• Transactions of the Korean hydrogen and new energy society
• /
• v.10 no.1
• /
• pp.19-26
• /
• 1999

The effectiveness of a double-tube heat exchanger has been investigated experimentally. This problem is of particular interest in the design of the heat exchanger in a hydrogen liquefaction system. Temperature, pressure, and mass flow rate for hydrogen were measured both in inner tube and in annulus of a double-tube heat exchanger. The effectiveness could be evaluated from the measured temperature and mass flow rate. It is found that the effectiveness increases with an increase in the heat transfer area of a double-tube heat exchanger and with a decrease of the heat capacity ratio. But the increase rate of the effectiveness decreased with a decrease of the heat capacity ratio. Therefore, it is presented that a criterion for selecting the heat exchanger length and heat capacity ratio to obtain the effectiveness required in a hydrogen liquefaction system.

• Transactions of the Korean hydrogen and new energy society
• /
• v.25 no.6
• /
• pp.594-601
• /
• 2014

Rare-earth (RE) nitrides can be used as magnetocaloric materials in low temperature. They exhibit ferromagnetism and have Curie temperature in the region from 6 to 70 K. In this study, Holmium nitride (HoN) nano particles were prepared through plasma arc discharge technique and their magnetocaloric properties were studied. Nitrogen gas ($N_2$) was employed as an active element for arc discharge between two electrodes maintained at a constant current. Also, it played an important role not only as a reducing agent but also as an inevitable source of excited nitrogen molecules and nitrogen ions for the formation of HoN phase. Partial pressure of $N_2$ was systematically varied from 0 to 28,000 Pa in order to obtain single phase of HoN with minimal impurities. Magnetic entropy change (${\Delta}S_m$) was calculated with data set measured by PPMS (Physical Property Measurement System). The as-synthesized HoN particles have shown a magnetic entropy change ${\Delta}S_m$) of 27.5 J/kgK in applied field of 50,000 Oe at 14.2 K thereby demonstrating its ability to be applied as an effective magnetic refrigerant towards the re-liquefaction of hydrogen.

• Journal of Energy Engineering
• /
• v.5 no.2
• /
• pp.176-182
• /
• 1996

The effects of some additives (black liquor, NaOH, water and wood) on the conversion of coal and product were investigated in the lab-scale, high pressure reacting system around 375$^{\circ}C$. The addition of black liquor enhances the coal conversion yield about 38.6%, which is mainly due to NaOH in black liquor. Also, sulfur of the black liquor in coal liquefaction process evolved hydrogen sulfide, which causes the odor problem. Addition of water in coal liquefaction increased CO$_2$content in the gas phase, and low boiling range components in liquid products. Coprocessing of wood and coal at 400$^{\circ}C$ increased yield of liquid product about 8%, but higher temperature above 400$^{\circ}C$ reduced liquid product due to increase of gas products.

• Transactions of the Korean hydrogen and new energy society
• /
• v.26 no.1
• /
• pp.15-20
• /
• 2015

During the liquefaction of hydrogen, the ortho hydrogen is converted into the para form with heat release that evaporates the liquefied hydrogen into the gaseous one backwards. The ortho-para conversion catalysts are usually used during liquefaction to avoid such boil-off. In order to compare and analyze the performance of the ortho-para hydrogen conversion catalysts, in-situ FT-IR device was designed and manufactured to measure the para hydrogen conversion rate in real-time. $LaFeO_3$ and $La_{0.7}Sr_{0.3}Cu_{0.3}Fe_{0.7}O_3$ perovskite catalysts were prepared by the citrate sol-gel method and their spin conversion characteristics from ortho to para hydrogen were investigated by in-situ FTIR spectroscopy at 17K. It was found that the spin conversion was affected by surface area, particle size, and crystallite size of the catalysts. Thus, the $La_{0.7}Sr_{0.3}Cu_{0.3}Fe_{0.7}O_3$ perovskite catalyst that had higher surface area, higher crystallite size, and smaller particle size than $LaFeO_3$ showed the better spin conversion property of 32.3% at 17K in 120min interaction with the perovskite catalysts.

• Korean Chemical Engineering Research
• /
• v.51 no.6
• /
• pp.677-684
• /
• 2013

A mixed refrigerant cycle (MRC) has been widely used in liquefaction of natural gas because it is simple and easily operable with reasonable equipment costs. One of the important techniques in MRC is selection of a refrigerant mixture and decision of its optimum mixing ratio. In this work, it is examined whether mixture components (refrigerants) and their mixing ratio influence performance of general MRC processes. In doing this, mixture design and response surface method, which are well-known statistical techniques, are used to find optimal mixture refrigerants and their optimal mixing ratio that minimize total energy consumption of the entire liquefaction process. A MRC process using several refrigerants and various mixing ratios is simulated by Aspen HYSYS and mixture design and response surface method are implemented using Minitab. According to the results, methane ($C_1$), ethane ($C_2$), propane ($C_3$) and nitrogen ($N_2$) are selected as best mixture refrigerants and the determined mixture ratio (mole ration) can reduce total energy consumption by up to 50%.

• Tribology and Lubricants
• /
• v.37 no.3
• /
• pp.91-98
• /
• 2021

This paper presents a hydrostatic bearing design and rotordynamic analysis of a turbo expander for a hydrogen liquefaction plant. Th~e turbo expander includes the turbine and compressor wheel assembled to a shaft supported by two hydrostatic radial and thrust bearings. The rated speed is 75,000 rpm and the rated power is 6 kW. For the bearing operation, we use pressurized air at 8.5 bar as the lubricant that is supplied to the bearing through the orifice restrictor. We calculate the bearing stiffness and flow rate for various gauge pressure ratios and select the orifice diameter providing the maximum bearing stiffness. Additionally, we conduct a rotordynamic analysis based on the calculated bearing stiffness and damping considering design parameters of the turbo expander. The predicted Cambell diagram indicates that there are two critical speeds under the rated speed and there exists a sufficient separation margin for the rated speed. In addition, the predicted rotor vibration is under 1 ㎛ at the rated speed. We conduct the operating test of the turbo expander in the test rig. For the operation, we supply pressurized air to the turbine and monitor the shaft vibration during the test. The test results show that there are two critical speeds under the rated speed, and the shaft vibration is controlled under 2.5 ㎛.

• Transactions of the Korean hydrogen and new energy society
• /
• v.34 no.5
• /
• pp.456-464
• /
• 2023

In this study, a compact hydrogen liquefaction system was constructed with the aim of creating a data storage and monitoring program for liquid hydrogen production. This program was designed to receive and record signals from diverse control equipment through the LabVIEW software. A range of measurement instruments were devised to collect data, encompassing variables such as flow rate, pressure, temperature, and liquid level. As a result, it was possible to directly check the production of liquid hydrogen by obtaining various data of condensed liquid hydrogen. In addition, it was confirmed that long-term storage of liquid hydrogen is possible by developing automatic ON/OFF through the LabVIEW program.

• Journal of the Korean Institute of Gas
• /
• v.22 no.4
• /
• pp.63-73
• /
• 2018

Innovative technical process for Energy Storage System (ESS), Liquid Air Energy Storage system (LAES) is mature technologies based on the gas liquefaction process. In spite of many advantages such as high energy density, no geographical constraints, low investment costs and long useful life, the system has not yet widely commercialized due to low round trip efficiency. To improve RTE and acquire high yield of liquid air, various configurations of LAES process have been considered. In this research, dual refrigerants cycle (R-600a and methanol) for air liquefaction and thermal oil circulation for power generation via liquid air gasification have been applied to improve cycle performance significantly using Aspen HYSYS simulator.

• New & Renewable Energy
• /
• v.2 no.2 s.6
• /
• pp.118-125
• /
• 2006

The target of this work was the process development of demonstration plant to produce the high quality alternative fuel oil by the pyrolysis of mixed plastic waste. In the first step of research, the bench-scale units of 70 t/y and the pilot plant of 360 t/y had been developed. Main research contents in this step were the process performance test of pilot plant of 360 ton/year and the development of demonstration plant of 3,000 t/y, which was constructed at Korea R & D Company in Kimjae City. The process performance of pilot plant of 360 t/y showed about 80% yield of liquid product, which was obtained by both light gas oil(LGO) and heavy gas oil(HGO), The boiling point range distribution of LO product that was mainly consisting of olefin components in PONA group appeared at between that of commercial gasoline and kerosene. On the other hand, HO product was mainly paraffin and olefin components and also appeared at upper temperature distribution range than commercial diesel. Gas product showed a high fraction of $C_3\;and\;C_4$ product like LPG composition, but also a high fraction of $CO_2$ and CO by probably a little leak of process.

• Journal of Energy Engineering
• /
• v.5 no.1
• /
• pp.80-86
• /
• 1996

Naphthalene hydrogenation reaction was performed as a model reaction for coal liquefaction. Product distributions of tetralin and decalin are sensitive to reaction temperature and hydrogen pressure. At 380$^{\circ}C$, hydrogenation reaction using sulfided pellet catalysts gives poor reproducibility and several experimental methods are tried to examine its cause. It was inferred that H$_2$S had, most possibly, a great effect on this phenomena and the effect of H$_2$S was systematically investigated at 250$^{\circ}C$. It is possible that the intermediate hydroaromatic compound (tetralin) is maximized by changing the partial pressure of H$_2$S. It was identified that the partial pressure of H$_2$S could be another important factor in addition to the reaction time and temperature in coal liquefaction using sulfided catalysts.