EEP decreased by 42% for both grafts, and by around 55% for the native blood vessels after grafting. The in vivo test showed no significant difference between both grafts in terms of EEP and SHE. Conclusion: The post-graft hemodynamic energy was not different between the Dacron and ePTFE grafts. Artificial grafts are less compliant than native blood vessels; however, they can deliver pulsatile blood flow and hemodynamic energy without any significant energy loss.

• Journal of the Korean Wood Science and Technology
• /
• v.30 no.1
• /
• pp.18-24
• /
• 2002

Small Sitka spruce specimens of 50×133×10 mm³ were artificially weathered in a chamber equipped with 340 mm xenon arc and water spray as part of the accelerated-weathering cycle. Specimens were exposed to only ultraviolet or ultraviolet with water spray for 10 and 20 hours. Physical properties of the weathered specimens were investigated by colorimetry, sorption and ultrasonic testing methods. The longer exposed to ultraviolet the less bright were the specimens. It was revealed that the water spray treatment accelerated the loss of brightness and increased the wettability. Among the specimens exposed to ultraviolet with water spray the specimens treated for 10 hours showed greater wettability than those for 20 hours, which might lose the wettability due to the excessive degradation on their surfaces. The ultrasonic velocities of the weathered specimens were obviously higher than those of the unweathered. It is considered that the accelerated weathering either increases the modulus of elasticity of wood or decrease the density of wood.

• Korean Journal of Agricultural Science
• /
• v.30 no.2
• /
• pp.154-163
• /
• 2003

This study was performed to examine the freezing and thawing properties of the high strength concrete using recycled coarse aggregate. The recycled coarse aggregate was replaced by 0%, 25%, 50%, 75% and 100% of natural crushed aggregate. The compressive strength of the concrete used recycled coarse aggregate was shown in more than $400kgf/cm^2$ at the curing age 28 days. The weight loss ratio by freezing and thawing was shown in less than 1% at all mix type. The pulse velocity and relative dynamic modulus were decreased with increasing the freezing and thawing cycles. Also, durability factor for the freezing and thawing were decreased with increasing the content of recycled coarse aggregate. But, recycled concrete replaced with recycled coarse aggregate 100% was shown in more than 60 by durability factor in freezing and thawing of 300cycles Accordingly, these recycled coarse aggregate can be used for high strength concrete.

• Korean Journal of Agricultural Science
• /
• v.31 no.2
• /
• pp.105-114
• /
• 2004

This study was performed to examine the physical and mechanical properties of eco-concrete using soil, natural coarse aggregate, soil compound and polypropylen fiber. The mass loss ratio was decreased with increasing the content of coarse aggregate and soil compound. The compressive strength, flexural strength, ultrasonic pulse velocity and dynamic modulus of elasticity were increased with increasing the content of coarse aggregate, soil compound and polypropylene fiber. The compressive and flexural strengths were showed in 8.07 MPa and 2.641 MPa at the curing age 28 days, respectively. The coefficient of permeability was decreased with increasing the content of coarse aggregate and soil compound, but it was increased with increasing the content of polypropylene fiber. The lowest coefficent of permeability was showed in $5.066{\times}10^{-9}cm/s$.

• Membrane Journal
• /
• v.27 no.5
• /
• pp.425-433
• /
• 2017

As the problems related to the environmental pollution such as carbon dioxide emission are emerging, the need for the renewable energy and environmentally friendly energy is getting intense. Fuel cells are eco-friendly energy generation devices that generate electrical energy and produce water as a sole by-product. Compared to the traditional proton exchange membrane fuel cell (PEMFC), anion exchange membrane alkaline fuel cell (AEMAFC) has a main advantage of possibility to use low cost metal catalysts due to its faster kinetics. The AEM, which conducts $OH^-$ ions, should possess high ion conductivity as well as high chemical stability at high pH conditions. We hereby introduce a crosslinked poly(2,6-dimethyl-1,4-phenylene oxide) having a spacer-type conducting group as novel AEM, and report a high ion conductivity ($67.9mScm^{-1}$ at $80^{\circ}C$) and mechanical properties (Young's modulus : 0.53 GPa) as well as chemical stability (6.8% IEC loss at $80^{\circ}C$ for 1,000 h,) for the developed membrane.

• Proceedings of the KACD Conference
• /
• 2008.05a
• /
• pp.235-245
• /
• 2008

The aim of this study was to develop a method for measuring the slumping resistance of resin composites and to relate it to the rheological characteristics. Five commercial hybrid composites (Z100. Z250. DenFil, Tetric Ceram. ClearFil) and a nanofill composite (Z350) were used to make disc-shaped specimens of 2 mm thickness. An aluminum mold with square shaped cutting surface was pressed onto the composite discs to make standardized imprints. The imprints were light-cured either immediately (non-slumped) or after waiting for 3 minutes at $25^{\circ}C$ (slumped). White stone replicas were made and then scanned for topography using a laser 3-D profilometer. Slumping resistance index (SRI) was defined as the ratio of the groove depth of the slumped specimen to that of the non-slumped specimen. The pre-cure viscoelasticity of each composite was evaluated by an oscillatory shear test and normal stress was measured by a squeeze test using a rheometer. Flow test was also performed using a flow tester. Correlation analysis was performed to investigate the relationship between the viscoelastic properties and the SRI. SRI varied between the six materials (Z100 < DenFil < Z250 < ClearFil < Tetric Ceram < Z350). The SRI was strongly correlated with the viscous (loss) shear modulus G' but not with the loss tangent. Also. slumping resistance was more closely related to the resistance to shear flow than to the normal stress. Slumping tendency could be quantified using the imprint method and SRI. The index may be applicable to evaluate the clinical handling characteristics of composites.

• Polymer(Korea)
• /
• v.33 no.3
• /
• pp.224-229
• /
• 2009

The dielectric properties of semi-IPN poly(phenylene oxide)(PPO) blend/$BaTiO_3$(BT) composites are investigated. The composites are fabricated via melt-mixing of crosslinker and peroxide in precursor PPO composite obtained by precipitating the suspension consisted of PPO, BT and toluene into methylethyl ketone, poor solvent of PPO. The permittivity of the precursor PPO composites shows higher value than that of integral-blended PPO composites by extruder and coincides with the theoretical value calculated by logarithmic rule of mixture. The blend of PPO and cross-linked triallyl isocyanurate is most effective for lowering the permittivity and loss tangent owing to the suppression of the orientation polarization of matrix. In contrast, 4,4'-(1,3-phenylene diisopropylidene) bisaniline, which has amine unit in its structure, increases the permittivity as well as loss tangent of the composite, but it has the ability to densify the matrix resin and the interfacial adhesion between the matrix and filler to improves flexural strength and modulus.

• Transactions of the Korean Society of Mechanical Engineers
• /
• v.17 no.10
• /
• pp.2498-2508
• /
• 1993

$Al/SiC/Al_{2}O_{3}$ hybrid composites are fabricated by squeeze infiltration method. From the misconstructive of $Al/SiC/Al_{2}O_{3}$ hybrid composites fabricated by squeeze infiltration method, uniform distribution of reinforcements and good bondings are found. Hardness value of $Al/SiC/Al_{2}O_{3}$ hybrid composites increases linearly with the volume fraction of reinforcement because SiC whisker and $Al_{2}$O$_{3}$ fiber have an outstanding hardness. Optimal aging conditions are obtained by examining the hardness of $Al/SiC/Al_{2}O_{3}$ hybrid composites with different aging time. Tensile properties such as Young's modulus and ultimate tensile strength are improved up to 30% and 40% by the addition of reinforcements, respectively. Failure mode of $Al/SiC/Al_{2}O_{3}$ hybrid composites is ductile on microstructural level. Through the abrasive wear test and wear surface analysis, wear behaviour and mechanism of 6061 aluminum and $Al/SiC/Al_{2}O_{3}$ hybrid composites are characterized under various testing conditions. The addition of SiC whisker to $Al/SiC/Al_{2}O_{3}$ composites gives rise to improvement of the wear resistance. The wear resistance of $Al/SiC/Al_{2}O_{3}$ hybrid composites is superior to that of Al/SiC composites. The wear mechanism of aluminum alloy is mainly abrasive wear at low speed range and adhesive and melt wear at high speed range. In contrast, that of $Al/SiC/Al_{2}O_{3}$ hybrid composites is abrasive wear at all speed range, but severe wear when counter material is stainless steel. As the testing temperature increases, wear loss of aluminum alloy decreases because the matrix is getting more ductile, but that of $Al/SiC/Al_{2}O_{3}$ hybrid composites is hardly varied. Oil lubricant is more effective to reduce the wear loss of aluminum alloy and $Al/SiC/Al_{2}O_{3}$ hybrid composites at high speed range.