• 한국수소및신에너지학회논문집
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• 제35권1호
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• pp.105-113
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• 2024

The natural gas dehydration process plays a central role in liquefying LNG. This study proposes two natural gas dehydration process systems applicable to liquefied natural gas (LNG) liquefaction plants, and compares and analyzes energy optimization measures through simulation. The fuel gas from feed stream (FFF) case, which requires additional equipment for gas circulation, disadvantages are design capacity and increased energy. On the other hand, the end flash gas (EFG) case has advantages such as low initial investment costs and no need for compressors, but has downsides such as increased power energy and the use of gas with different components. According to the process simulation results, the required energy is 33.22 MW for the FFF case and 32.86 MW for the EFG case, confirming 1.1% energy savings per unit time in the EFG case. Therefore, in terms of design pressure, capacity, device configuration, and required energy, the EFG case is relatively advantageous. However, further research is needed on the impact of changes in the composition of regenerated gas on the liquefaction process and the fuel gas system.

• 한국지반공학회:학술대회논문집
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• 한국지반공학회 2008년도 춘계 학술발표회 초청강연 및 논문집
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• pp.575-586
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• 2008

The main objective of this paper is to develop an improved model for the analysis of liquefaction potential and to predict excess pore pressure (EPP) using the proposed model that can simulate behavior of saturated sand under earthquake loading conditions. The damage concept is adopted for the development of the proposed model. For the development of the model, a general formulation based on experimental results and damage potential using cumulative absolute velocity (CAV) is proposed for a more realistic description of dynamic responses of saturated sand. Undrained dynamic triaxial tests are conducted using earthquake loading conditions. Based on test results, the NCER-NCW function in terms of $w_d$ and CAV is developed. Procedure for the evaluation of EPP and determination of model parameters for the proposed model is presented as well. For the determination of initial liquefaction, the minimum curvature method using the NCS-NCW curve is proposed. It is observed that predicted initial liquefaction using the proposed method agrees well with measured initial liquefaction. From results of additional undrained dynamic triaxial tests, it is seen that predicted EPP generation using the proposed model agrees well with measured results for earthquake loading cases.

• 한국수소및신에너지학회논문집
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• 제34권2호
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• pp.226-233
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• 2023

In this study, we compared the performance of several refrigeration cycles using different refrigerants and utilizing the cold heat of liquefied natural gas (LNG) for the liquefaction of carbon dioxide. The final conditions for the liquefied CO₂ were set to -20℃ and 20 bar. The refrigerants used included R404a, ammonia, propane, and propylene using a vapor recompression refrigeration cycle. For the refrigeration cycle, the CO₂ at room temperature and pressure was compressed in a two-stage compression process with an intermediate cooling stage using a refrigeration unit. To compare with the liquefaction process using refrigeration, we compressed the CO₂ to 8 bar in a single compression stage and cooled it to around -50℃ using the cold heat of the LNG before liquefying it. Results showed that using ammonia as the refrigerant required the least amount of compressor power for the liquefaction process, and the heat transfer area of the evaporator was the smallest when using propylene as the refrigerant. Using the cold heat of LNG instead of refrigeration using R404a resulted in approximately 69% less energy consumption.

• 한국초전도ㆍ저온공학회논문지
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• 제22권3호
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• pp.20-24
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• 2020

The purpose of this analytic study is to design and examine an efficient hydrogen liquefaction cycle by using a pre-cooler. The liquefaction cycle is primarily comprised of a pre-cooler and a refrigerator. The fed hydrogen gas is cooled down from ambient temperature (300 K) to the pre-cooling coolant temperature (either 77 K or 120 K approximately) through the pre-cooler. There are two pre-cooling methods: a single pre-coolant pre-cooler and a cascade pre-cooler which uses two levels of pre-coolants. After heat exchanging with the pre-cooler, the hydrogen gas is further cooled and finally liquefied through the refrigerator. The working fluids of the potential pre-cooling cycle are selected as liquid nitrogen and liquefied natural gas. A commercial software Aspen HYSYS is utilized to perform the numerical simulation of the proposed liquefaction cycle. Efficiency is compared with respect to the various conditions of the heat exchanging part of the pre-cooler. The analysis results show that the cascade method is more efficient, and the heat exchanging part of the pre-coolers should have specific UA ratios to maximize both spatial and energy efficiencies. This paper presents the quantitative performance of the pre-cooler in the hydrogen liquefaction cycle in detail, which shall be useful for designing an energy-efficient liquefaction system.

• 한국수소및신에너지학회논문집
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• 제25권6호
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• pp.609-619
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• 2014

In the present study, the frequency of the undesired accident was estimated for a quantitative risk assessment of a large-scale hydrogen liquefaction plant. As a representative example, the hydrogen liquefaction plant located in Ingolstadt, Germany was chosen. From the analysis of the liquefaction process and operating conditions, it was found that a $LH_2$ storage tank was one of the most dangerous facilities. Based on the accident scenarios, frequencies of possible accidents were quantitatively evaluated by using both fault tree analysis and event tree analysis. The overall expected frequency of the loss containment of hydrogen from the $LH_2$ storage tank was $6.83{\times}10^{-1}$times/yr (once per 1.5 years). It showed that only 0.1% of the hydrogen release from the $LH_2$ storage tank occurred instantaneously. Also, the incident outcome frequencies were calculated by multiplying the expected frequencies with the conditional probabilities resulting from the event tree diagram for hydrogen release. The results showed that most of the incident outcomes were dominated by fire, which was 71.8% of the entire accident outcome. The rest of the accident (about 27.7%) might have no effect to the population.

• Journal of Industrial and Engineering Chemistry
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• 제68권
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• pp.267-273
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• 2018

Hydrothermal liquefaction of Chlorella vulgaris feedstock containing 80% (w/w) water was conducted in a batch reactor as a function of temperature (300, 325 and $350^{\circ}C$) and reaction times (5, 10 and 30 min). The biocrude yield, elemental composition and higher heating value obtained for various reaction conditions helped to predict the optimum conditions for maximizing energy recovery. To optimize the recovery of inorganic nutrients, we further investigated the effect of reaction conditions on the ammonium ($NH_4{^+}$), phosphate ($PO_4{^{3-}}$), nitrate ($NO_3{^-}$) and nitrite ($NO_2{^-}$) concentrations in the aqueous phase. A maximum energy recovery of 78% was obtained at $350^{\circ}C$ and 5 min, with a high energy density of 34.3 MJ/kg and lower contents of oxygen. For the recovery of inorganic nutrients, shorter reaction times achieved higher phosphorus recovery, with maximum recovery being 53% at $350^{\circ}C$ and 5 min. Our results indicate that the reaction condition of $350^{\circ}C$ for 5 min was optimal for maximizing energy recovery with improved quality, at the same time achieving a high phosphorus recovery.

• 한국가스학회지
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• 제15권6호
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• pp.38-43
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• 2011

천연가스 액화공정은 극저온에서 운전되며 에너지 소비가 매우 크기 때문에 압축기의 에너지 소모를 최소화하는 것이 공정의 효율 측면에서 중요하다. 여러 가지 천연가스 액화공정 중 C3-MR(Propane Pre-cooled Mixed Refrigerant) 공정의 경우 순수냉매인 프로판과 혼합냉매를 사용하는 두 개의 냉각 사이클로 구성되어있다. 본 연구에서는 C3-MR 공정에서 최적의 프로판 압력 레벨을 찾기 위해 프로판 사이클을 별개로 구성하여 모사하였다. 또한, 압력 레벨에 따른 조건을 변화시켜가며 사례 연구를 수행하고 이를 통해 압축기에서 소모되는 에너지양을 비교하였다. 그 결과 압력 레벨이 높을수록 총 에너지 소모량이 감소하는 것을 확인 할 수 있었다. 압력 레벨이 3일때 보다 압력 레벨이 5일 때 에너지 소모는 약 23.7% 감소하는 값을 얻을 수 있었다.

• KEPCO Journal on Electric Power and Energy
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• 제2권3호
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• pp.447-452
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• 2016

It is imperative to develop an effective pathway to depolymerize lignin into liquid fuel that can be used as a bioheavy oil. Lignin can be converted into liquid products either by a solvent-free thermal cracking in the absence air, or thermo-chemical degradation in the presence of suitable solvents and chemicals. Here we show that the solvent-assisted liquefaction has produced promising results in the presence of metal-based catalysts. The supercritical ethanol is an efficient liquefaction solvent, which not only provides better solubility to lignin, but also scavenges the intermediate species. The concentrated sulfuric acid hydrolysis lignin (CSAHL) was completely liquefied in the presence of solid catalysts (Ni, Pd and Ru) with no char formation. The effective deoxy-liquefaction nature associated with scEtOH with aid hydrodeoxygenation catalysts, resulted in significant reduction in oxygen-to-carbon (O/C) molar ratio up to 61%. The decrease in oxygen content and increase in carbon and hydrogen contents increased the calorific value bio-oil, with higher heating value (HHV) of $34.6MJ{\cdot}Kg^{-1}$. The overall process is energetically efficient with 129.8% energy recovery (ER) and 70.8% energy efficiency (EE). The GC-TOF/MS analysis of bio-oil shows that the bio-oil mainly consists of monomeric species such as phenols, esters, furans, alcohols, and traces of aliphatic hydrocarbons. The bio-oil produced has better flow properties, low molecular weight, and high aromaticity.

• 한국가스학회지
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• 제17권1호
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• pp.67-72
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• 2013

LNG Value Chain에서 액화플랜트는 고부가가치를 지니며 전체 Cost의 약 35%를 차지한다. 액화플랜트의 핵심기술은 액화공정이며, 여기서 발생하는 대부분의 Cost는 액화공정의 운전에 필요한 에너지 생성과정에서 소비된다. 액화공정의 에너지소비를 줄이기 위한 방법은 액화공정의 핵심공정인 액화사이클의 효율을 높이는 것이다. 세계적으로 널리 이용되고 액화 효율이 높은 LNG 플랜트의 액화공정은 C3MR(프로판과 혼합냉매) 공정이다. C3MR 공정은 프로판 사이클과 혼합냉매 사이클을 이용하여 천연가스를 액화시키는 공정이다. 본 연구에서는 C3MR을 대상공정으로 하여 공정분석과 공정모사를 수행하였다. 이를 통해 C3MR의 공정변수를 알아내었으며 이후 공정최적화를 수행하였다. 본 연구에서 수행한 C3MR의 공정분석, 공정변수, 최적화 결과는 새로운 액화 공정개발에 활용 될 것으로 생각된다.

• 대한기계학회논문집B
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• 제20권5호
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• pp.1591-1602
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• 1996

In operating the underwater engines such as encountered in exploring submarines, the dumping of the exhaust gas out of the engine requires a large portion of the total power, frequently amounting to 25-30% of the power generated. This unfavorable circumstance can be cured by liquefying the exhaust gas and storing it. In the present study, two liquefaction systems were simulated to enhance the overall efficiency; one is a closed cycle diesel engine and the other is a closed cycle LNG engine. The liquefied natural gas (LNG) is chosen as a fuel, not only because its use is economical but also because its cold energy can be utilized within the liquefaction system. Since a mixture of oxygen and carbon dioxide is used as an oxidizer, liquefying carbon dioxide is of major concern in this study. For further improving this system, the intercooling of the compressor is devised. The necessary power consumed for the liquefying system is examined in terms of the related properties such as pressure and temperature of the carbon dioxide vessel as a function of the amount of the exhaust gas which enters the compressor. The present study was successful to show that much gain in the power and reduction of the vessel pressure could be achieved in the case of the closed cycle LNG engine. The compression power of exhaust gas were observed remarkably lower, typically only 6.3% for the closed cycle diesel engine and 3.4% for the closed cycle LNG engine respectively, out of net engine power. For practicality, a design -purpose map of the operating parameters of the liquefaction systems was also presented.