• Proceedings of the IEEK Conference
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• 2001.06b
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• pp.185-188
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• 2001

In this study, $Al_2$O$_3$films have been deposited with Atomic Layer Deposition(ALD) for gate insulator for MPTMA and $H_2O$ at low temperature below 40$0^{\circ}C$ . Conventional methods of $Al_2$O$_3$thin film deposition have suffered from the poor step coverage due to reduction of device dimension and increasing contact/via hole aspect ratio. ALD is a self-limiting growth process with controlled surface reaction where the growth rate is only dependent on the number of growth cycle and the lattice parameter of materials. ALD growth process has many advantages including accurate thickness control, large area and large batch capability, good uniformity, and pinholes freeness.

• Corrosion Science and Technology
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• v.2 no.1
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• pp.41-46
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• 2003

Flow-Accelerated Corrosion behavior concerning both activation and mass transfer process of SA106 Gr.C steel was studied using rotating cylinder electrode in room temperature alkaline solution by DC and AC electrochemical techniques. Passive film was tanned from pH 9.8 by step oxidation of ferrous product into hydroxyl compound. Corrosion potential shifted slightly upward with rotating velocity through the diffusion of cathodic species. Corrosion current density increased with rotating velocity in pH 6.98, while it soon saturated from 1000 rpm at above pH 9.8. On the other hand the limiting current increased with rotating speed regardless of pH values. It seems that activation process, which represents formation of passive film on the bare metal surface, controls the entire corrosion kinetics

• Journal of the korean Society of Automotive Engineers
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• v.11 no.4
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• pp.35-42
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• 1989

The major purpose of this paper is a study on the effect of die profile radius on the formability of spring-type blankholder system in deep drawing process. By drawing the various materials, formability is studied by means of checking the drawing force, blankholding force variation, limiting drawing ratio and wall wrinkling phenomenon. As the die profile radius increases, the maximum drawing force and maximum blankholding force decrease regardless of lubrication condition. Because better lubrication induces blankholding force to rise, spring type blankholder system is better to protect flange wrinkling phenomenon than constant pressure type. And wall wrinkling phenomenon was not detected in experimental die radius range, so the Miyakawa's upper wrinkling limit is understimated in case of material tested.

• International Journal of Reliability and Applications
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• v.11 no.2
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• pp.69-87
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• 2010

The optimal replacement problem was investigated for a multi-state deteriorated system for which the true internal state cannot be observed directly except when the system breaks down completely. The internal state was assumed to be monitored incompletely by a monitor that gives information related to the true state of the system. The problem was formulated as a partially observable Markov decision process. The optimal procedure was found to be a monotone procedure with respect to stochastic increasing ordering of the state probability vectors under some assumptions. Limiting the optimal procedure to a monotone procedure would greatly reduce the tremendous amount of calculation time required to find the optimal procedure.

• Proceedings of the Korean Vacuum Society Conference
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• 2013.02a
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• pp.274-274
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• 2013

We fabricate encapsulation-layer of OLED panel from organic-inorganic hybrid thin film by atomic layer deposition (ALD) molecular layer deposition (MLD) using Al2O3 as ALD process and Adipoyl Chloride (AC) and 1,4-Butanediamine as MLD process. Ellipsometry was employed to verify self-limiting reaction of MLD. Linear relationship between number of cycle and thickness was obtained. By such investigation, we found that desirable organic thin film fabrication is possible by MLD surface reaction in monolayer scale. Purging was carried out after dosing of each precursor to eliminate physically adsorbed precursor with surface. We also confirmed roughness of the organic thin film by atomic force microscopy (AFM). We deposit AC and 1,4-Butanediamine at $70^{\circ}C$ and investigated surface roughness as a function of increasing thickness of organic thin film. We confirmed precursor's functional group by IR spectrum. We calculated WVTR of organic-inorganic hybrid super-lattice epitaxial layer using Ca test. WVTR indicates super-lattice film can be possibly use as encapsulation in flexible devices.

• Bulletin of the Korean Chemical Society
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• v.30 no.8
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• pp.1805-1810
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• 2009

The adsorptions of trimethygallium (TMG) and arsine (As$H_3$) on H/Si(100)-2x1 surface were theoretically investigated. In the case of TMG adsorption, methane loss reaction, surface methylation, hydrogen loss reaction and ring closing reaction channels were found. The mechanism of As$H_3$ adsorption on the surface was also identified. Among these, the methane loss reaction depositing –Ga(C$H_3)_2$ was found to be the major channel due to its low barrier height and the large exothermicity. The surface methylation reaction is the second most favorable channel. In contrast, arsine turned out to be less reactive on the surface, implying that Arsine surface reaction would be the rate limiting step in the overall ALD process.

• Membrane and Water Treatment
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• v.7 no.1
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• pp.1-10
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• 2016

Ultrafiltration is known to be one of the most commonly applied techniques in water treatment. Membrane fouling is the main limiting factor in terms of process efficiency and restricting it to the manageable degree is crucial. Natural organic matter is often found to be a major foulant in surface waters. Among many known fouling prevention techniques, the membrane chemical cleaning is widely employed. This study focuses on evaluating the cleaning efficiency of polymeric and ceramic membranes with the use of various chemicals. The influence of cleaning agent type and its concentration, membrane material and its MWCO, and cleaning process duration on the recovery of membrane flux was analyzed. Results have shown that, regardless of membrane type and MWCO, the most effective cleaning agent was NaOH.

• Communications for Statistical Applications and Methods
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• v.27 no.2
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• pp.163-175
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• 2020

We consider a wide class of general weakly-dependent processes, called ψ-weak dependence, which unify almost all weak dependence structures of interest found in statistics under natural conditions on process parameters, such as mixing, association, Bernoulli shifts, and Markovian sequences. For detecting the tail behavior of the weakly dependent processes, change point tests are developed by means of cumulative sum (CUSUM) statistics with the empirical distribution functions of sample extremes. The null limiting distribution is established as a Brownian bridge. Its proof is based on the ψ-weak dependence structure and the existence of the phantom distribution function of stationary weakly-dependent processes. A Monte-Carlo study is conducted to see the performance of sizes and powers of the CUSUM tests in GARCH(1, 1) models; in addition, real data applications are given with log-returns of financial data such as the Korean stock price index.

• Bulletin of the Korean Chemical Society
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• v.13 no.4
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• pp.385-388
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• 1992

The transition probabilities for the thermal intramolecular electron transfer and the optical intervalence transfer band for a symmetric mixed-valence Cu(I)-Cu(II) compound were used to extract the PKS parameters $\varepsilon$ = -1.15, ${\lambda}$ = 2.839, and ${\nu}g$- = 923 $cm^{-1}$. These parameters determine the potential energy surfaces and vibronic energy levels. Three pairs of vibrational levels are below the top of the energy barrier in the lower potential surface. The contribution of each vibrational state to the intramolecular electron transfer was calculated. It is shown that the three pairs of vibrational states below the top of the barrier are responsible for most of the electron transfer at 261-306 K. So the intramolecular electron transfer in this system is a tunneling process. The transition probability exhibits the usual high-temperature Arrhenius behavior, but at lower temperature falls off to a temperature-independent value as tunneling from the lowest levels becomes the limiting process.

• Proceedings of the Korean Society for Technology of Plasticity Conference
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• 1999.08a
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• pp.293-300
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• 1999

A mathematical model for the analysis of roll gap phenomena in strip temper rolling process is described. The mechanical peculiarities of temper rolling process, such as high friction value and non-circular contact arc, low reduction and non-negligible entry and exit elastic zones as well as central restricted deformation (preliminary displacement or sticking) zone etc., are all taken into account. The deformation of work rolls is calculated with the influence function method and arbitrary contact arc shape is permitted. The strip deformation is modeled by slab method and the entry and exit elastic deformation zones are included. The restricted deformation zone near the neutral point is also considered. The concept and the calculation method of limiting preliminary displacement are used to determine the length of the central restricted deformation zone. The comparison of the model results with the measured mill data is also made.