• Title/Summary/Keyword: linear low density polyethylene

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NEAR-INFRARED STUDIES ON STRUCTURE-PROPERTIES RELATIONSHIP IN HIGH DENSITY AND LOW DENSITY POLYETHYLENE

  • Sato, Harumi;Simoyama, Masahiko;Kamiya, Taeko;Amari, Trou;Sasic, Slobodan;Ninomiya, Toshio;Siesler, Heinz-W.;Ozaki, Yukihiro
    • Proceedings of the Korean Society of Near Infrared Spectroscopy Conference
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    • 2001.06a
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    • pp.1281-1281
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    • 2001
  • Near-infrared (NIR) spectra have bean measured for high-density (HDPE), linear low-density (LLDPE), and low-density (LDPE) polyethylene in pellet or thin films. The obtained spectra have been analyzed by conventional spectroscopic analysis methods and chemometrics. By using the second derivative, principal component analysis (PCA), and two-dimensional (2D) correlation analysis, we could separate many overlapped bands in the NIR. It was found that the intensities of some bands are sensitive to density and crystallinity of PE. This may be the first time that such bands in the NIR region have ever been discussed. Correlations of such marker bands among the NIR spectra have also been investigated. This sort of investigation is very important not only for further understanding of vibration spectra of various of PE but also for quality control of PE by vibrational spectroscopy. Figure 1 (a) and (b) shows a NIR reflectance spectrum of one of the LLDPE samples and that of PE, respectively. Figure 2 shows a PC weight loadings plot of factor 1 for a score plot of PCA for the 16 kinds of LLDPE and PE based upon their 51 NIR spectra in the 1100-1900 nm region. The PC loadings plot separates the bands due to the $CH_3$ groups and those arising form the $CH_2$ groups, allowing one to make band assignments. The 2D correlation analysis is also powerful in band enhancement, and the band assignments based upon PCA are in good agreement with those by the 2D correlation analysis.(Figure omitted). We have made a calibration model, which predicts the density of LLDPE by use of partial least square (PLS) regression. From the loadings plot of regression coefficients for the model , we suggest that the band at 1542, 1728, and 1764 nm very sensitive to the changes in density and crystalinity.

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A Study on Thickness and Temperature Dependence of Dielectric Breakdown in Polyethylene (폴리에틸렌의 절연파괴와 그의 온도 및 두께의존성)

  • Kim, Jeom-Sik;Lee, Jong-Bum;Jung, Woo-Kyo;Kim, Mi-Hang;Park, Dae-Hee
    • Proceedings of the KIEE Conference
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    • 1995.07c
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    • pp.1388-1390
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    • 1995
  • The characteristic of dielectric breakdown in solid insulating material dominates the reliability and safety of power equipment and affects directly to its life. In this point of view, the thickness and temperature dependence of dielectric breakdown strength and mechanism of dielectric breakdown in low density polyethylene which has been employed widely as insulating material have been technically reviewed by examinations of thermal property. The dielectric breakdown strength depending on its thickness was measured 2.6[MV/cm] at the thickness of 20[${\mu}m$] and 1.9[MV/cm] at the thickness of 75[${\mu}m$] based on ambient temperature of 30[$^{\circ}C$]. It is shown the temperature dependence that dielectric breakdown strength decreases in linear as the thickness increases. The dielectric breakdown strength depending on temperature was measured 2.6[MV/cm] at the temperature of 30[$^{\circ}C$], 1.6[MV/cm] at 60[$^{\circ}C$] and 1.3[MV/cm] at 90[$^{\circ}C$] based on the thickness of 20[${\mu}m$]. As the ambient temperature increases, the temperature dependence is shown that a very large drop is occurred up to temperature of 60[$^{\circ}C$] and a very small drop is discovered over 60[$^{\circ}C$].

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Effect of Pallet Size Modified Atmosphere Packaging Using Polyamide Film and Linear Low Density Polyethylene Film on the Shelf Life of Strawberries (PA와 LLDPE 필름을 이용한 딸기 저장용 Modified Atmosphere Pallet Packaging 연구)

  • Kim, Jinse;Jung, Hyun Kyung;Nam, So Young;Son, Jae Yong;Park, Seok Ho;Choi, Dong Soo;Kim, Yong Hoon;Lee, Soo Jang;Park, Chun Wan
    • Food Engineering Progress
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    • v.23 no.1
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    • pp.55-61
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    • 2019
  • For the vessel export of strawberries, modified atmosphere package (MAP) using polyamide (PA) film and linear low density polyethylene (LLDPE) film was investigated to extend the shelf life of strawberries. Because the temperature and relative humidity changes of the MAP were lower than the changes of the control, the weight loss of the MAP were lower than that of the control. The low oxygen level and high carbon dioxide level were effective to decrease the fungal decay rate and to increase the hardness of strawberries. The Hunter's color differences before and after storage showed no distinct difference between the MAP and the control. The lightness had a tendency to decrease while the redness increased. There were no significant changes of the soluble solids during the storage. The shelf life of strawberries could be extended to 16 days using the MAP considering the weight loss and the fungal decay rate. Thus, this MAP method using PA film and LLDPE film was effective to extend the shelf life of strawberries.

Dispersions of partially reduced graphene oxide in various organic solvents and polymers

  • Kim, Hye Min;Kim, Seo Gyun;Lee, Heon Sang
    • Carbon letters
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    • v.23
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    • pp.55-62
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    • 2017
  • We report on the dispersion state of partially reduced graphene oxide (PRGO) in organic solvents, namely methyl ethyl ketone, ethyl acetate, methylene chloride, toluene, and xylene, by controlling the carbon to oxygen (C/O) atomic ratio of the PRGOs. A two-phase solvent exchange method is also proposed to transfer PRGO from water to an aprotic solvent, such as methyl ethyl ketone. We achieve relatively good dispersion in aprotic and non-polar solvents by controlling the C/O atomic ratio of the PRGOs and applying the two-phase solvent exchange method. There is an increase in the glass transition temperatures with the dispersion of PRGOs into amorphous polymers, in particular a $4.4^{\circ}C$ increase for poly(methyl methacrylate) and $3.0^{\circ}C$ increase for polycarbonate. Good dispersion of PRGO in a nonpolar polymer, such as linear low density polyethylene, is also obtained.

Properties of PD Pulses Accompanying with Bush-type Tree in LDPE (저밀도 폴리에틸렌에서 부시형 전기트리에 수반되는 부분방전 펄스의 특성)

  • 강성화;박영국;정수현;이광우;임기조
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.11 no.12
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    • pp.1055-1059
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    • 1998
  • The correlation between the propagation of electrical tree and distributions of partial discharge(PD) pulses accompanying with electrical tree of bush type in low density polyethylene were discussed. We measured the growth of electrical tree by using optical microscope and PD data simultaneously. The PD data detected and analyzed were PD magnitude, repetition rate, average discharge power, average phase angle, and $\psi$-q-n distribution pattern. The average discharge power and repetition rate of PD had good linear relation with area of tree. Repetition rate and peak discharge magnitude and width of discharge phase angle increased with the tree.

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Development of Oxo-biodegradable Bio-plastics Film Using Agricultural By-product such as Corn Husk, Soybean Husk, Rice Husk and Wheat Husk (농산부산물인 옥피, 대두피, 왕겨, 소맥피를 이용한 산화생분해 바이오플라스틱 필름 개발)

  • You, Young-Sun;Kim, Mi-Kyung;Park, Myung-Jong;Choi, Sung-Wook
    • Clean Technology
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    • v.20 no.3
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    • pp.205-211
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    • 2014
  • Biomass-based plastics containing the biomass content higher than 25 wt% have been considered as environment-friendly materials due to their effects on the reduction in the $CO_2$ emission and petroleum consumption as well as biodegradability after use. This article described the effect of the additions of oxo-biodegradable additive, 4 kinds of plant biomass, unsaturated fatty acid, citric acid in the properties of polyethylene films. Bio films were prepared using a variety of biomasses and tested for feasibility as a food packaging film. Mechanical properties such as tensile strength and percent elongation at break were evaluated. Husk biomasses from such as corn, soybean, rice, and wheat were pulverized using air classifying mill (ACM) and four different types of packaging films with thickness of $50{\mu}m$ were prepared using the pulverized biomass and low density polyethylene/linear low density polyethylene. The packaging film with wheat husk biomass was found to have greater mechanical properties of elongation and tensile strength than the other samples. Biodegradability of bio film was measured to be 51.5% compared to cellulose.

A Study on the Development of Plastic Floater for Solar Power Plant on a Body of Water (수상 태양광 발전을 위한 플라스틱 부유체 개발에 관한 연구)

  • Jeong, Kwang-Soo;Jung, In Jun;Shin, Dong-Kil
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.21 no.10
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    • pp.283-290
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    • 2020
  • In this study, a floater was developed for a frame-type solar power plant. The floater supports the frame and the solar panels. A finite element analysis was performed to design its shape and thickness, and the floater was manufactured by a rotational molding method using linear low-density polyethylene. It was found that the floater did not cause collapse and it maintained its stiffness even at 4 times the maximum load of 322.7 kgf. To perform a long-term compression test, a weight-type load application device that uses gravity was designed and manufactured. The amount of compressive deformation was measured for 7 days, and a long-term deformation equation was obtained. Even under small loads, continuous deformation was observed. However, the 10-year deformation amount for a constant load of 100 kgf was predicted to be small at about 4.64 mm. As a result, it was found that the developed floater could be used in a solar power plant on a body of water.

Inhibition Effect of Bacillus subtilis on 365 nm UV-LED Irradiation According to Packaging Materials (포장재 조건에 따른 365 nm UV-LED 조사의 Bacillus subtilis 생육 억제 효과)

  • Lee, Da-Hye;Jeong, So-Mi;Xu, Xiaotong;Kim, Koth-Bong-Woo-Ri;Ahn, Dong-Hyun
    • Microbiology and Biotechnology Letters
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    • v.47 no.3
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    • pp.332-336
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    • 2019
  • The use of ultraviolet (UV) spectroscopy for foods is known to have a microbial inhibitory effect. UV-A having a longer wavelength than UV-C can be used for continuous or intermittent UV irradiation of food stored in containers or packages. Because UV-LED can be used effectively at a low price, this study reported the effect of UV-A 365 nm-LED on inhibiting Bacillus subtilis in accordance with the packaging conditions employed in daily use. The packaging materials were linear low-density polyethylene (LLD-PE), nylon/low density polyethylene (LDPE), polystyrene, and glass. When all packaging materials were treated with 365 nm UV-LED, B. subtilis was observed to remain inactive for 30-60 min. Further, compared with the control (-log 5), the survival rate of B. subtilis was -log 2.0-2.5 for nylon/LDPE and -log 2.58-3.61 for LLD-PE. These packaging materials showed an excellent inhibitory effect regardless of their thickness. Typically, a decrease in the viable cell count of more than 3 log indicates a 99.9% bactericidal effect. These results suggest that 365 nm UV-LED permeated the packaging material and inhibited bacterial growth.

Preparation of Semi-Dried Jellyfish and Its Stability during Storage (해파리 반건품의 제조와 저장안정성)

  • 양승택
    • Journal of Life Science
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    • v.12 no.5
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    • pp.535-543
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    • 2002
  • To investigate the possibility of processing semi-dried jellyfish and to examine its keeping quality, the factors such as moisture content, pH, volatile basic nitrogen (VBN), viable cell counts, color value and texture were analyzed. For processing of the semi-dried product, optimum conditions of drying temperature and drying time were $25^{\circ}C$ and 90min, respectively, under 60 $\pm$ 5% of relative humidity and 2 m/sec of air blast speed. The shelf-life of the products, vacuum-packing method in nylon/polyethylene/linear low density polyethylene (0.015/0.045/0.040 mm) laminated film bag was at least 6 weeks during storage at 4$^{\circ}C$, while that of air packaged one was at least 4 weeks. In case of 2$0^{\circ}C$ storage the shelf-life of the products was at least 3 weeks in both air and vacuum packaged ones.

Preparation of Seasoned and Semi-Dried Right-Eyed Flounder and Quality of Its Product during Storage (참가자미 조미 반건조제품의 제조와 저장 중 품질안정성)

  • 양승택
    • Journal of Life Science
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    • v.9 no.1
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    • pp.44-49
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    • 1999
  • A study was conducted to investigate the possibility of processing seasoned and semi-dried right-eyed flounder (Pseudopleuronects herzensteini) and to examine its quality during storage at $\pm$$3^{\circ}C$ by analyzing the factors such as moisture content, pH, volatile basic nitrogen (VBN), viable cell count and peroxide value (POV). For processing of the seasoned and semi-dried product, optimum conditions of drying temperature and drying time were $20^{\circ}C$ and 4 hrs, respectively, under 50$\pm$5$\%$ of relative humidity and 2 m/sec of air blast speed. The shelf-lives of the products by vacuum-packaging method in nylon/polyethylene/linear low density polyethylene (0.015/0.045/0.040 mm) laminated film bag were 35 and 16 days during storage at $-3^{\circ}C$ and $3^{\circ}C$, respectively.

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