• Title/Summary/Keyword: limiting diffusion

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Room Acoustic Properties of Coupled Rooms Connected by an Aperture in the Steady State Condition (정상상태조건에서의 개구부로 연결된 커플룸의 음향 특성)

  • Na, Hae Joong;Lim, Byoung-Duk
    • Transactions of the Korean Society for Noise and Vibration Engineering
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    • v.26 no.3
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    • pp.315-322
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    • 2016
  • Room acoustic properties of coupled rooms connected by an aperture has been analyzed using statistical acoustic model based on the diffused sound field assumption, which has limitation in dealing with the parameters such an room geometries and non uniform absorptivity of the boundary surfaces. In order to overcome these difficulties the acoustic diffusion model has been introduced, by which distribution of the acoustic energy density can be analyzed for various shapes and wall absorptivity. In this study acoustic properties of coupled rooms connected by an aperture(e.g. door) is analyzed using acoustic diffusion equation, which is solved numerically. The mean energy densities of two rooms obtained by the diffusion model are compared with those from the statistical model. The results show good agreement for various coupling aperture sizes and absorption coefficients. For a limiting case when the partition wall is substituted by an aperture and the two rooms eventually forms a single room, results of coupled room analysis using diffusion model show good agreement with those of a single room.

Effect of Anode Gas Channel Height on Gas Diffusion and Cell Performance in a Molten Carbonate Fuel Cell (용융탄산염 연료전지 연료극 기체 유로 높이에 따른 가스 확산 및 단전지 성능 변화 연구)

  • Lee, Jung-Hyun;Kim, Do-Hyung;Kim, Beum-Ju;Kang, Seung-Won;Lim, Hee-Chun
    • Transactions of the Korean hydrogen and new energy society
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    • v.20 no.6
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    • pp.479-484
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    • 2009
  • The effect of anode gas channel height on gas diffusion and cell performance in a 100 $cm^2$ class molten carbonate single cell is investigated. Single cell separators with three different channel height are used. The effect of the gas channel height on the distribution of the reactive gas concentration is evaluated by the two-dimensional concentration diffusion equation. The overpotential caused by concentration drop with different channel height is estimated by the voltage decay related to diffusion of reactants, well known as concentration polarization, using limiting current density. The estimation could have the possibility to identify the reactant mass transfer polarization in the complicate factors of the overall electrodes.

CONCENTRATION CONTOURS IN LATTICE AND GRAIN BOUNDARY DIFFUSION IN A POLYCRYSTALLINE SOLID

  • Kim, Yongsoo;Wonmok Jae;Saied, Usama-El;Donald R. Olander
    • Proceedings of the Korean Nuclear Society Conference
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    • 1995.05a
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    • pp.707-712
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    • 1995
  • Grain boundary diffusion plays significant role in the fission gas release, which is one of the crucial processes dominating nuclear fuel performance. Gaseous fission products such as Xe and Kr generated inside fuel pellet have to diffuse in the lattice and in the grain boundary before they reach open space in the fuel rod. In the mean time, the grains in the fuel pellet grow and shrink according to grain growth kinetics, especially at elevated temperature at which nuclear reactors are operating. Thus the boundary movement ascribed to the grain growth greatly influences the fission gas release rate by lengthening or shortening the lattice diffusion distance, which is the rate limiting step. Sweeping fission gases by the moving boundary contributes to the increment of the fission gas release as well. Lattice and grain boundary diffusion processes in the fission gas release can be studied by 'tracer diffusion' technique, by which grain boundary diffusion can be estimated and used directly for low burn-up fission gas release analysis. However, even for tracer diffusion analysis, taking both the intragranular grain growth and the diffusion processes simultaneously into consideration is not easy. Only a few models accounting for the both processes are available and mostly handle them numerically. Numerical solutions are limited in the practical use. Here in this paper, an approximate analytical solution of the lattice and stationary grain boundary diffusion in a polycrystalline solid is developed for the tracer diffusion techniques. This short closed-form solution is compared to available exact and numerical solutions and turns out to be acceptably accurate. It can be applied to the theoretical modeling and the experimental analysis, especially PIE (post irradiation examination), of low burn up fission. gas release.

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A Understanding of the Temporal Stem

  • Choi, Chan-Young;Han, Seong-Rok;Yee, Gi-Taek;Lee, Chae-Heuck
    • Journal of Korean Neurosurgical Society
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    • v.47 no.5
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    • pp.365-369
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    • 2010
  • Objective : There has been inconsistency about definition of the temporal stem despite of several descriptions demonstrating its microanatomy using fiber dissection and/or diffusion tensor tractography. This study was designed to clarify three dimensional configurations of the temporal stem. Methods : The fronto-temporal regions of several formalin-fixed human cerebral hemispheres were dissected under an operating microscope using the fiber dissection technique. The consecutive coronal cuts of the dissected specimens were made to define the relationships of white matter tracts comprising the temporal stem and the subcortical gray matters (thalamus, caudate nucleus, amygdala) with inferior limiting (circular) sulcus of insula. Results : The inferior limiting sulcus of insula, limen insulae, medial sylvian groove, and caudate nucleus/amygdala were more appropriate anatomical structures than the roof/dorso-lateral wall of the temporal horn and lateral geniculate body which were used to describe previously for delineating the temporal stem. The particular space located inside the line connecting the inferior limiting sulcus of insula, limen insulae, medial sylvian groove/amygdala, and tail of caudate nucleus could be documented. This space included the extreme capsule, uncinate fasciculus, inferior occipito-frontal fasciculus, anterior commissure, ansa peduncularis, and inferior thalamic peduncle including optic radiations, whereas the stria terminalis, cingulum, fimbria, and inferior longitudinal fiber of the temporal lobe were not passing through this space. Also, this continued posteriorly along the caudate nucleus and limiting sulcus of the insula. Conclusion : The temporal stem is white matter fibers passing through a particular space of the temporal lobe located inside the line connecting the inferior limiting sulcus of insula, limen insulae, medial sylvian groove/amygdala, and tail of caudate nucleus. The three dimensional configurations of the temporal stem are expected to give the very useful anatomical and surgical insights in the temporal lobe.

Fabrication of Organic-Inorganic Superlattice Films Toward Potential Use For Gas Diffusion Barrier

  • Yun, Gwan-Hyeok;Muduli, Subas Kumar;Seong, Myeong-Mo
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.08a
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    • pp.394-394
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    • 2012
  • We fabricated organic-inorganic superlattice films using molecular layer deposition (MLD) and atomic layer deposition (ALD). The MLD is a gas phase process in the vacuum like to atomic layer deposition (ALD) and also relies on a self-terminating surface reaction of organic precursor which results in the formation of a monolayer in each sequence. In the MLD process, 'Alucone' is very famous organic thin film fabricated using MLD. Alucone layers were grown by repeated sequential surface reactions of trimethylaluminum and ethylene glycol at substrate temperature of $80^{\circ}C$. In addition, we developed UV-assisted $Al_2O_3$ with gas diffusion barrier property better than typical $Al_2O_3$. The UV light was very effective to obtain defect-free, high quality $Al_2O_3$ thin film which is determined by water vapor transmission rate (WVTR). Ellipsometry analysis showed a self-limiting surface reaction process and linear growth of each organic, inorganic film. Composition of the organic films was confirmed by infrared (IR) spectroscopy. Ultra-violet (UV) spectroscopy was employed to measure transparency of the organic-inorganic superlattice films. WVTR is calculated by Ca test. Organic-inorganic superlattice films using UV-assisted $Al_2O_3$ and alucone have possible use in gas diffusion barrier for OLED.

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Analysis of Insulating Characteristics of Cl2-He Mixture Gases in Gas Discharges

  • Tuan, Do Anh
    • Journal of Electrical Engineering and Technology
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    • v.10 no.4
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    • pp.1734-1737
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    • 2015
  • Insulating characteristics of Cl2-He mixture gases in gas discharges were analysed to evaluate ability of these gases for using in medium voltage and many industries. These are electron transport coefficients, which are the electron drift velocity, density-normalized longitudinal diffusion coefficient, and density-normalized effective ionization coefficient, in Cl2-He mixtures. A two-term approximation of the Boltzmann equation was used to calculate the electron transport coefficients for the first time over a wide range of E/N (ratio of the electric field E to the neutral number density N). The limiting field strength values of E/N, (E/N)lim, for these binary gas mixtures were also derived and compared with those of the pure SF6 gas.

Strain measurement in the interface between crystalline Silicon and amorphous Silicon with MEIS

  • Yongho Ha;Kim, Sehun;Kim, H.K.;D.W. Moon
    • Proceedings of the Korean Vacuum Society Conference
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    • 1999.07a
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    • pp.178-178
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    • 1999
  • Low temperature Si epitaxy can provide flexibility for a device designer to tailor or optimize the device performance. It is better method for controlling the doping thickness, concentration and profile than ion implantation and diffusion. But there is a limited growth thickness in this method. At a given temperature, the film grows epitaxially for a certain limiting thickness(hepi) and becomes amorphous. The transition from crystalline Si to amorphous Si is abrupt. In this study, Si film was deposited by ion beam sputter deposition on Si (0001) above a limiting thickness and measure the strain in the interface between crystalline Si and amorphous Si. The strain was compressive and the maximum value was about 2%.

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A Study on Buoyancy Effects in Double-Diffusive Convecting System (이중확산대류계에서의 부력효과에 관한 연구(Ⅰ)- 실험적 연구 -)

  • Kim, Yang-Hun;Hyun, Myung-Taek;Kim, Min-Chan
    • Journal of Ocean Engineering and Technology
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    • v.13 no.1 s.31
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    • pp.121-129
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    • 1999
  • Double-diffusive convection with verical temperature and concentration gradients in thermally stratified fluids has been investigated experimentally using an electrochemical technique. Cupric sulfuric-sulffuric acid solution confined between two horizontal copper electrodes was used. The change of thermal and solutal buoyance has no influence on the range of voltage for the limiting current. Due to Soret effect, the onset time of natural convection is delayed as the stabilizing thermal buoyancy decreases. Also it is found that the shrinkage of the unstabilizing solutal buoyancy makes the onset of natural convection retard. Multi-layered convective phenomena do not appear because cupric sulfate-sulfuric acid solution is thermally stratified, and heat diffuses faster than cupric sulfate solfate solution.

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Mass Transfer to Amalgamated Copper Rotating Disk Electrode

  • Sulaymon, Abbas H.;Abbar, Ali H.
    • Journal of Electrochemical Science and Technology
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    • v.3 no.4
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    • pp.165-171
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    • 2012
  • An experimental study of mass transfer to an amalgamated copper rotating disc electrode has been employed to determine an empirical correlation for the mass transfer rate in laminar flow. The study was performed in a three-electrodes configuration using 0.1 M boric acid and 0.1M potassium chloride as supporting electrolyte with Zn (II) concentration in the range (25-100 mg $dm^{-3}$). Polarization curves at different zinc ion concentration are reported. Hydrogen and oxygen reduction has also been considered.The diffusion coefficients and mass transfer coefficient were obtained using limiting diffusion current technique based on zinc ion reduction. A least squares analysis indicates that the laminar flow results for 13067 < Re > 57552 and 550 < Sc > 1390 can be correlated by the following equation with correlation coefficient (CR) equal to 0.98: $sh=0.61Re^{0.5}Sc^{1/3}$.

Onset on the Rate Limiting Factors of InP Film Deposition in Horizontal MOCVD Reactor (수평형 MOCVD 반응기 내의 InP 필름성장 제어인자에 대한 영향 평가)

  • Im, Ik-Tae;Sugiyama, Masakazu;Nakano, Yoshiyaki;Shimogaki, Yukihiro
    • Proceedings of the KSME Conference
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    • 2003.11a
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    • pp.73-78
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    • 2003
  • The InP thin films grown by metalorganic chemical vapor deposition (MOCVD) are widely used to optoelectronic devices such as laser diodes, wave-guides and optical modulators. Effects of various parameters controlling film growth rate such as gas-phase reaction rate constant, surface reaction rate constant and mass diffusivity are numerically investigated. Results show that at the upstream region where film growth rate increases with the flow direction, diffusion including thermal diffusion plays an important role. At the downstream region where the growth rate decreases with flow direction, film deposition mechanism is revealed as a mass-transport limited. Mass transport characteristics are also studied using systematic analyses.

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