• 청정기술
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• 제22권3호
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• pp.203-207
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• 2016

Here, we report a novel fabrication technique for patchable organic lasing sheet based on non-volatile liquid organic semiconductors and freestanding polymeric film with high flexibility and patchability. For this work, we have fabricated the second-order DFB grating structure, which leads to surface emission, embedded in the freestanding polymeric film. Using an ultra-violet (UV) curable polyurethaneacrylate (PUA) mixture, the periodic DFB grating structure can be easily prepared on the freestanding polymeric film via a simple UV curing process. Due to unsaturated acrylate remained in the PUA mixture after UV curing, the freestanding PUA film provides adhesive properties, which enable mounting of the patchable organic lasing sheet onto non-flat surfaces with conformal contact. To achieve laser actions in the freestanding resonator structure, a composite material of liquid 9-(2-ethylhexyl)carbazole (EHCz) and organic laser dyes was used as the laser medium. Since the degraded active materials can be easily refreshed by a simple injection of the liquid composite, such a non-volatile liquid organic semiconducting medium has degradation-free and recyclable characteristics in addition to other strong advantages including tunable optoelectronic responses, solvent-free processing, and ultimate mechanical flexibility and uniformity. Lasing properties of the patchable organic lasing sheet were also investigated after mounting onto non-flat surfaces, showing a mechanical tunability of laser emission under variable surface curvature. It is anticipated that these results will be applied to the development of various patchable optoelectronic applications for light-emitting displays, sensors and data communications.

• 대한기계학회논문집B
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• 제32권7호
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• pp.529-535
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• 2008

The characteristics of combustion process in an internal combustion engine are affected by the mixing process between injected fuel and ambient gas. Therefore, it is necessary to understand the mixture formation process of diesel spray. In this study, the spray structure was visualized by the exciplex fluorescence method, which can provide the simultaneous 2-D images of vapor and liquid phase in inner spray. For accurate investigation, the liquid-phase images were recorded with a 35mm still camera and CCD camera. Consequentially, it could be confirmed that the high-concentration vapor phase is formed in the region of spray tip and the edge of the liquid phase where droplets exist in the evaporating diesel spray, and the formed vapor is spread by diffusion. Also, the distribution of vapor is determined by the motion of droplets that exist in the edge of the liquid phase and the spray-tip region.

• 한국응용과학기술학회지
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• 제19권4호
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• pp.251-257
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• 2002

Liquid-phase methanol synthesis via methyl formate using coal-derived syngas was carried out in a bench-scale(diameter 173 mm and dispersion height 1200 mm) slurry bubble column reactor(SBCR) Under the condition of $180^{\circ}$. 61 atm, 30 L/min, $H_{2}$/CO=2 and a slurry mixture of 2 kg of copper chromite and 0.5 kg of $KOCH_{3}$ suspended in 14 L of methanol, the per pass conversions of syngas is 6 %, maximum concentration of methyl formate 3.088 mol% and maximum synthesis, rate of methanol 0.8 gmole/kg ${\cdot}$ hr. It is a significant evidence that copper chromite powder as heterogeneous catalyst didn't active for the hydrogenolysis of methyl formate to methanol, resulting copper chromite powder was not efficiently suspended in a slurry mixture. To enhance the hydrogenolysis of methyl formate in liquid-phase methanol synthesis process, the designed SBCR have need to use the higher specific gravity solvent and/or decrease the catalyst particle size.

• 설비공학논문집
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• 제7권1호
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• pp.120-131
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• 1995

Thermodynamic analysis of extraction process from the constant pressure LNG(Liquefied Natural Gas) vessel was performed in this study. LNG was assumed as a binary mixture of 90% methane and 10% ethane by mole fraction. The thermodynamic properties such as temperature, composition, specific volume and the amount of cold energy were predicted during extraction process. Pressure as a parameter ranges from 101.3kPa to 2000kPa. The result shows the peculiar phenomena for the LNG as a mixture. Both vapor and liquid extraction processes were investigated by a computer model. The property changes are negligible in the liquid extraction process. For the vapor extraction process, the temperature in the vessel increases rapidly and the extracted composition of methane decreases rapidly near the end of extracting process. Specific volume of vapor has the maximum and that of liquid has the minimum during the process. When pressure is increased, specific volume of vapor decreases and that of liquid increases. It was found that specific volume of vapor phase had a major effect on the heat absorption at constant pressure during vapor extraction process. If the pressure of the vessel increases, the total cold energy which can be utilized from LNG decreased.

• 공업화학
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• 제16권6호
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• pp.749-754
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• 2005

이성분 methanol/3-methyl-1-butanol계에 대하여 정온하 즉 50, 55 60, 65 및 $70^{\circ}C$에서의 기-액평형치를 측정하고, 그 측정치를 이용하여 기-액평형치를 추산하는 추산식을 이끌어 내었다. 측정치와 추산치를 비교 검토한 결과 기상조성의 몰분율은 ${\pm}0.0007$의 오차범위 내에서 잘 일치하고, methanol/3-methyl-1-butanol계에 대한 과잉 몰부피를 측정한 결과 전체 조성범위에서 양의 편차를 나타내며 최대치는 x= 0.683에서 $0.096cm^3/mol$로 나타났다.

• 한국추진공학회지
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• 제27권1호
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• pp.27-36
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• 2023

소형로켓엔진에 적용되는 기체-액체 스월 동축형 인젝터의 분무성능을 파악하고자 형상변수와 추진제의 공급조건을 변화시켜 수류시험을 수행하였다. 인젝터의 형상변수인 스월 챔버의 직경 및 수축부의 각이 증가할수록 스월 강도가 증대되어 분무성능이 향상되었다. 또한, 기체-액체의 운동량 플럭스 비가 증가함에 따라 기체 유동이 액적 일부를 분무액막에서 이탈시켜, 분무시트의 중심부에서 gas-droplet mixture core가 형성되었다.

• 한국분무공학회지
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• 제2권2호
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• pp.1-7
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• 1997

• Bulletin of the Korean Chemical Society
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• 제24권10호
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• pp.1515-1516
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• 2003

• Korean Chemical Engineering Research
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• 제52권3호
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• pp.307-313
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• 2014

본 연구에서는 Isobutyl Acetate와 Isobutyl Alcohol의 공비혼합물을 압력변환증류공정(PSD; Pressure Swing Distillation Process)을 이용하여 99.9 mol% 이상의 Isobutyl Acetate를 분리하는 공정모사를 수행하였다. 압력변환증류공정은 공비혼합물의 상대휘발도와 공비조성이 압력의 변화에 따라 차이가 나는 특성을 이용한 공정이다. 액상에서는 Non-Random Two Liquid (NRTL) model을 그리고 기상에서는 Peng-Robinson equation을 이용하였다. 최적화 방법으로 환류비와 주입단 위치를 변수로 두고 총 재비기 소요 열량을 최소화시키는 목적으로 최적화를 수행하였다. 압력변환 증류공정은 두 개의 증류탑을 필요로 함에 따라 고압 증류탑과 저압 증류탑의 배열에 따른 최적화 조건 또한 비교를 수행하였다.

• Restorative Dentistry and Endodontics
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• 제19권1호
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• pp.217-230
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• 1994

The purpose of this study was to assess the 24-hour shear bond strength of amalgam to glass ionomer cement, using five different intermediaries. The intermediaries used in this study were Scotchbond 2 (light curing dentin adhesive), Panavia (resin cement), liquid' of glass ionomer cement (chemical curing & light curing), and uncured mixture of light curing glass ionomer cement. This study was operated with 48 specimens devided into 6 groups. The experimental groups are as follows: Group 1 : Bonded Amalgam to chemical curing glass ionomer cement with liquid of chemical curing glass ionomer. Group 2 : Bonded Amalgam to light curing glass ionomer cement with liquid of chemical curing glass ionomer. Group 3: Bonded Amalgam to light curing glass ionomer cement with resin cement. Group 4: Bonded Amalgam to light curing glass ionomer cement with light curing dentin adhesive. Group 5: Bonded Amdlgam to light curing glass ionomer cement with liquid of light curing glass ionomer. Group 6: Bonded Amalgam to light curing glass ionomer cement with uncured mixture of light curing glass ionomer cement. 30 minutes after amalgam condensation, all specimens were stored for 24 hours in water at $37^{\circ}C$ and tested with Instron (1122). The following results obtained: 1. The shear bond strength of group 6 was higher than those of the other groups (46.7 kgf/$cm^2$, p<0.05). 2. The shear bond strength of resin cement intermediary group was lower than that of the group using uncured mixture of light curing glass ionomer cement. 3. The results of group 1 and group 2 were different, even though the inter-me diaries used were same. 4. Intermediary of Group 5 did not show complete set in Scanning Electromicroscopic examination. 5. Light-curing dentin adhesive did not show any bonding ability to amalgam.