• Title/Summary/Keyword: liquid product

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Precipitation of Manganese in the p-Xylene Oxidation with Oxygen-Enriched Gas in Liquid Phase

  • Jhung, Sung-Hwa;Park, Youn-Seok
    • Bulletin of the Korean Chemical Society
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    • v.23 no.3
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    • pp.369-373
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    • 2002
  • The liquid phase oxidation of p-xylene has been carried out with oxygen-enriched gas, and the manganese component was precipitated probably via over-oxidation to $Mn^{4+}$. The precipitation increased with rising oxygen concentration in the reaction gas and occurred mainly in the later part of the oxidation. The activity of the reaction decreased, and the blackening of the product and side reactions to carbon dioxide increased with the degree of precipitation. Precipitation can be decreased with the addition of metal ions, such as cerium, chromium and iron.

Effects of Additives on Yield of Coal Liquefaction (석탄액화시 첨가제에 의한 수율 향상 효과)

  • 김종원;명광식;김연순;심규성;한상도
    • Journal of Energy Engineering
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    • v.5 no.2
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    • pp.176-182
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    • 1996
  • The effects of some additives (black liquor, NaOH, water and wood) on the conversion of coal and product were investigated in the lab-scale, high pressure reacting system around 375$^{\circ}C$. The addition of black liquor enhances the coal conversion yield about 38.6%, which is mainly due to NaOH in black liquor. Also, sulfur of the black liquor in coal liquefaction process evolved hydrogen sulfide, which causes the odor problem. Addition of water in coal liquefaction increased CO$_2$content in the gas phase, and low boiling range components in liquid products. Coprocessing of wood and coal at 400$^{\circ}C$ increased yield of liquid product about 8%, but higher temperature above 400$^{\circ}C$ reduced liquid product due to increase of gas products.

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Kinetics of the Low-temperature Pyrolysis of Mixed Plastics in the Batch Reactor (회분식반응기에서의 혼합 플라스틱의 저온열분해 kinetics)

  • Cha, Wang Seog;Oh, Myung Seog;Jang, Hyun Tae;Tae, Beomseok
    • Korean Chemical Engineering Research
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    • v.46 no.3
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    • pp.540-544
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    • 2008
  • Pyrolytic characteristics of mixed plastics containing 22 wt.% HDPE, 17 wt.% LDPE, 27 wt.% PP, 12 wt.% PS, 16 wt.% ABS, 6 wt.% PVC have been studied in the batch-type microreactor of stainless steel. Thermal degradation experiments were performed at temperature of $410{\sim}450^{\circ}C$. The yield of each pyrolytic products were obtained by the weight measurement and molecular weight distribution of pyrolytic liquid products determined by the GC-SIMDIS method. It was shown that the yield and molecular weight of pyrolytic liquid product were decreased with the increase of reaction temperature and time. It was know that 20wt% of PVC composing of the mixed plastics was converted to the gas products of chloride during the pyrolysis process. The chain-end scission rate parameter was determined to be 50.2 kcal/mole of mixed plastics by the Arrhenius plot.

Effects of Biomass Additives on Yield of Coal Liquefaction (석탄액화시 바이오매스계 첨가제의 효과)

  • Kim, J.W.;Sim, K.S.;Lee, S.H.;Park, K.B.;Lalvani, S.B.
    • Solar Energy
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    • v.18 no.3
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    • pp.161-167
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    • 1998
  • The effects of some additives(black liquor, wood and lignin) on the conversion of coal and product were investigated in the lab-scale, high pressure reacting system around $375^{\circ}C$. The addition of lignin to coal during liquefaction significantly increased the depolymerization of coal and enhanced the quality of the liquid products. Coprocessing of wood and coal at $400^{\circ}C$ increased yield of liquid product about 8%, but higher temperature above $400^{\circ}C$ reduced liquid product due to increase of gas products. The addition of black liquor resulted in an enhancement in coal conversion yields, however, the observed increase is lower than that obtained in the presence of NaOH because lignin present in black liquor is not very effective due to the $OH^-$ presence.

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Anticholinesterase activity of Cinnamomum zeylanicum L. leaf extract

  • Dalai, Manoj Kumar;Bhadra, Santanu;Chaudhary, Sushil Kumar;Chanda, Joydeb;Bandyopadhyay, Arun;Mukherjee, Pulok K.
    • CELLMED
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    • v.4 no.2
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    • pp.11.1-11.6
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    • 2014
  • Cinnamomum zeylanicum (C. zeylanicum) is a tropical evergreen tree of Lauraceae family. It is one of the oldest culinary spices known and used traditionally in many cultures for centuries. In addition to its culinary uses, cinnamon also possesses as a folk remedy of many health disease condition including analgesic, antiseptic, antispasmodic, aphrodisiac, astringent, carminative, haemostatic, insecticidal, and parasiticide and memory enhancing property. This study was aimed to assess the acetylcholinesterase and butyrylcholinesterase inhibitory activity of standardized methanol extract of the C. zeylanicum. Gas chromatography - mass spectrometry (GC-MS) and high performance liquid chromatography (HPLC) analysis were done to identify the presence of eugenol as chemical component and support the neuroprotective activity in the extract. Anticholinesterase inhibitory activity of crude methanol extract of C. zeylanicum leaves and cinnamon oil were evaluated by 96-well microtiter plate assay and thin layer chromatography bioassay detection methods. This study revealed that cinnamon oil ($IC_{50}:45.88{\pm}1.94{\mu}g/ml$) has better anticholinesterase activity than methanol extract ($IC_{50}:77.78{\pm}0.03{\mu}g/ml$). In HPLC analysis, retention time of eugenol in cinnamon oil was found to be 15.81 min which was comparable with the retention time (15.99 min) of the reference standard, eugenol. Seven chemical compounds were identified by GC-MS analysis, in which eugenol as an important phytoconstituents. Thus the phytochemicals from C. zeylanicum methanol leaves extract could be developed as potential source of anticholinesterase activity, with particular benefit in the symptomatic treatment of Alzheimer's disease.

Neuroprotective and anti-inflammatory activity of marine sponge extract and HPLC profiling of its components (해면 추출물의 신경세포 보호 및 항염증 활성과 함유 성분의 HPLC 프로파일링)

  • Kim, Da-Eun;Kim, Min-Seon;An, Hye Suck;Lee, Jae Wook;Park, Jin-Soo
    • Journal of Applied Biological Chemistry
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    • v.64 no.1
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    • pp.33-38
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    • 2021
  • Marine sponges contain pharmacologically attractive substances that exhibit strong cytotoxicity and are used as materials to isolate potential drug candidates. However, with a growing interest in marine ecosystem conservation, it is becoming increasingly difficult to gather a sponge for natural product research. To build a database to cope with this issue, we measured the neuroprotective and anti-inflammatory activity of 181 sponge extracts. As a result, we found 17 samples with neuroprotective effects and 14 samples with anti-inflammatory effects. In addition, high-performance liquid chromatography (HPLC) analysis was performed to compare the components contained in each sample, and based on HPLC profiles, a dendrogram according to similarity was created. The results of this study suggested the possibility of discovering the active compounds in the sponge and laid the basis for efficient research on the sponge.

Study on liquid carbonation using the recycling water of ready-mixed concrete (레미콘회수수를 이용한 액상탄산화에 관한 연구)

  • Lim, Yun-Hui;Lee, Ju-Yeol;Choi, Chang-Sik;Hong, Bum-Ui;Park, Jin-Won;Lee, Dae-Young;Park, Byung-Hyun
    • Journal of the Korean Applied Science and Technology
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    • v.30 no.4
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    • pp.770-778
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    • 2013
  • In this study, a liquid carbonation method was applied for producing precipitate calcium carbonate by liquid-liquid reaction. We recycled the recycling water of ready-mixed concrete, one of construction waste for use source of carbonate ion. A supernatant separated from the recycling water of ready-mixed concrete, as a result of ICP analysis of a cation, $Ca^{2+}$ was contained up to 1100 ppm. We used MEA as a $CO_2$ absorbent for the liquid carbonation. A precipitate $CaCO_3$ was produced at more than MEA 20 wt%. The precipitate $CaCO_3$ as a final product was separated and dried. The result of XRD was confirmed the generation of $CaCO_3$ to calcite structure.

Persistence Evaluation of Mosquito Repellents against Aedes albopictus (Diptera: Culicidae) (흰줄숲모기에 대한 기피제의 지속성 평가)

  • Kang, Shin-Ho;Jang, Sun-Ah;Han, Jong-Been;Seo, Dong-Kyu;Song, Chi-Hun;Kim, Min-Ki;Kim, Young-Lim;Choi, Seon-Hee;Kim, In-Kyu;Kim, Gil-Hah
    • Korean journal of applied entomology
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    • v.44 no.4 s.141
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    • pp.331-336
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    • 2005
  • Four mosquito repellents, product A (aerosol), product B (liquid), product C (aerosol) and product D (lotion) were tested for their persistent repellency and quantity of DEET remained with the lapse was analyzed. In shirt term test with human (or 8 hours, product A (aerosol), product B (liquid), product C (aerosol) and product D (lotion) appeared over 95% repellency for eight, five, six and six hours. respectively. In long-term tests with shirt piece for 16 days, product A (aerosol) and product C (aerosol) showed 100% repellency for 10 days. In the assay of quantity of DEET remained in shirt pieces with the lapse of time, two products was decreased to the same pattern.

Development of a Simulation Program to Predict the Performance of the Multi-grade Lubricant before Blending Base Oil with Additives (기유와 첨가제 혼합 전 다등급 윤활유의 성능 예측 시뮬레이션 프로그램 개발)

  • Chun, Sang-Myung
    • Tribology and Lubricants
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    • v.28 no.2
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    • pp.47-55
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    • 2012
  • Generally, to product multi-grade oil like engine oil, a sort of mineral base oil is mixed with a fundamental additive package liquid and a polymer liquid as viscosity index improver in order to improve the lubricating property of base oil. That is, engine oil is the mixture of more than two fluids. Specially, a polymeric type liquid cannot be seen as the linear viscosity like Newtonian fluids. In this research, by using the governing equation describing non-Newtonian hydrodynamic lubrication related with the mixture of incompressible fluids based on the principle of continuum mechanics, it will be compared the bearing performance between the mixture of each liquid to be blended and multi-grade engine oil as a single fluid in a high speed hydrodynamic journal bearing. Further, it is to be found the way estimating the performance of the blended multi-grade engine lubricant in a journal bearing in advance before blending by using the physical properties of mineral base oil, fundamental additive liquid and polymer liquid of viscosity index improver. So, it can be reduced the number of trial and error to get the wanted lubricant by selecting the proper volume fraction of each liquid to satisfy the expected performance and estimating in advance the performance of various multi-grade oils before blending. Therefore, it can be shorten the developing time and saved the developing cost.

A Study on Performance Improvement in Durability and Reliability of LPi Injector (LPI 인젝터의 성능 및 내구성 개선에 관한 연구)

  • Park, Cheol-Woong;Kim, Chang-Up;Choi, Kyo-Nnam;Baik, Seung-Kook;Shin, Moon-Sung
    • Journal of the Korean Institute of Gas
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    • v.16 no.2
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    • pp.38-44
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    • 2012
  • In recent years, the need for more fuel-efficient and lower-emission vehicles has driven the technical development of alternative fuels such as LPi (Liquid phase LPG injection) which uses pump for the high pressure supply of liquid LPG fuel and is able to meet the limits of better emission levels while it has an advantage of higher power. Although it has the advantage of power and lower emission levels, the characteristics of LPG, such as high vapor pressure, lower viscosity and surface tension than gasoline fuels makes it difficult design system. Therefore most fuel pumps and injectors are imported. In the present study, in order to domestically develop LPG injector which guarantees flow rates and optimal operation, the experimental investigation on leakage and flow rate characteristics of developed prototype injector was carried out at the bench test rig for developed injector.