• Title/Summary/Keyword: liquid membrane

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Forward Osmosis Based Seawater Desalination using Liquid Fertilizer as Draw Solution (액상 비료를 유도 용액으로 사용하는 정삼투 기반의 해수 담수화)

  • Park, Seong-Jik;An, Hee-Kyung
    • Journal of The Korean Society of Agricultural Engineers
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    • v.55 no.2
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    • pp.21-27
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    • 2013
  • The present study explored the way to desalinate seawater for agricultural irrigation using forward osmosis (FO) process using liquid fertilizer as draw solution. FO experiments were performed in a cross flow mode using flat sheet FO membrane. The effect of membrane orientation, flow rate, and draw solution concentration on the performance of forward osmosis was investigated by measuring water flux of forward osmosis membrane. The water flux when the draw solution was placed against the membrane active layer was lower than the water flux when the feed solution was placed against the membrane active layer. This results indicated that the decrease of effective osmotic pressure by dilutive internal concentration polarization was less than that by concentrative internal concentration polarization. Increasing flow rate from 66.7 to 133.1 $cm^3$/min resulted in increase of the water flux when the membrane active layer orient to draw solution and feed solution, respectively. The reduction of resistance to water flow increased water flux at higher flow rate. The water flux of FO membrane increased with increasing draw solution concentration from 10000 to 30000 mg/L. The water flux for $KH_2PO_4$ draw solution was similar to that for commercial fertilizer. Optimization of FO process would contribute to economically desalinate brackish water for agricultural use.

Finite Element Analysis of Membrane for LNG Storage Tank (액화천연가스 저장탱크용 멤브레인의 유한요소해석)

  • 김영규;윤인수;홍성호;전인기
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.18 no.10
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    • pp.2797-2804
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    • 1994
  • This paper analyzes the behaviors of corrugated membrane under the cryogenic liquid pressure and thermal loading using the FEM analysis program MARC. The FEM calculations were carried out on the basis of measured data of Technigaz membrane. It is very important to know the concentration levels and distributions of stress in the corrugated membrane. A quarter of the membrane sheet in place of the whole membrane was simulated because of its geometric symmetricity. The calculated results of the concentrated stress showed that the maximum stress occurs at the knot parts and at the root corner radius of the corrugations. The FEM calculated results indicated that the ring knot membrane which was developed in this study showed uniformly distributed stress and the lowest stress levels in the cross knot area in comparison with other two membranes. These results are very important to optimize the shape and improve the safety of membrane structure.

Perfluorinated Sulfonic Acid Ionomer-PTFE Pore-filling Membranes for Polymer Electrolyte Membrane Fuel Cells (고분자전해질연료전지용 과불소계 술폰화 이오노머-PTFE 강화막)

  • Kang, Seong Eun;Lee, Chang Hyun
    • Membrane Journal
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    • v.25 no.2
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    • pp.171-179
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    • 2015
  • Perfluorinated sulfonic acid ionomers (PFSAs) have been widely as solid electrolyte materials for polymer electrolyte membrane fuel cells, since they exhibit excellent chemical durability under their harsh application conditions as well as good proton conductivity. Even PFSA materials, however, suffer from physical failures associated with repeated membrane swelling and deswelling, resulting in fairly reduced electrochemical lifetime. In this study, pore-filling membranes are prepared by impregnating a Nafion ionomer into the pore of a porous PTFE support film and their fundamental characteristics are evaluated. The developed pore-filling membranes exhibit extremely high proton conductivity of about $0.5S\;cm^{-1}@90^{\circ}C$ in liquid water.

Distortion of Eelectrical Double Layer in Liquid Filtration by Fibrous Filters

  • Lee, Myong-Hwa;Hirose, Shogo;Otani, Yoshio
    • Particle and aerosol research
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    • v.10 no.3
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    • pp.99-108
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    • 2014
  • Liquid filtration by membrane filters is essential for the preparation of ultrapure water in semiconductor manufacturing processes. The separation of submicrometer particles suspended in ultrapure water with a laminated fibrous membrane filter was studied numerically and experimentally in the present work. We found that an electrical double layer around a single fiber expanded to a large extent at a low ion concentration, as in ultrapure water, and deformed toward the upstream of the fiber with increasing filtration velocity. Since an increase in the electrical double-layer thickness leads to a decrease in the electrical potential gradient, particles with the same polarity as the fiber approach the fiber more easily and are captured at a high filtration velocity. Experimental results also confirmed that the collection efficiency of polystyrene latex(PSL) particles through a PTFE filter became higher as the filtration velocity increased.

Finite Element Analysis of the Corrugated Membrane of LNG Storage Tank for Its Geometric Design (LNG 저장탱크용 멤브레인 형상설계를 위한 유한요소해석)

  • 김성원;이성우;이중남
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 1997.04a
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    • pp.620-624
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    • 1997
  • Corrugated membranes which are used as a means of liquid- and gas-sealing for a LNG storage tank and provide one of the most reliable primary barrier are the main component of in-ground membrane types for the assurance of high safety. It absorbs large thermal and mechanical deformations caused by ultra low temperature of LNG, -162 .deg.c, the cryogenic liquid and mechanical deformations caused by was carried out on crossing corrugation by commercial F.E code, ANSYS. This paper presents some of results in stress analysis of membranes performed for the purpose to investigate the strength of existing membrane for LNG storage tank designed by IHI,MHI, KHI and KGC expect for Technigaz eariy published. Based on these analytical studies,design criteria were estabilished and SHI original membranes having a high level of safety and fitting to larger capacities were developed.

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REPONSE OF POLYMERIC MEMBRANES AS SENSING ELEMENTS FOR ELECTRONIC TOUGUE

  • Bae, Y.M.;Cho, S.I.
    • Proceedings of the Korean Society for Agricultural Machinery Conference
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    • 2000.11b
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    • pp.219-226
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    • 2000
  • The study was executed for development of sensing elements of electronic tongue which could discriminate taste of liquid and semi-liquid foods. Five polymeric membranes which were composed of polymer, plasticizer, electro-active materials were prepared. After each polymeric membranes were mounted in an electrode body, membrane potentials due to electrochemical reaction with taste stimuli were measured. The experimental results were interpreted in view of the membrane's non-selective responses to stimuli.

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Facilitated Transport of Cr(VI) through a Supported Liquid Membrane with a Carrier

  • Park, Sang-Wook;Lee, Jae-Wook;Kim, Sung-Soo;Choi, Byoung-Sik
    • Journal of the Korean Applied Science and Technology
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    • v.20 no.2
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    • pp.154-164
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    • 2003
  • This paper has applied a simple model to the mass transfer mechanism of Cr(VI) with crownether in a batch-type, supported liquid membrane module. Concentration at pH 3 are as follows : 0.012 kmol/$m^3{\le}$18-crown-6${\le}$0.036 kmol/$m^3$ and 20 g/$m^3{\le}$ Cr(VI)${\le}$500 g/$m^3$. The measured values of forward- and backward-reaction rate constants between Cr(VI) and 18-crown-6 were used to simulate the model with the mass conservation equation and associated boundary conditions. Comparison between the experimental and simulated facilitated factor of Cr(VI) transport led to classification of reaction regions.

Efficient extraction and recovery of Lignosulfonate using sunflower oil as green solvent in liquid membrane transport: Equilibrium and kinetic study

  • Kumar, Vikas;Singh, Raghubansh K.;Chowdhury, Pradip
    • Journal of Industrial and Engineering Chemistry
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    • v.67
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    • pp.109-122
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    • 2018
  • This work highlights extraction and removal of Lignosulfonate using sunflower oil-Tri-n-octylamine (TOA) system in bulk liquid membrane transport. Maximum extraction and recovery percentages of 92.4% and 75.2% were achieved. Optimum manifold operating conditions were: 4 vol.% TOA, $2{\pm}0.1$ feed phase pH, 300 rpm stirring speed, at $40^{\circ}C$ with 0.2 (M) $Na_2SO_4$ solution. 1:2 (organic/aqueous) and 1:1 (aqueous/aqueous) phase ratios produced best results. Extraction (36.85 kJ/mol) was found to be intermediate controlled and stripping (54.79 kJ/mol) was chemical reaction controlled. Kinetic estimation of data with higher rate constants for stripping vis-${\grave{a}}$-vis extraction showed latter to be rate determining.

In Vitro Test of a Micro Syringe Fabricated for the Intravascular Injection (초소형 주사 시스템의 모의 혈관 내에서의 작동 시험)

  • Kim, Geun-Young;Sim, Woo-Young;Lee, Sang-Woo;Yang, Sang-Sik;Chang, Jun-Keun;Lee, Seung-Ki
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.50 no.6
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    • pp.307-313
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    • 2001
  • A micro syringe which can be attached to the end of a micro intravascular endoscope for drug injection is fabricated and its characteristic is tested. The syringe consists of a drug chamber and an actuator chamber which are separated by a silicone rubber membrane. The drug chamber is filled with liquid drug by the membrance actuation caused by the vaporization and condensation of the working liquid in the actuator chamber. The liquid drug is ejected by the electrolysis of the working liquid. The membrane deflection by each actuation method has been measured. The liquid ejection image has been captured during the electrolysis of the electrolyte. Also, the successful operation of the micro syringe under the normal blood pressure was verified.

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