• Title/Summary/Keyword: liquid absorption

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Development of a Novel System for Measuring Sizing Degree Based on Contact Angle(I) - Development of a Novel Principle for Automatic Measurement of Contact Angle - (접촉각 측정 원리를 이용한 새로운 사이즈도 측정기 (제1보) -자동 접촉각 측정 원리의 개발 -)

  • 이찬용;김철환;최경민;박종열;권오철
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.35 no.3
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    • pp.43-52
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    • 2003
  • The new principle to measure a sizing degree by a contact angle was developed using an automatic determination of the 3-end point coordinates of the water droplet on a sheet, which could diminish the operator's bias during measurement. A constant amount of water was first placed on a sample sheet by a water dispenser, and then an image of the liquid droplet was captured by a digital camera and then transmitted to a computer. The program measuring for contact angle extracted a liquid contour by Gaussian function combined with a 8-direction chain code. The Euclidean equation was applied to the binary image of the liquid contour in order to measure the diameter of the contour. Finally, the contact angle of the liquid was calculated by using the diameter and the top coordinates. In addition, a surface free energy of the sample sheet and an elapsed time taken up to the complete absorption into the sheet were simultaneously measured with the contact angle.

Frost Prevention of Fin-Tube Heat Exchanger by Spreading Antifreezing Solution (부동액 도포에 의한 핀-튜브 열교환기 착상방지)

  • Oh, Sang-Youp;Chang, Young-Soo
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.18 no.6
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    • pp.477-485
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    • 2006
  • A study on frost prevention of fin-tube heat exchanger is experimently performed by spreading antifreezing solution on heat exchanger surface. It is desirable that the antifreezing solution spreads completely on the surface forming thin liquid film to prevent frost nucleation and crystal growth and to reduce the thermal resistance across the liquid film. A small amount of antifreezing solution falls in drops on heat exchanger surface using two types of supplying devices, and a porous layer coating technique is adopted to enhance the wettedness of antifreezing solution on the surface. It is observed that the antifreezing solution liquid film prevents fin-tube heat exchanger from frosting, and heat transfer performance does not degrade through the frosting tests. The concentration of supplied antifreezing solution can be determined by heat transfer analysis of the first row of heat exchanger to avoid antifreezing solution freezing due to dilution by moisture absorption.

Thermodynamic Analysis of the Extraction Process and the Cold Energy Utilization of LNG (LNG추출과정과 냉열이용의 열역학적 해석)

  • Lee, G.S.;Chang, Y.S.;Ro, S.T.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.7 no.1
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    • pp.120-131
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    • 1995
  • Thermodynamic analysis of extraction process from the constant pressure LNG(Liquefied Natural Gas) vessel was performed in this study. LNG was assumed as a binary mixture of 90% methane and 10% ethane by mole fraction. The thermodynamic properties such as temperature, composition, specific volume and the amount of cold energy were predicted during extraction process. Pressure as a parameter ranges from 101.3kPa to 2000kPa. The result shows the peculiar phenomena for the LNG as a mixture. Both vapor and liquid extraction processes were investigated by a computer model. The property changes are negligible in the liquid extraction process. For the vapor extraction process, the temperature in the vessel increases rapidly and the extracted composition of methane decreases rapidly near the end of extracting process. Specific volume of vapor has the maximum and that of liquid has the minimum during the process. When pressure is increased, specific volume of vapor decreases and that of liquid increases. It was found that specific volume of vapor phase had a major effect on the heat absorption at constant pressure during vapor extraction process. If the pressure of the vessel increases, the total cold energy which can be utilized from LNG decreased.

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How Do Liquid Crystal Molecules Align on Treated Surfaces?

  • Okada, Yoshinori;Shioda, Tatsutoshi;Chung, Doo-Han;Park, Byoung-Choo;Takezoe, Hideo
    • Journal of Information Display
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    • v.4 no.2
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    • pp.29-34
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    • 2003
  • We have studied liquid crystal (LC) molecular alignment on rubbed and photoaligned surfaces. Particular attention was paid to the intermolecular liquid crystalline interaction. We will first show that uniform molecular orientation on a rubbed surface does not mean spatially uniform interaction between the surface and LC molecules. Rather LCs tend to align themselves through LC interaction. The existence of nonuniformity of rubbing was successfully visualized by double surface treatment. The importance of intermolecular LC interaction was also found in the orientation formation process in 5CB evaporated on rubbed and photoaligned surfaces. By simultaneously analyzing polarized UVNIS absorption and second-harmonic generation (SHG) using the maximum entropy method, we succeeded in obtaining the temporal variation of the orientational distribution functions in the film forming process. The distribution anisotropy and pretilt are found to be generated under the influence of intermolecular LC interaction.

High-Performance Liquid Chromatographic Determination of Cyclosulfamuron Residues in Soil, Water, Rice Grain and Straw

  • Lee, Young-Deuk;Kwon, Chan-Hyeok
    • Korean Journal of Environmental Agriculture
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    • v.23 no.4
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    • pp.251-257
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    • 2004
  • Analytical methods were developed to determine cyclosulfamuron residues in soil, water, rice grain and straw using high-performance liquid chromatography (HPLC) with ultraviolet absorption detection. In these methods, cyclosulfamuron was extracted with aqueous $Na_2HPO_4$/acetone and acetone/methanol mixture from soil and rice samples respectively. Liquid-liquid partition coupled with ion-associated technique, Florisil column chromatography, and solid-phase extraction (SPE) were used to separate cyclosulfamuron from interfering co-extractives prior to HPLC analysis. For water sample, the residue was enriched in $C_{18}$-SPE cartridge, cleaned up in situ, and directly subjected to HPLC. Reverse-phase HPLC under ion-suppression was successfully applied to determine cyclo-sulfamuron in sample extracts with the detection at its ${\lambda}_{max}$ (254 nm). Recoveries from fortified samples averaged $87.8{\pm}7.1%$ (n=12), $97.3{\pm}7.2%$ (n=12), $90.8{\pm}6.6%$ (n=6), and $78.5{\pm}6.7%$ (n=6) for soil, water, rice grain and straw, respectively. Detection limits of the methods were 0.004 mg/kg, 0.001 mg/L, 0.01 mg/kg and 0.02 mg/kg for soil, water, rice grain and straw samples, respectively.

Liquid Chromatographic Determination of Etofenprox Residues in Foods with Mass-Spectrometric Confirmation

  • Lee, Young-Deuk;Kwon, Chan-Hyeok;Kwon, Ki-Sung
    • Korean Journal of Environmental Agriculture
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    • v.30 no.4
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    • pp.432-439
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    • 2011
  • BACKGROUND: An official analytical method was developed to determine etofenprox residues in agricultural commodities using high-performance liquid chromatography (HPLC). METHODS AND RESULTS: The etofenprox residue was extracted with acetone from representative samples of five raw products which comprised rice grain, apple, mandarin, cabbage, and soybean. The extract was then serially purified by liquid-liquid partition and Florisil column chromatography. For rice and soybean samples, acetonitrile/n-hexane partition was additionally coupled to remove nonpolar lipids. Reversed phase HPLC using an octadecylsilyl column was successfully applied to separate etofenprox from co-extractives. Intact etofenprox was sensitively detected by ultraviolet absorption at 225 nm. Recovery experiment at the quantitation limit validated that the proposed method could apparently determine the etofenprox residue at 0.02 mg/kg. Mean recoveries from five crop samples fortified at three levels in triplicate were in the range of 93.6~106.4%. Relative standard deviations of the analytical method were all less than 10%, irrespective of crop types. A selected-ion monitoring LC/mass spectrometry with positive atmospheric-pressure chemical ionization was also provided to confirm the suspected residue. CONCLUSION(s): The proposed method is simple, rapid and sensitive enough to be employed in routine inspection or monitoring of agricultural products for the etofenprox residue.

Study on the Energy Efficiency Improvement of Hybrid Dehumidification Air Conditioning System Compared with Refrigeration System (냉각식 시스템과 비교한 복합식 제습냉방시스템의 냉각 열량증가에 관한 실험적 연구)

  • Lee Su-Dong;Park Moon-Soo;Chung Jin-Eun;Choi Young-Seok
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.16 no.10
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    • pp.952-959
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    • 2004
  • The hybrid liquid desiccant air conditioning system has been in use for many years, primarily in industrial process applications requiring dehumidification and humidity control. In this study, the hybrid dehumidifier has been designed to study the dehumidification characteristic of the aqueous triethylene glycol (TEG) solution. The experimental results show energy efficient characteristics of hybrid liquid desiccant air conditioning system compared with the refrigeration system in terms of energy use, the difference of pressure loss between hybrid liquid desiccant air conditioning system and refrigeration system. Data obtained are useful for design guidance and performance analysis of the hybrid air conditioning system.

Study on the Performance Characteristics with the Height of a Regenerator and Dehumidifier for Liquid Desiccant Dehumidification System (액체식 제습시스템을 위한 재생기와 제습기의 높이에 따른 성능특성에 관한 연구)

  • 이수동;박문수;정진은;최영석
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.16 no.7
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    • pp.630-638
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    • 2004
  • Liquid desiccant dehumidification systems have the ability to provide efficient humidity and temperature control while saving the electrical energy requirement for air conditioning as compared to a conventional system. The dehumidifier and the regenerator form the heart of this system. The latent part of the cooling load is overcome using liquid desiccant. The model regenerator has been designed to study the absorption characteristic of the aqueous triethylene glycol (TEG) solution which is in the flow range from 20 to 50 LPM. Also, this system designed that was able to change the height of the regenerator and dehumidifier. Because the effect of performance have different result according the height. The effect of performance factors of the regenerator with inlet solution flow rate, air flow rate, solution concentration, solution temperature, brine temperature, air temperature and inlet air relative humidity have been analyzed. Data obtained are useful for design guidance and performance analysis of the hybrid air conditioning system.

Characteristics of artificial lightweight fine aggregates manufactured by using a vertical fluidizing furnace (수직형 유동층로에서 제조된 인공경량 세골재의 특성)

  • Kang, Seung-Gu
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.19 no.1
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    • pp.54-59
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    • 2009
  • It was difficult for the existing rotary kiln to fabricate the fine aggregates under 3 mm due to the sticking phenomenon between specimens. In this study, the vertical type fluidizing furnace was designed and manufactured by which the lightweight fine aggregates of specific gravity $1.1{\sim}1.7$, water absorption $11{\sim}19%$ could be fabricated from the green body of clay: stone sludge: spent bleaching clay = 60 : 30 : 10 (wt%) without sticking-together happening. The minimum sintering temperature for bloating of aggregates was $1130^{\circ}C$. The specimens sintered over $1140^{\circ}C$ showed the typical bloating characteristics of lightweight aggregates and an inner layer was discovered due to widened cracks on a surface. But the crack on a surface did not propagate into a black core area so had no effect on a water absorption of aggregates. The sintering temperature made the thickness of shell and the black core area thin and expanded respectively but the sintering time did not affect the microsturcture of aggregates. The water absorption of aggregates decreased with increasing temperature owing to increased amount of liquid formed on a surface. Also sintering time affected a lot on a water absorption because it takes a time to form a liquid, which change the open pores to closed pores by blocking.

Preparation of Borosilicate Foamed Glass Body with Sound Absorption Characteristics by the Recycling Waste Liquid Crystal Display Glass (폐 LCD 유리를 이용한 흡음특성을 갖는 붕규산유리발포체 제조)

  • Lee, Chul-Tae
    • Applied Chemistry for Engineering
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    • v.27 no.6
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    • pp.612-619
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    • 2016
  • In this research, an alumino-borosilicate foamed glass with sound absorption property was prepared using the waste borosilicate glass obtained from the recycling process of waste liquid crystal display (LCD) panel. A 100 g of pulverized waste borosilicate glass with the particle size of under 325 mesh, was mixed with 0.3 g (wt/wt) of graphite, each 1.5 g (wt/wt) of $Na_2CO_3$, $Na_2SO_4$ and $CaCO_3$ as a foaming agent, and 6.0 g (wt/wt) of $H_3BO_3$ and 3.0 g (wt/wt) of $Al_2O_3$ as a pore control agent. Following mixture was under the foaming process for 20 minutes at a foaming temperature of $950^{\circ}C$. The result yielded the foaming agent with 45% of the opened porosity and 0.5-0.7 of the sound absorbing coefficient. This alumino-borosilicate foamed glass with the sound absorption property showed excellent physical and mechanical properties such as density of $0.21g/cm^3$, bending strength of $55N/cm^2$ and compression strength of $298N/cm^2$ which can be ideally used as sound absorption materials with heat-resisting and chemical-resisting property.