• 제목/요약/키워드: lindane

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Photo-Fenton 공정과 UV/$H_2O_2$ 공정을 이용한 Lindane의 분해특성 비교 연구 (A Study on the degradation of Lindane in water by a Photo-Fenton process and a UV/$H_2O_2$ process)

  • 이주현;최혜민;김일규
    • 상하수도학회지
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    • 제24권1호
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    • pp.109-117
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    • 2010
  • In the present study, the degradation characteristics of Lindane by Advanced Oxidation Processes(UV/$H_2O_2$, Photo-Fenton process) were studied. The degradation efficiency of Lindane in aqueous solution was investigated at various initial pH values, Fenton's reagent concentrations and initial concentrations of Lindane. GC-ECD was used to analyze lindane. Lindane has not been degraded without application of AOPs over two hours. But, approximately 5% of lindane was degraded with UV or $H_2O_2$ alone. Lindane with UV/$H_2O_2$ process showed approximately 7% higher removal efficiency than $H_2O_2$ process. In the UV/$H_2O_2$ process, the pH values did not affect the removal efficiency. The optimal mole ratio of $H_2O_2/Fe^{2+}$ for lindane degradation is about 1.0 in Photo-Fenton process. Also, the experimental results showed that lindane removal efficiency increased with the decrease of initial concentration of lindane. Under the same conditions, the order lindane of removal efficiency is as following : Photo-Fenton process > UV/$H_2O_2$ process > $H_2O_2$ process. In addition, intermediate products were identified by GC-MS techniques. Than PCCH(Pentachlorocyclohexene) was identified as a reaction intermediate of the Photo-Fenton process.

Enhanced Biodegradation of Lindane Using Oil-in-Water Bio-Microemulsion Stabilized by Biosurfactant Produced by a New Yeast Strain, Pseudozyma VITJzN01

  • Abdul Salam, Jaseetha;Das, Nilanjana
    • Journal of Microbiology and Biotechnology
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    • 제23권11호
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    • pp.1598-1609
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    • 2013
  • Organochlorine pesticide residues continue to remain as a major environmental threat worldwide. Lindane is an organochlorine pesticide widely used as an acaricide in medicine and agriculture. In the present study, a new lindane-degrading yeast strain, Pseudozyma VITJzN01, was identified as a copious producer of glycolipid biosurfactant. The glycolipid structure and type were elucidated by FTIR, NMR spectroscopy, and GC-MS analysis. The surface activity and stability of the glycolipid was analyzed. The glycolipids, characterized as mannosylerythritol lipids (MELs), exhibited excellent surface active properties and the surface tension of water was reduced to 29 mN/m. The glycolipid was stable over a wide range of pH, temperature, and salinity, showing a very low CMC of 25 mg/l. Bio-microemulsion of olive oil-in-water (O/W) was prepared using the purified biosurfactant without addition of any synthetic cosurfactants, for lindane solubilization and enhanced degradation assay in liquid and soil slurry. The O/W bio-microemulsions enhanced the solubility of lindane up to 40-folds. Degradation of lindane (700 mg/l) by VITJzN01 in liquid medium amended with bio-microemulsions was found to be enhanced by 36% in 2 days, compared with degradation in 12 days in the absence of bio-microemulsions. Lindane-spiked soil slurry incubated with bio-microemulsions also showed 20-40% enhanced degradation compared with the treatment with glycolipids or yeast alone. This is the first report on lindane degradation by Pseudozyma sp., and application of bio-microemulsions for enhanced lindane degradation. MEL-stabilized bio-microemulsions can serve as a potential tool for enhanced remediation of diverse lindane-contaminated environments.

A survey on head lice infestation in Korea (2001) and the therapeutic efficacy of oral trimethoprim/sulfamethoxazole adding to lindane shampoo

  • Sim, Seo-Bo;Lee, In-Yong;Lee, Kyu-Jae;Seo, Jang-Hoon;Im, Kyung-Il;Shin, Myeong-Heon;Yong, Tai-Soon
    • Parasites, Hosts and Diseases
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    • 제41권1호
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    • pp.57-61
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    • 2003
  • Total of 7,495 children including 3,908 boys and 3,587 girls from a kindergarten and 15 primary schools were examined for head lice infestation (HLI). The overall prevalence of HLI in this study was found to be 5.8%. Head lice were much more commonly detected in girls than in boys with prevalence of 11.2% and 0.9%, respectively. Sixty-nine children with HLI were treated with 1% lindane shampoo alone (group 1), and 45 children with HLI were treated with 1% lindane shampoo and oral trimethoprim/sulfamethoxazole (group 2), and follow-up visits were conducted 2 and 4 weeks later, The children who still had HLI 2 weeks after the primary treatment were treated again. At the 2-week follow-up visit, the treatment success rates of groups I and 2 were 76.8% and 80.7%, respectively, and at the 4-week follow-up visit, the rates were 91.3% and 97.8%, respectively. No statistically significant synergistic effect was observed for the combination of a 1% lindane shampoo and oral trimethoprim/sulfamethoxazole.

Effects of Benomyl and Lindane during late pregnancy in the rat

  • Moon, Hyun-Ju;Shin, Jae-Ho;Lee, Sujung;Kang, Il-Hyun;Kim, Tae-Sung;Hoon Bae;Ryu, Seung-Yeoul;Seok, Ji-Hyun;Ahn, Ji-Yeon
    • 한국독성학회:학술대회논문집
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    • 한국독성학회 2002년도 Molecular and Cellular Response to Toxic Substances
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    • pp.165-165
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    • 2002
  • These experiments tested whether exposure to benomyl (BN) or lindane (LD) during late pregnancy affect the development of reproductive tract in adult offspring. Timed pregnant Sprague Dawley rats (N=7∼8/treatment) were gavaged with LD (1, 5, or 10 mg/kg), BN (50, 250, or 500 mg/kg), or com oil on gestation days 15∼19.(omitted)

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휴믹산에 의한 유기 염소계 농약의 수중 용해도 증가에 중금속이 미치는 영향에 관한 연구 (Effect of heavy metal on the solubility enhancement of organochlorine pesticides by humic acids)

  • 조현희;강소영;권효진;박재우
    • 한국토양환경학회지
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    • 제5권3호
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    • pp.55-64
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    • 2001
  • 많은 유기 염소계 농약들은 환경에서 매우 지속적이며, 먹이 사슬을 통해서 중요하게 생물학적으로 농축하는 경향이 있다. 농업에 적용되는 농약은 지표수의 유출이나 지하수의 흐름을 통해서 사실상 수 계로 이동되어지기 때문에 수환경에 특히 많은 영향을 끼치게 된다. 이 논문의 연구 목적은 두 가지 다른 휴믹산에 의한 유기 염소계 농약인 lindane과 dieldrin의 수중 용해도 증가에 중금속인 납 이온이 미치는 영향에 대해 알아보고자 하는 것이다. 또한 유기 염소계 농약이 두 가지 혼합물로 존재할 때 각각의 용해도에 서로의 상호작용에 대해서도 연구해 보고자 하였다. 휴믹산에 의한 lindane의 용해도 증가 정도는 거의 일정하였지만, 이에 비해 휴믹산에 의한 dieldrin의 수중 용해도 증가는 훨씬 증가함을 보여주었다. 또한 수중에 휴믹산과 납이 공존하면 dieldrin의 용해도는 납이 존재하지 않을 때보다 더욱 감소하였다.

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Infestation status of head louse and treatment with lindane shampoo in children of primary school and kindergarten in Chinju-shi, Kyongsangnam-do, Korea

  • Ha, Yong-Chan;Heo, Jung-Min;Kim, Hyung-Joon;Go, Gi-Moon;Lee, Sang-Jeong;Jeong, Song-Hoan;Ahn, Seung-In;Kim, Min-Cheol;Kim, Jeong-Eun;Song, Hyee-Young;Park, Jeong-Woon;Kim, Byung-Sung;Sohn, Woon-Mok
    • Parasites, Hosts and Diseases
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    • 제38권1호
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    • pp.41-43
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    • 2000
  • The infestation status of head louse among children attending primary schools and kindergartens in Chinju-shi, Kyongsangnam-do, Korea, was investigated between June and July 1999. Out of 2,288 children examined, 3.9% of boys (48/1,242) and 23.5% of girls (246/1,046) were infested with nits or adult/nymphs of lice. The effectiveness of lindane shampoo (1% gamma benzene hexachloride solution) was evaluated after one or two time applications to all the children infested. The negative conversion rate of pediculosis was 93.5%. Effective control measures are needed to control and prevent such ectoparasite infestation amongst children.

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신규 잔류성 유기오염물질(Emerging Persistent Organic Pollutants E-POPs) 핵사클로로시클로핵산(HCH)의 대기-토양-물-저질에서의 잔류특성 (Characteristics of Persistent of Hexachlorocyclohexane(HCH) in Ambient Air-Soil-Water-Sediment for a Emerging Persistent Organic Pollutants(POPs))

  • 황성민;이석형;박노진;옥곤
    • 한국환경과학회지
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    • 제19권12호
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    • pp.1343-1354
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    • 2010
  • The purpose of the study was to analyze the persistence of HCH in atmosphere, soil, sediment and water of the western and southern regions of Korea. The samples from the western region were collected from Anmyeon Island, and the samples from the southern region were collected from Kimhae and Busan. The concentration of HCH isomers in atmosphere showed the pattern of $\alpha$-HCH>$\gamma$-HCH>$\beta$-HCH. The regions with high HCH concentration in the atmosphere are the regions that have been highly exposed to HCH used in the past, and the areas that have been influenced by the long range transport. The HCH that persists in the soil, water and sediment evaporates into the atmosphere, showing the characteristics of Air-Surface exchange. When the regional concentration distributions are compared, the concentration of HCH was higher in the atmosphere of a plain and the cities near the plain, than the urban areas. In this study, the ratio of $\alpha/\beta$-HCH was used as an indicator for estimating the source of Technical HCH and Lindane. According to the result, the contribution of Lindane was high in Kimhae plain and Kimhae urban areas. However, in Busan, the contribution of Technical HCH was higher than Lindane. In case of Anmyeon Island, the western region of Korea had high contribution from Tehcnical HCH. In soil and sediment, $\beta$-HCH was dominant. In water, $\gamma$-HCH was dominant among other isomers. Such results are due to $\gamma$-HCH inLindane. Furthermore, the source of $\gamma$-HCH in urban areas is assumed to be the use of medicine, medical supplies and other living supplies. Based on the results of this study, the management of HCH, a newly list up emerging POPs, should be strengthened by further research on sources, fate, persistency, accumulation and exposures and etc. to the risk assessments.

Effects of Benomyl and Lindane during late pregnancy in the rat

  • Moon, Hyun-Ju;Shin, Jae-Ho;Lee, Su-Jung;Kang, Il-Hyun;Kim, Tae-Sung;Bae, Hoon;Ryu, Seung-Yeoul;Seok, Ji-Hyun;Ahn, Ji-Yeon;Jeung, Eui-Bae;Han, Soon-Young
    • 한국환경성돌연변이발암원학회:학술대회논문집
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    • 한국환경성돌연변이발암원학회 2002년도 Molecular and Cellular Response to Toxic Substances
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    • pp.165-165
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    • 2002
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