• Title/Summary/Keyword: lithium chloride

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Synthesis and Electrochemical Properties of Carbon Coated Li4Ti5O12 using PVC (PVC를 원료로 탄소코팅한 Li4Ti5O12의 합성 및 전기화학적 특성)

  • Hyun, Si-Cheol;Na, Byung-Ki
    • Clean Technology
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    • v.24 no.1
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    • pp.77-84
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    • 2018
  • In this study, $Li_4Ti_5O_{12}$ anode materials for lithium ion battery were synthesized by dry ball-mill method. Polyvinyl chloride (PVC) as a carbon source was added to improve electrochemical properties. When the PVC was added after $Li_4Ti_5O_{12}$ formation, the spinel structure was well synthesized and it was confirmed by X-ray diffraction (XRD) experiments. When the carbon material was added before the synthesis and the heat treatment was performed, it was confirmed that a material having a different crystal structure was synthesized even when a small amount of carbon material was added. In the case of $Li_4Ti_5O_{12}$ without the carbon material, the electrical conductivity value was about $10{\mu}S\;m^{-1}$, which was very small and similar to that of the nonconductor. As the carbon was added, the electrical conductivity was greatly improved and increased up to 10,000 times. Electrochemical impedance spectroscopy (EIS) analysis showed that the size of semicircle corresponding to the resistance decreased with the carbon addition. This indicates that the resistance inside the electrode is reduced. According to the Cyclic voltammetry (CV) analysis, the potential difference between the oxidation peak and the reduction peak was reduced with carbon addition. This means that the rate of lithium ion insertion and deinsertion was increased. $Li_4Ti_5O_{12}$ with 9.5 wt% PVC added sample showed the best properties in rate capabilities of $180mA\;h\;g^{-1}$ at 0.2 C-rate, $165mA\;h\;g^{-1}$ at 0.5 C-rate, and $95.8mA\;h\;g^{-1}$ at 5 C-rate.

Development of Yeast-Vector System for Eukaryotic Gene Cloning - Optimum Condition for Intact Yeast Cell Transformation and Plasmid Stability in the Transformants - (진핵생물 유전자 조작을 위한 효모 vector계 이용에 관한 기초연구 -생효모 형질전환 최적조건과 숙주별 plasmid안정성에 관하여 -)

  • 기우경;조성환;김범규;조무제
    • Microbiology and Biotechnology Letters
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    • v.14 no.2
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    • pp.125-131
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    • 1986
  • In order to obtain the optimum conditions for intact yeast cell transformation in the various yeast host-vector systems, 3 yeast plasmid vectors, YRp7, YEpl3 and YIp5 were introduced into 5 yeast hosts, Saccaromyces cervisiae Dl3-1A, DKD-5D, DBY-746, MC-16 and S2022D with various transformation conditions, and plasmid stabilities in all the transformants were also observed. The highest transformation frequencies in all the host-vector system were obtained in the 16 hour Cultured cell (5.4 $\times$ 10$^6$ - 2.4 $\times$ 10$^8$cells/$m{\ell}$) treated with 0.1-0.2 M lithium chloride in 0.1 M tris-HCl (pH 7.6), 35% polyethylene glycol 4000, and heat-shocked at 42$^{\circ}C$ for 5 minutes after 60 minutes of induction. The intact cell transformation got more transformation frequency in DKD-5D (YRp7) and DBY-746 (YEpl3) than protoplast transformation, but reverse tendency was observed in DKD-5D (YEp13) and Dl3-lA (YRp7). The transformants, D13-1A (YRp7) and DKD-5D (YRp7) were very unstable in selective medium, with 80 to 85% of the transformants losing the plasmid after 70 generations, but the transformants, DKD-5D (YEpl3) and DBY-746 (YEpl3) were quite stable, with 35% of the transformants losing the plasmid.

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Comparison of Bifidobacteria Selective Media for the Detection of Bifidobacteria in Korean Commercial Fermented Milk Products

  • Kim, Eung-Ryool;Cho, Young-Hee;Kim, Yong-Hee;Park, Soon-Ok;Woo, Gun-Jo;Chun, Ho-Nam
    • Food Science of Animal Resources
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    • v.30 no.1
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    • pp.154-162
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    • 2010
  • This study was carried out to compare the efficacy and selectivity of TOS and BS media for enumeration of bifidobacteria in commercial fermented milk products. First, bifidobacteria was isolated from 20 fermented milk products, and all isolated bifidobacteria were identified by genomic technology as Bifidobacterium lactis. The two media significantly differed from each other with regard to the recovery of B. lactis, that is, the recovery of this organism was as much as 6 logs lower on BS medium than on TOS. When the concentration of BS solution (mixture of paromomycin sulfate, neomycin, sodium propionate, and lithium chloride) used in BS medium was reduced to 50% (BS50), a relatively high percentage recovery of bifidobacteria from pure cultures was achieved. Susceptibility tests to antibiotics and tests for selective agents for the isolated bifidobacteria and lactic acid bacteria were conducted. The BS solution inhibited some lactic acid bacteria and Bifidobacterium species, while mupirocin (MU) suppressed the growth of all tested lactic acid bacteria but not Bifidobacterium. As compared with BS50 medium, TOS with or without MU showed good bifidobacteria recovery and readily distinguishable colonies; in particular, TOS supplemented with MU had a high selectivity for bifidobacteria. In conclusion, all results suggested that TOS medium with or without MU was found to be suitable for selective enumeration of bifidobacteria from mixed cultures in fermented milk, and better in that capacity than BS medium.

Luminescence Studies of N-Methyllutidone, an Unusually High Triplet Energy Sensitizer (N-메틸루티돈의 루미네센스에 관한 연구)

  • Sang Chul Shim;Myung Ho Hyun;Kuy Ho Chae
    • Journal of the Korean Chemical Society
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    • v.22 no.1
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    • pp.45-51
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    • 1978
  • The luminescence of N-methyllutidone is studied in ethanol matrix at $77^{\circ}C$K. No fluorescence is observed but a strong phosphorescence with the quantum yield of 0.1 and the lifetime of 0.2 sec is recorded. An unusually high triplet energy of 85.1 kcal/mole is determined for the compound from the O-O band of phosphorescence. The cis ${\leftrightarrow}$ trans photoisomerization of high triplet energy olefins such as 2-hexene and trans-1,4-dichlorobutene-2 is efficiently sensitized by N-methyllutidone substantiating the high triplet energy of the compound. The negative polarization of O-O band reveals the emitting triplet state to be $({\pi},{\pi}^*)^3$ state. Alkaline metal salts such as lithium chloride enhances the phosphorescence intensity through cation-N-methyllutidone coordination widening the gap between $({\pi},{\pi}^*)^3$and $(n,{\pi}^*)^3$ states.

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Expression, Purification, Crystallization and Preliminary X-Ray Crystallographic Analysis of CnrX from Cupriavidus metallidurans CH34

  • Kim, Kook-Han;Jung, Eun-Jung;Im, Ha-Na;Lelie, Daniel Van Der;Kim, Eunice Eun-Kyeong
    • Journal of Microbiology and Biotechnology
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    • v.18 no.1
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    • pp.43-47
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    • 2008
  • The nickel and cobalt resistance of Cupriavidus metallidurans CH34 is mediated by the CnrCBA efflux pump encoded by the cnrYHXCBAT metal resistance determinant. The products of the three genes cnrYXH transcriptionally regulate expression of cnr. CnrY and CnrX are membrane-bound proteins, probably functioning as anti-sigma factors, whereas CnrH is a cnr-specific extracytoplasmic functions (ECF) sigma factor. The periplasmic domain of CnrX (residues 29-148) was cloned as a N-terminal His-tagged protein, expressed in Escherichia coli, and purified using affinity chromatography and gel filtration. The molecular mass was estimated to be about 13.6kDa by size exclusion chromatography, corresponding to a monomer. The tetragonal bipyramid crystals were obtained by mixing an equal volume of protein in 50mM Tris-HCl, pH 7.5, 1% glycerol, 100mM NaCl, 1mM DTT, and the reservoir solution of 15% w/v PEG 2000, 100mM lithium chloride at 277K in 2-4 days using hanging drop vapor diffusion. The protein concentration was 24mg/ml. The crystal that diffracted to $2.42{\AA}$ resolution belongs to space group $P4_1\;or\;P4_3$ with unit cell parameters of $a=b=32.14{\AA},\;c=195.31{\AA},\;{\alpha}={\beta}={\gamma}=90^{\circ}$, with one molecule of CnrX in the asymmetric unit.

A Study on the Electrolytic Reduction Mechanism of Uranium Oxide in a LiCl-Li$_2$O Molten Salt (LiCl-Li$_2$O 용융염계에서 우라늄 산화물의 전기화학적 금속전환 반응 메카니즘에 관한 연구)

  • 오승철;허진목;서중석;박성원
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.1 no.1
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    • pp.25-39
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    • 2003
  • This study proposed a new electrolytic reduction technology that is based on the integration of simultaneous uranium oxide metallization and Li$_2$O electrowinning. In this electrolytic reduction reaction, electrolytically reduced Li deposits on cathode and simultaneously reacts with uranium oxides to produce uranium metal showing more than 99% conversion. For the verification of process feasibility, the experiments to obtain basic data on the metallization of uranium oxide, investigation of reaction mechanism, the characteristics of closed recycle of Li$_2$O and mass transfer were carried out. This evolutionary electrolytic reduction technology would give benefits over the conventional Li-reduction process improving economic viability such as: avoidance of handling of chemically active Li-LiCl molten salt increase of metallization yield, and simplification of process.

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Inhibitory effects of xylamine on the arterial contraction in rats (흰쥐 대동맥 수축에 대한 xylamine의 억제효과)

  • Kim, Sang-Jin;Kang, Hyung-sub;Kim, Jin-shang
    • Korean Journal of Veterinary Research
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    • v.44 no.3
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    • pp.389-397
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    • 2004
  • The therapeutic efficacy of xylamine in the field of psychological medicine has been recognized for years and the drug is used to treat depression and some other conditions, but little is known about its mechanism of action on vascular system. Therefore, the present study was designed to investigate the influence of xylamine on the contractile responses of isolated rat thoracic arteries to phenylephrine(PE) and potassium chloride(KCl). Xylamine produced a concentration-dependent relaxation in PE-precontracted endothelium intact(+E) rat aortic rings, but not in a KCl-precontracted aortic rings. Also, xylamine inhibited the PE-induced contraction in concentration-dependent manner, but not in the high KCl-induced contraction in +E rings. This concentration-dependent inhibition was suppressed by the removal of the endothelium (-E). The inhibitory effects of xylamine($0.3{\mu}M$) on the PE-induced contractions were suppressed by N(G)-nitro-L-arginine(L-NNA), N(omega)-nitro-L-arginine methyl ester(L-NAME), aminoguanidine, dexamethasone, methylene blue, 1H-[1,2,4]oxadiazolo [4,3-a]quinoxalin-1-one(ODQ), indomethacin, ryanodine, tetrabutylammonium(TBA), lidocaine, procaine and 0 mM extracellular $Na^+$, but not by 2-nitro-4-carboxyphenyl-n,n-diphenylcarbamate(NCDC), lithium, nifedipine, verapamil, 0 mM extracellular $Ca^{2+}$, glibenclamide and clotrimazole. These findings suggest that xylamine could act as a vasorelaxant and direct inhibitor of arterial contraction. This vasorelaxation involves an endothelial nitric oxide (NO)/cGMP (guanosine 3',5'-cyclic monophosphate) pathway or cyclooxygenase system, and an interference with $Ca^{2+}$ release, TBA-sensitive $Ca^{2+}$-activated $K^+$ channels and $Na^+$$ channels.

Modelling of the Heat and Mass Transfer in a Liquid Desiccant Dehumidifier with Extended Surface (확장표면을 적용한 액체식 제습기의 열물질 전달 모델링)

  • Chang, Y.S.;Lee, D.Y.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.23 no.4
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    • pp.303-311
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    • 2011
  • This study presents a new idea of liquid desiccant dehumidifier with extended surface to improve the compactness. Extended surface is inserted between vertical cooling tubes, and the liquid desiccant flows down along the tube walls and the extended surface as well. Though the extended surface contributes to the increase in the mass transfer area, the effect tends to be limited because less conductive non-metallic materials need to be applied due to the high corrosiveness of liquid desiccant. To analyze the effects of the extended surface insertion, mathematical modelling and numerical integration are performed for the heat and mass transfer in the liquid desiccant dehumidifier. The results show that, though the liquid desiccant on the extended surface is heated due to the moisture absorption, the temperature can be maintained by periodic mixing at the contact points between the tube and the extended surface with the liquid desiccant stream from the tube side at a relatively low temperature. This implies the absorption heat from the extended surface side can be removed effectively by mixing, which leads to a substantial improvement of the dehumidification in the liquid desiccant dehumidifier with extended surface. When the interval of the extended surface, $p_e/L$, is less than 0.1, the dehumidification is shown to increase by more than two times compared with that without extended surface.

Electric Conductance of Dilute Solutions of Lithium, Sodium and Potassium Chloride in Isopropanol_Water Mixtures (이소프로판올-물 混合溶媒中의 리튬, 나트륨 및 칼륨 鹽化沕 溶液의 電導度)

  • Byung-Rin Cho;Yong-Ja Lee;Jae-Bin Kim
    • Journal of the Korean Chemical Society
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    • v.20 no.4
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    • pp.260-265
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    • 1976
  • The conductances of dilute solutions of LiCl, NaCl and KCl in a series of isopropanol-water mixtures were determined at $30^{\circ}C$. The values of equivalent conductance agreed well with Debye-Huckel-Onsager equation and the limiting equivalent conductance was greatly reduced as the isopropanol content of the solvent was increased in accord with predictions based on solvent viscosity and dielectric properties. Also, the limiting equivalent conductance increased in sequence ${\Lambda}_{0,LiCl} < {\Lambda}_{0,NaCl} < {\Lambda}_{0,KCl} in 0.0, 0.1 and 0.2 mole fraction isopropanol, but {\Lambda}_{0,LiCl} < {\Lambda}_{0,KCl} < {\Lambda}_{0,NaCl} in 0.3 mole fraction ispropanol. The maximum Walden product, {\Lambda}_{0{\eta}0}$ was found in 0.1 mole fraction isopropanol for all electrolytes.

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Moisture Sorption Isotherms of Four Echinochloa Species Seeds (피속 잡초 종자의 등온흡습곡선 특성)

  • Lee, Yong Ho;Byun, Ji Young;Na, Chae Sun;Kim, Tae Wan;Kim, Jeong-Gyu;Hong, Sun Hee
    • Weed & Turfgrass Science
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    • v.4 no.2
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    • pp.111-117
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    • 2015
  • The equilibrium moisture contents (EMC) in seeds of four Echinochloa (E. crus-galli var. crus-galli, E. crus-galli var, echinata, E. crus-galli var. praticola, E. esculenta) were measured at $20^{\circ}C$ with equilibration over a series of lithium chloride solutions with relative humidities ranging from 0.11 to 0.8 to determine sorption isotherms and safe storage relative humidity. Standard seed sorption isotherm models i.e. modified Henderson, modified Chung-Pfost, modified Halsey, modified Oswin and Guggenheim-Anderson-deBoer (GAB) equations were adopted to evaluate the goodness of fit to sorption isotherms. This study indicated that EMC of seeds was significantly different in four Echinochloa species at various relative humidity. The modified Oswin equations for E. crus-galli var. crou-galli, E. crus-galli var, echinata, E. esculenta and GAB equation for E. crus-galli var. praticola were adequate models for the EMC data. Seeds of four Echinochloa species have monolayer moisture contents when stored at RH < 0.1. These results show that seed moisture isotherm model should be selected according to genetic variation.