• Journal of Korean Society for Atmospheric Environment
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• v.14 no.6
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• pp.621-630
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• 1998

The concentrations of organic carbon (OC) and elemental carbon (EC) in fine aerosols were determined from the samples collected at the two background sites of Kosan in Cheju Island and Kangwha. Samplings were carried out during the spring and winter of 1996 and the fall and winter of 1997. PM25 particles were collected on the prefired quartz filters for 24 hours and analyzed by the selective thermal oxidation method. The concentrations of OC at the sites were higher than those commonly observed from clean areas around the world, but those of EC at both sites were lower than, or comparable to, other clean areas in the world. Both the OC and EC levels at Kangwha were higher than those at Kosan. According to backward trajectory analysis, most air pollutants collected at the two sites were from China. It was found that the OC and EC concentrations in air masses from southern China were higher than those from northern China.

• Proceedings of the Korea Air Pollution Research Association Conference
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• 2000.04a
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• pp.191-192
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• 2000

최근 동아시아 지역의 산업의 발전과 함께 대기오염물질이 발생하여 인접국가간에 상호영향을 미치므로, 이들 오염물질들의 이동에 관한 정량적 파악과 영향에 대한 규명이 필요하다. 대기중의 입자상 이온물질중 질산염과 황산염의 경우 대부분이 인간활동의 결과로 유입된 NOx와 대기중의 SO$_2$가 대기 중에서 화학적 반응에 의해 형성된 2차 오염물질이다. 자동차, 공장의 가동 등으로 인하여 발생되는 이들 오염물질들은 국지적으로 기상조건에 따라 이동되고 있는 것으로 알려져 있고, 각 지역에서 측정을 비롯한 많은 연구가 이루어지고 있다. (중략)

• Journal of Korean Society for Atmospheric Environment
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• v.33 no.1
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• pp.19-30
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• 2017

The altitudinal potential source contribution function (PSCFa) method was developed by considering topography and height of back trajectories. The PSCFa calculated on the contributions of trans-boundary transport to the hourly mean concentrations of aerosol optical depth (AOD) of the Aerosol Robotic Network (AERONET) in the Distributed Regional Aerosol Gridded Observation Networks (DRAGON) KORea-US Air Quality (KORUS-AQ) campaign from March 31 to July 1 in 2016. Eastern China ($33^{\circ}N{\sim}35^{\circ}N$ and $119^{\circ}E{\sim}121^{\circ}E$) can be the major source of trans-boundary pollution to the western area in South Korea resulted from PSCFa (0~700 m). In this study, AOD by Moderate Resolution Imaging Spectroradiometer (MODIS) was compared to verify the source regions. Regionally, the effects of the long-range transport of pollutants from the eastern China on air quality in south Korea have become more significant over this period.

• Atmosphere
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• v.25 no.1
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• pp.141-148
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• 2015

Recently increased anthropogenic aerosols change the radiative energy balance and affect human life. The management of air quality requires monitoring both the local emissions and transported pollutants. In order to estimate the quantitative contribution of long-range transport from remote sources on aerosol concentrations in Seoul, the airmasses were classified into five types with respect to their pathways. When airmass came from west over strong emission regions in China, high concentrations of $PM_{10}$, $PM_{2.5}$, black carbon (BC), organic carbon (OC), and elemental carbon (EC) were found, even higher than those for the stagnated airmass. High OC concentrations were found when airmass came from north while BC, EC, and $PM_{2.5}$ concentrations were lower than those of the stagnated airmasses. During dust events, the $PM_{2.5}$ and $PM_{10}$ concentrations increased significantly while carbonaceous aerosol concentrations did not increased. The temporal variations of aerosol concentrations in Seoul were affected by the seasonal variations of airmass pathways. The high $PM_{2.5}$ concentrations over $100{\mu}g\;m^{-3}$ appeared most frequently when the airmasses came from west.

• Journal of the Korean earth science society
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• v.43 no.2
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• pp.265-282
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• 2022

This study analyzes the impact of long-range transport of biomass burning emissions from northeastern China on the concentration of particulate matter of diameter less than 10 ㎛ (PM₁₀) in Korea using the Weather Research and Forecasting model coupled with Chemistry (WRF-Chem). Korea was impacted by anthropogenic emissions from eastern China, dust storms from northern China and Mongolia, and biomass burning emissions from northeast China between April 4-and 7, 2020. The contributions of long-range PM₁₀ transport were calculated by separating biomass burning emissions from mixed air pollutants with anthropogenic emissions and dust storms using the zeroing-out method. Further, the radiation energy budget over land and sea around the Korean Peninsula was analyzed according to the distribution of biomass burning emissions. Based on the WRF-Chem simulation during April 5-6, 2020, the contribution of long-range transport of biomass burning emissions was calculated as 60% of the daily PM₁₀ average in Korea. The net heat flux around the Korean Peninsula was in a negative phase due to the influence of the large-scale biomass burning emissions. However, the contribution of biomass burning emissions was analyzed to be <45% during April 7-8, 2020, when the anthropogenic emissions from eastern China were added to biomass burning emissions, and PM₁₀ concentration increased compared with the concentration recorded during April 5-6, 2020 in Korea. Furthermore, the net heat flux around the Korean Peninsula increased to a positive phase with the decreasing influence of biomass burning emissions.

• Proceedings of the Korea Air Pollution Research Association Conference
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• 2002.11a
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• pp.429-429
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• 2002

This study examines the influence of long-range transport of dust particles and air pollutants on photochemistry of OH and NO$_3$ at Jeju Island (33.17$^{\circ}$ N, 126.10$^{\circ}$ E) during the Asian dust-storm (ADS) period in April 2001. The atmospheric concentrations of criteria pollutants (O$_3$, NO$_2$, CO) and sulfur species were measured at a ground station on Jeju Island, Korea as part of the ACE-Asia intensive operation. Three ADS events were observed during the periods of 10-12, 13-14, and 25-26 April, respectively. The concentrations of the criteria pollutants (i.e., $O_3$, NO$_2$, and SO$_2$) were not significantly different from those during the non-Asian-dust-storm (NADS) period. Average OH and NO$_3$ levels at Jeju Island during the study period (ADS and NADS) were estimated to be 4-10 $\times$ 10$^{5}$ moleculescm$^{-3}$ and 2-4 pptv, respectively. Two main sources of OH radical were the primary production from the reaction of water vapor ($H_2O$) and O(1D) radicals and the reaction of HO$_2$ with NO. CO was a dominant sink of OH during the ADS period: whereas NO$_2$ was the most important during the NADS period. for NO$_3$ radical, a reaction of NO$_2$ with $O_3$ was the most important atmospheric source; while $N_2$O$_{5}$ uptake on dust particles was the most dominant sink during the ADS period.

• Journal of the Korean earth science society
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• v.41 no.6
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• pp.557-574
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• 2020

The purpose of this study is to analyze the cause of high PM2.5 mass concentrations in Cheongju for the period of non-Asian dust days using the weather chart, the stream lines at 850 hPa, the backward trajectory, and the weather and air quality model. As a result of analyzing the time series of PM2.5 concentrations and weather charts for the episodic days in Cheongju, the weather patterns were shown in related to long-range transport of PM2.5 from China or surrounding areas. In fact, in the PM2.5 time series, 60-80 ㎍ m-3, which is more than 2-3 times higher than the concentration attributed to Cheongju activities, was observed as a background concentration related to long-range transport. The distribution of high PM2.5 concentration was typically dependent on the locations of the high and low pressures above the ground while the upper jet stream passed through the Korean Peninsula. Consequently, the high PM2.5 concentration in Cheongju is due to massive air pollutants in the form of smog originated from industrial, household and energy combustion sources of Beijing and other nearby regions of China. These air pollutants move along a fast zonal wind caused by the atmospheric pressure arrangement. high concentration of PM2.5 in Cheongju City is because the mass of air pollutants in the form of smog generated from industrial, household and energy combustion origins in Beijing or other nearby regions of China move along a fast wind speed zone according to the atmospheric pressure arrangement of long-distance transportation. Air pollutants including PM2.5 show an M-shaped pattern that passes through the topography of the Cheongju basin from north to south as a belt or band-shaped pollutant. The ground high pressure according to the above-ground high pressure expansion area and cut-off low or low pressure arrangement, or the bands in the form of river stems appear in a gradual incremental pattern that changes into a U-shape under the influence of the wind.

• Journal of Korean Society for Atmospheric Environment
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• v.21 no.E1
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• pp.23-35
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• 2005

Size distribution of particulate water-soluble ion components was measured at Gosan, Korea using a micro-orifice uniform deposit impactor (MOUDI). Sulfate, ammonium, and nitrate showed peaks in three size ranges; Sulfate and ammonium were of dominant species measured in the fine mode ($D_{p} < 1.8 {\mu}m$). One peak was observed in the condensation mode ($0.218\sim0.532{\mu}m$), and the other peak was obtained in the droplet mode ($0.532\sim1.8{\mu}m$). Considering the fact that the equivalent ratios of ammonium to sulfate ranged from 0.5 to 1.0 in these size ranges, it is inferred that they formed sufficiently neutralized compounds such as ($NH_{4})_{2}SO_{4} and (NH_{4})_{3}H(SO_{4})_{2}$ during the long-range transport of anthropogenic pollutants. On the other hand, nitrate was distributed mainly in the coarse mode ($3.1\sim6.2{\mu}m$) combined with soil and sea salt. Two sets of MOUDI samples were collected in each season. One sample was collected when the concentrations of criteria air pollutants were relatively high, but the other represented relatively clean air quality. The concentrations of sulfate and ammonium particles in droplet mode were the highest in winter and the lowest in summer. When the air quality was bad, the increase of nitrate was observed in the condensation mode ($0.218\sim0.282{\mu}m$). It thus suggests that the nitrate particles were produced through gas phase reaction of nitric acid with ammonia. Chloride depletion was remarkably high in summer due to the high temperature and relative humidity.

• Journal of Korean Society for Atmospheric Environment
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• v.20 no.5
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• pp.603-613
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• 2004

Extensive forest fires occurred across the border in Russia. particularly east of Lake Baikal between the Amur and Lena rivers in May 2003. These forest fires released large amounts of particulates and gases into the atmosphere. resulting in adverse effects on regional air quality and the global radiation budget. Smoke pollution from the Russian fires near Lake Baikal was sometimes transported to Korea through Mongolia and eastern China. In this study ground based radiation (visible and UV-B) data measured during May 2003 at Seoul and Kwangju were analyzed to estimate smoke aerosol impacts on solar radiation. Surface criteria air pollutants ($PM_{10}$, CO, $O_3$) data were also obtained from National Institute of Environmental Research (NIER) during smoke aerosol event period (19 May~24 May 2003). Large Aerosol Optical Depth (AOD) 1.0~3.0 was observed during this period due to the influence of the long range transport of smoke aerosol plume from the Russian fires, resulting in short-wavelength direct aerosol radiative forcing of -90~ -200W/$m^2$. These smoke aerosol plume caused decrease in surface UV-B radiation up to 80% and increase in PM_(10) concentration up to 200${\mu}g/m^3$ exceeding the 24 hour ambient air quality standard.

• Asian Journal of Atmospheric Environment
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• v.6 no.3
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• pp.234-243
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• 2012

The wintertime high loading for atmospheric pollutants is certainly expected in the Byunsan Peninsula of Korea because of a great-scale reclamation project having construction of 33 km tidal sea dike impounding an area of over 40,000 ha and long-range transport. The goal of this study is to trace the origin of this wintertime burden for ambient particulate matter (hereafter called "PM") in the Byunsan Peninsula of Korea. The size-segregated (i.e., cutoff size from 0.01 ${\mu}m$ to 4.7 ${\mu}m$) PM sampling was conducted at a ground-based site of Byunsan Peninsula located in the west coast of Korean Peninsula during the height of dike constructing. Data archived in this study are the mass concentrations of ionic, elemental, and carbonic components in size-fractioned PM. The elemental mass of individual submicrometer particles was also analyzed. The sum of 5-source (i.e., elemental carbon, organic materials, inorganic secondary pollutants, crustal matter, and sea-salts) concentrations shows the bimodal distribution (major and minor peaks formed around $D_p$, 0.65 ${\mu}m$ and $D_p$, 4.7 ${\mu}m$, respectively) by border with 0.19 ${\mu}m$ of cutoff size. The concentrations of EC in $PM_{1.1-0.01}$ in winter and spring times were 4.62 ${\mu}g\;m^{-3}$ and 3.74 ${\mu}g\;m^{-3}$, respectively. Elemental masses of submicron individual particles are classified into two groups, i.e., the major elements (Cl, Al, Si, S, and P) and the minor trace elements. Cluster analysis differentiated the elements in submicron individual particles into 4-cluster. Among them, three clusters are in agreement with the major (Al, Si, S, and P), minor (Fe, Ca, and K), and trace compositions of coal burning. Meanwhile, Cl classified as an independent cluster has different source profile which was mainly due to the Saemangeum seawall project. Some highly toxic elements (e.g., Cr, Mn, and As (and/or Pb)) were also detected in some part of submicron individual PM. As a consequence, the combination of the Saemangeum project and winter monsoon played a considerable part in the double aggravation of wintertime air pollution in the Byunsan Peninsular.