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http://dx.doi.org/10.12925/jkocs.2003.20.2.11

Facilitated Transport of Cr(VI) through a Supported Liquid Membrane with a Carrier  

Park, Sang-Wook (Department of Chemical Engineering, Pusan National University)
Lee, Jae-Wook (Department of Chemical Engineering, Sogang University)
Kim, Sung-Soo (School of Industrial Hygiene and Environmental System Engineering, Catholic University of Pusan)
Choi, Byoung-Sik (Department of Chemical Engineering, Pusan National University)
Publication Information
Journal of the Korean Applied Science and Technology / v.20, no.2, 2003 , pp. 154-164 More about this Journal
Abstract
This paper has applied a simple model to the mass transfer mechanism of Cr(VI) with crownether in a batch-type, supported liquid membrane module. Concentration at pH 3 are as follows : 0.012 kmol/$m^3{\le}$18-crown-6${\le}$0.036 kmol/$m^3$ and 20 g/$m^3{\le}$ Cr(VI)${\le}$500 g/$m^3$. The measured values of forward- and backward-reaction rate constants between Cr(VI) and 18-crown-6 were used to simulate the model with the mass conservation equation and associated boundary conditions. Comparison between the experimental and simulated facilitated factor of Cr(VI) transport led to classification of reaction regions.
Keywords
facilitated transport; immobilized liquid membrane; Cr(VI); 18-crown-6; mass transfer coefficient;
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