• Title/Summary/Keyword: liquid absorption

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Analysis of Heat and Mass Transfer on Helical Absorber (헬리컬 흡수기의 흡수 열물질전달 해석)

  • Gwon, O-Gyeong;Im, Jong-Geuk;Yun, Jeong-In;Kim, Seon-Chang;Yun, Jae-Ho
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.24 no.11
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    • pp.1428-1436
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    • 2000
  • The absorption of vapor involves simultaneous heat and mass transfer in the vapor/liquid system. In this paper, a numerical study for vapor absorption process into LIBr-H$_2$O solution film flowing over helical absorber has been carried out. Axisymmetric cylindrical coordinate system was adopted to model the helical tube and the transport equations were solved by the finite volume method. The effects of operating conditions, such as the cooling water temperature. the system pressure, the film Reynolds number and the solution inlet concentration have been investigated in view of the absorption mass flux and the total absorption mass flux and the total absorption rate. The results for the temperature and concentration profiles, as well as the local absorption mass flux at the helical absorber are presented. It is shown that solution inlet concentration affected other than operation conditions for a mass flux.

Absorption characteristic of carbon dioxide in Ionic Liquids based sulfite anion in the pre-combustion condition (연소 전 조건에서 음이온이 Sulfite계인 이온성 액체의 CO2 흡수 특성)

  • Baek, Geun Ho;Jang, Hyun Tae;Cha, Wang Seog
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.22 no.3
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    • pp.763-769
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    • 2021
  • In this study, ionic liquids were synthesized to remove carbon dioxide (CO2) on a laboratory scale. The vapor-liquid absorption equilibrium device (VLE) was used to investigate the carbon dioxide absorption capacity. In the regeneration study, the absorption capacity after regeneration was reduced by approximately 7% for all ionic liquids, in which the anion was sulfite-based, showing excellent regeneration. Ethyl sulfite showed the highest absorption capacity of CO2 among the ionic liquids based on the sulfite anion. In particular, the absorption capacity of [beim] ethyl sulfite was 1.1 mol CO2 / mol IL at an absorption equilibrium pressure of 22 bar. In the regeneration study, the absorption capacity after regeneration was reduced by approximately 7% for all ionic liquids, in which the anion was sulfite-based, from which regeneration is outstanding. After the absorption experiment, the viscosity of the sample tended to decrease by approximately 8% compared to that before the absorption experiment. On the other hand, the absorbent was synthesized in the first step. Moreover, the raw material used is also inexpensive and has excellent reproducibility and highly stable absorbent capacity.

Chemical Reaction of Carbon Dioxide with AMP in w/o Emulsion Membrane (W/O 에멀션액막에서 이산화탄소와 AMP의 화학반응)

  • Park Sang-Wook;Choi Byoung-Sik;Kim Seong-Soo;Lee Jae-Wook
    • Membrane Journal
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    • v.14 no.4
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    • pp.275-288
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    • 2004
  • Carbon dioxide was absorbed into water-in-oil (w/o) emulsion composed of aqueous 2-amino-2-methyl-1-propanol (AMP) droplets as a dispersed phase and benzene solutions of polybutene and polyisobutylene as a continuous phase in a flat-stirred vessel to investigate the effect of non-Newtonian rheological behavior on the rate of chemical absorption of $CO_2$, where the reaction between $CO_2$ and AMP in the aqueous phase was assumed to be a pseudo-first-order reaction. It was expressed that PIB with elastic property made the rate of chemical absorption of $CO_2$ accelerated by comparison of mass transfer coefficient of $CO_2$ in the non-Newtonian liquid with that in the Newtonian liquid.

Mass transfer characteristics of benzene in nonpolar solution (비극성용매 내의 벤젠 물질전달특성)

  • 최성우;김혜진;박문기
    • Journal of Environmental Science International
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    • v.11 no.6
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    • pp.605-610
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    • 2002
  • The absorption of benzene in nonpolar solution was studied in a laboratory-scale of bubble column varying of gas flow rates and gas-to-liquid ratios. A bubble column had a 0.8∼l$\times$10$\^$-3/ m$^3$ total volume (height 1500 mm, diameter 50 mm). Solution analysis was performed by GC-FID and GC-MSD. The objectives of this research were to select the best absorption fluid and to evaluate the mass transfer characteristics under specific conditions of each absorption. The results of this research were follow as: First, the heat transfer fluid is more efficient than the other nonpolar solution in removing VOC. Second, The benzene removal efficiency improved according to an increasing rate of gas flow. Also, volumetric mass transfer rate of column can be enhanced by increasing gas flow rate. Finally, the relation of gas flow rates, liquid amount, and volumetric mass transfer coefficient was obtained as follows. K$\_$y/a: 0.5906(V$\_$g//L)$\^$0.7611/ The following correlation of mass transfer coefficient and efficiency was proposed. v= 0.06078 K$\_$y/a$\^$0.2444/.

Noise Generation by Water-Sodium Reaction and its Absorption on Hydrogen Bubbles for KALIMER Steam Generator (칼리머 증기발생기에서 물-소듐 반응에 의한 소음 발생과 수소 기포의 소음 흡수)

  • Kim, Tae-Joon;Yughay, Valeri S.;Hwang, Sung-Tai
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2000.06a
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    • pp.1829-1835
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    • 2000
  • The experimental results of sodium-water reaction noise measurement in frequency range $1{/sim}200kHz$ are presented. The experiments of noise generation under the condition of sodium test facility, water leak rate $0.01{\sim}1.2g/s$ and temperature of sodium $250{\sim}500^{\circ}C$, were carried out. From theoretical study it is noted that the noise resonant attenuation on hydrogen bubbles in liquid sodium plays the significant role for leak noise spectra formation. Interaction of leak noise and hydrogen bubbles in sodium being accompanied by thermal, emission and viscosity energy dissipation was studied. Acoustic noise spectra were investigated from point of view of water leak detection in sodium/water steam generator. The results of sodium-water reaction noise absorption on hydrogen bubbles in liquid sodium by temperature $250{\sim}500^{\circ}C$ are presented. The theoretical model of noise absorption using the coefficients of attenuation was developed. From calculation the coefficients of attenuation were estimated.

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Response Surface Approach to Design Optimization of Regenerator Using Hot Air Heated by Solar Collector (태양열 온풍 이용을 위한 재생기의 설계 최적화 모델에 관한 연구)

  • Woo, Jong-Soo;Choi, Kwang-Hwan;Yoon, Jeong-In
    • Journal of the Korean Solar Energy Society
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    • v.23 no.3
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    • pp.7-14
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    • 2003
  • Absorption potential of desiccant solution significantly decreases after absorbing moisture from humid air, and a regeneration process requires a great amount of energy to recover absorption potential of desiccant solution. In an effort to develop an energy efficient regenerator, this study examines a regeneration process using hot air heated by solar radiation to recover absorption potential by evaporating moisture in liquid desiccant. More specifically, this study is aimed at finding the optimum operating condition of the regenerator by utilizing a well-established statistical tool, so-called response surface methodology(RSM), which may provide a functional relationship between independent and dependent variables. It is demonstrated that an optimization model to find the optimum operating condition can be obtained using the functional relationship between regeneration rate and affecting factors which is approximated on the basis experimental results.

Instability Analysis of Marangoni Convection for $NH_3-H_2O$ Absorption Process Accompanied by Heat Transfer (열전달을 수반하는 $NH_3-H_2O$ 흡수과정에서의 Marangoni 대류 불안정성 해석)

  • 김제익;최창균;강용태
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.15 no.2
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    • pp.126-131
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    • 2003
  • Convective instability driven by surface tension is analyzed in an initially quiescent water absorbing ammonia gas with heat transfer using the linear stability analysis. The propagation theory is adapted to find the critical conditions of the onset of Marangoni convection. In this theory, the solutal penetration depth is chosen as the length scale factor. The results show that the liquid layer becomes more stable with decreasing the Schmidt number and increasing the Lewis number. It is also found that there is a critical Biot number to make the liquid layer be most unstable, and there is a linear relationship between the thor-mal Marangoni number and the solutal Marangoni number.

Photoisomerization and Photo-induced Optical Anisotropy of Polymethacrylate Containing Aminonitroazobenzene

  • Park, Dong-Hoon;Cho, Kang-Jin
    • Fibers and Polymers
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    • v.2 no.1
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    • pp.123-130
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    • 2001
  • Photoresponsive side chain copolymer and homopolymer containing an aminonitroazobenzene were synthesized for studying photoisomerization behavior and photo-induced anisotropy. Trans-to-cis photoisomerization was observed under the exposure of a circularly polarized visible light with UV-Vis absorption spectroscopy. Reorientation of polar azobenzene molecules induced optical anisotropy under a linearly polarized light at 532nm. Polarized absorption spectroscopy was employed to investigate the anisotropy of the polymer film during irradiationg of the excitation light. Layers of two photosensitive polymers were used for aligning liquid crystal(LC) molecules instead of one of the rubbed polyimide layers in the conventional twisted nematic cell. For producing homogeneous alignment of a nematic LC molecule, a linearly polarized light was exposed to the films of two polymers. The stability of the LC alignment upon the linearly polarized light exposure was also studied.

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A Study on the Acoustic Damping Characteristics of Acoustic Cavities in a Liquid Rocket Combustor (로켓연소실에서 음향공의 음향학적 감쇠에 대한 정량적 고찰)

  • Kim Hong Jip;Kim Seong-Ku
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.30 no.1 s.244
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    • pp.32-40
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    • 2006
  • A linear acoustic analysis has been performed to elucidate damping characteristics of acoustic cavities in a liquid rocket combustor. Results have shown that resonant frequencies of acoustic cavity obtained by classical theoretic approach and by the present linear analysis are somewhat different with each other. This difference is attributed to the limitation of the simplified classical theory. To quantify the damping characteristics, acoustic impedance has been introduced and resultant absorption coefficient and conductance have been evaluated. Satisfactory agreement has been achieved with previous experiment. Finally the design procedure for an optimal tuning of acoustic cavity has been established.

Frequency-domain Diffuse Optical Tomography System Adopting Lock-in Amplifier (Lock-in 증폭기를 채용한 주파수영역 확산 광단층촬영 시스템)

  • Jun, Young-Sik;Baek, Woon-Sik
    • Korean Journal of Optics and Photonics
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    • v.22 no.3
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    • pp.134-140
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    • 2011
  • In this paper, we developed a frequency-domain diffuse optical tomography(DOT) system for non-invasively imaging in vivo. The system uses near-infrared(NIR) light sources and detectors for which the photon propagation in human tissue is dominated by scattering rather than by absorption. We present the experimental reconstruction images of absorption and scattering coefficients using a liquid tissue phantom, and we obtain the location and shape of an anomaly which has different optical properties than the phantom.