Journal of Industrial and Engineering Chemistry

  • Volume 67
  • /
  • Pages.109-122
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  • 2018
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  • 1226-086X(pISSN)
  • /
  • 1876-794X(eISSN)
The Korean Society of Industrial and Engineering Chemistry (한국공업화학회)
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Efficient extraction and recovery of Lignosulfonate using sunflower oil as green solvent in liquid membrane transport: Equilibrium and kinetic study

  • Kumar, Vikas (Department of Chemical Engineering, National Institution of Technology Rourkela) ;
  • Singh, Raghubansh K. (Department of Chemical Engineering, National Institution of Technology Rourkela) ;
  • Chowdhury, Pradip (Department of Chemical Engineering, National Institution of Technology Rourkela)
  • Received : 2017.06.19
  • Accepted : 2018.06.22
  • Published : 2018.11.25
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Abstract

This work highlights extraction and removal of Lignosulfonate using sunflower oil-Tri-n-octylamine (TOA) system in bulk liquid membrane transport. Maximum extraction and recovery percentages of 92.4% and 75.2% were achieved. Optimum manifold operating conditions were: 4 vol.% TOA, $2{\pm}0.1$ feed phase pH, 300 rpm stirring speed, at $40^{\circ}C$ with 0.2 (M) $Na_2SO_4$ solution. 1:2 (organic/aqueous) and 1:1 (aqueous/aqueous) phase ratios produced best results. Extraction (36.85 kJ/mol) was found to be intermediate controlled and stripping (54.79 kJ/mol) was chemical reaction controlled. Kinetic estimation of data with higher rate constants for stripping vis-${\grave{a}}$-vis extraction showed latter to be rate determining.

Keywords

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