• Title/Summary/Keyword: limited diffraction

Search Result 117, Processing Time 0.034 seconds

Degradation of Volatile Hydrocarbons Using Continuous-Flow Photocatalytic Systems with Enhanced Catalytic Surface Areas

  • Jo, Wan-Kuen;Yang, Sung-Hoon;Shin, Seung-Ho;Yang, Sung-Bong
    • Environmental Engineering Research
    • /
    • v.16 no.2
    • /
    • pp.91-96
    • /
    • 2011
  • Limited information is available on the degradation of volatile hydrocarbons determined via the use of plate-inserted photocatalytic reactors. This has led to the evaluation of surface areas of cylindrical continuous-flow photocatalytic reactors for the degradation of three selected aromatic hydrocarbons. Three types of reactors were prepared: a double cylinder-type, a single cylindrical-type without plates and a single cylindrical-type with inserted glass tubes. According to diffuse reflectance, FTIR and X-ray diffraction (XRD) spectroscopy, the surface characteristics of a coated photocatalyst were very similar to those of raw $TiO_2$, thereby suggesting that the coated photocatalyst exhibited the same photocatalytic activity as the raw $TiO_2$. The photocatalytic degradation efficiencies were significantly or slightly higher for the single cylinder-type reactor than for the double cylinder-type reactor which had a greater catalytic surface area. However, for all target compounds, the degradation efficiencies increased gradually when the number of plates was increased. Accordingly, it was suggested that the surface area being enhanced for the plate-inserted reactor would elevate the photocatalytic degradation efficiency effectively. In addition, this study confirmed that both initial concentrations of target compounds and flow rates were important parameters for the photocatalytic removal mechanism of these plate-inserted photocatalytic reactors.

DISSIMILAR FRICTION-STIR WELDING OF ALALLOY 1050 AND MGALLOY AZ31

  • Park, Seung Hwan C.;Masato Michiuchi;Yutaka S. Sato;Hiroyuki Kokawa
    • Proceedings of the KWS Conference
    • /
    • 2002.10a
    • /
    • pp.534-538
    • /
    • 2002
  • Dissimilar friction stir welding of aluminum (AI) alloy 1050 and magnesium (Mg) alloy AZ31 was successfully done in the limited welding parameters. The dissimilar weld showed good quality and facility compared to conventional fusion weld. Transverse cross section perpendicular to the welding direction had no defects. The weld was divided into base material of Al alloy, an irregular shaped stir zone and base material of Mg alloy. The irregular shaped stir zone was roughly located around the initial weld center. The weld interface near plate surface shifted from initial weld centerline to the advancing side. Hardness profile of the weld was heterogeneous, and the hardness value of the stir zone was raised to about 150 Hv to 250 Hv. The mixed phase was identified to intermetallic compound $Mg_{17}$Al$_{12}$ using x-ray diffraction method, energy dispersive x-ray spectroscopy (EDX) and electron probe micro analysis (EPMA). The formation of intermetallic compound $Mg_{17}$Al$_{12}$ during FSW causes the remarkable increase in hardness value in the stir zone.one.

  • PDF

Development and Characterization of a 400-W Slab-type Nd:YAG Gain Module

  • Cha, Yong-Ho;Lee, Sungman;Lim, Gwon;Baik, Sung-Hoon;Kwon, Sung-Ok;Cha, Byung-Heon;Lee, Jung-Hwan;Kang, Eung-Cheol
    • Journal of the Optical Society of Korea
    • /
    • v.16 no.1
    • /
    • pp.53-56
    • /
    • 2012
  • We have developed a slab-type Nd:YAG gain module based on the techniques of conduction cooling and end pumping. The Nd:YAG slab is end-capped on both ends by undoped pure YAG and is pumped through the end-caps by stacked arrays of laser diode bars. The slab's surfaces of total internal reflection are in contact on both sides with microchannel cooling blocks which are cooled by water circulation. The power oscillator based on the gain module generates more than 400 W at 1-kW pumping with a slope efficiency of 55%. The small-signal gain of the gain module is 10 in a single zig-zag pass, and the amplified beam shows a near diffraction-limited beam quality.

Viscous Flow Behavior of (90-x)SiO2-xNa2O-10RO (x = 15-40) Glasses with Low Sintering Temperature

  • Lee, Hansol;Park, Hyun-A;Kim, Hyeong-Jun;Chung, Woon Jin
    • Journal of the Korean Ceramic Society
    • /
    • v.56 no.2
    • /
    • pp.167-172
    • /
    • 2019
  • Silicate glasses with varying SiO2 and Na2O contents were prepared and their viscous flow property at the elevated temperature was studied. When the glass powders were packed and sintered at 550℃ to examine their feasibility as a low sintering temperature glass frit, contrary to expectations, glasses with lower SiO2 content than 60 mol% showed no vitrification after sintering. High temperature microscopy revealed the viscous flow change of the silicate glasses with varying temperature and duration time and also indicated that the viscous flow was limited at low SiO2 content. X-ray diffraction (XRD) on the sintered samples and Raman spectroscopy were carried out to shed light on the compositional dependency of viscous flow of silicate glasses.

A study on $YBa_2Cu_3O_x$ thick films by diffusion process for a superconducting fault current limiter (확산법을 이용한 사고전류제한기용 $YBa_2Cu_3O_x$ 후막연구)

  • Cho, Dong-Eon;Yim, Seong-Woo;Choi, Myung-Ho;Han, Byoung-Sung
    • Proceedings of the KIEE Conference
    • /
    • 1998.07d
    • /
    • pp.1516-1518
    • /
    • 1998
  • $YBa_2Cu_3O_x$(Yl23) Superconducting thick films on $Y_2BaCuO_5$(Y211) substrate were Prepared by surface diffusion process between $BaCuO_2$+CuO composite coating powder and a Y2ll substrate. X-ray diffraction shows that the Yl23 layer onto Y2ll substrate is the orthorhombic crystal structure. The specimen heated at $940^{\circ}C$ for 2h showed the maximum $J_c$ fo 500A/$cm^2$. Based on optimal condition, the superconducting fault current limiter(FCL) having a current limiting area 1mm wide and 66mm long was fabricated on Y211 substrate. A typical current limiting waveform was measured. When a voltage of 3V was applied, the fault current with a peak of 15A was limited to about 0.11A.

  • PDF

Characteristics of Acoustic Impulse Response of Submerged Cylindrical Objects as Elements of Target-Scattered Echo (표적신호 시뮬레이션 요소로서 원통형 몰수체의 충격응답의 특성)

  • Kim, Jae-Soo;Seong, Nak-Jin;Lee, Sang-Young;Kim, Kang;Yu, Myong-Jong;Cho, Woon-Hyun
    • The Journal of the Acoustical Society of Korea
    • /
    • v.13 no.2E
    • /
    • pp.5-13
    • /
    • 1994
  • Simulation of the target-scattered echo requires the understanding of scattering mechanism at the highlight points. In this paper, the basic assumption of Highlight Model is reviewed through the analyzed data obtained in the acoustic water tank experiment. The analysis shows that the scattering mechanism involves pulse elongation and frequency shift as elements of target-scattered echo, and that the internal structures affect the temporal response of the target-scattered echo significantly. The band-limited impulse response or Green's function due to the diffraction from highlight points of internal structures is not mere delta function, but acts like a filter, which causes frequency shift and is elongated in time.

  • PDF

The Optical Design of Probe-type Microscope Objective for Intravital Laser Scanning CARS Microendoscopy

  • Rim, Cheon-Seog
    • Journal of the Optical Society of Korea
    • /
    • v.14 no.4
    • /
    • pp.431-437
    • /
    • 2010
  • A stack of gradient-index (GRIN) rod lenses cannot be used for coherent anti-Stokes Raman scattering (CARS) microendoscopy for insertion to internal organs through a surgical keyhole with minimal invasiveness. That's because GRIN lens has large amount of inherent chromatic aberrations in spite of absolutely requiring a common focus for pump and Stokes beam with each frequency of ${\omega}_p$ and ${\omega}_S$. For this endoscopic purpose, we need to develop a long slender probe-type objective, namely probe-type microscope objective (PMO). In this paper, we introduce the structure, the working principle, and the design techniques of PMO which is composed of a probe-type lens module (PLM) and an adaptor lens module (ALM). PLM is first designed for a long slender type and ALM is successively designed by using several design parameters from PLM for eliminating optical discords between scanning unit and PLM. A combined module is optimized again to eliminate some coupling disparities between PLM and ALM for the best PMO. As a result, we can obtain a long slender PMO with perfectly diffraction-limited performance for pump beam of 817 nm and Stokes beam of 1064 nm.

Preparation of $Ba_{1-x}Sr_xTiO_3$thin films by metal by metal-organic chemical vapor deposition and electrical properties. (Preparation of $Ba_{1-x}Sr_xTiO_3$ thin films by metal-organic chemical vapor deposition and electrical properties)

  • Yoon, Jong-Guk;Yoon, Soon-Gil;Lee, Won-Jae;Kim, Ho-Gi
    • Journal of the Korean Vacuum Society
    • /
    • v.5 no.1
    • /
    • pp.62-66
    • /
    • 1996
  • $(Ba_{1-x}Sr_xTiO_3$ (BST) thin films have been grown on Pt-coated MgO by metal -organic chemical vapor deposition. X-ray diffraction results showed that BST films were grown on a Pt/MgO substrate with (100) preferred orientation perpendicular to the surface. The lineawr relationship of P-E curve obtained form hysteresis loop measurement indicated that the BST films had a Curie transitions below room temperature . Films deposited at $900^{\circ}C$ exhibited a smooth and dense microstructure, a dielectric constant of 202, and a dissipation facotr of 0.02 at 100kHz. The leakage current density of the BST films is about $2\times10^{-10} \;A/\textrm{cm}^2$$ at an applied electric field of 0.2 MV/cm. The electrical behavior on the current-voltage characteristics is well explained by the bulk-limited Pool-Frenkel emission.

  • PDF

A New Way to Prepare MoO3/C as Anode of Lithium ion Battery for Enhancing the Electrochemical Performance at Room Temperature

  • Yu, Zhian;Jiang, Hongying;Gu, Dawei;Li, Jishu;Wang, Lei;Shen, Linjiang
    • Journal of Electrochemical Science and Technology
    • /
    • v.7 no.2
    • /
    • pp.170-178
    • /
    • 2016
  • Composited molybdenum oxide and amorphous carbon (MoO3/C) as anode material for lithium ion batteries has been successfully synthesized by calcining polyaniline (PANI) doped with ammonium heptamolybdate tetrahydrate (AMo). The as prepared electrode material was characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR) and field emission scanning electron microscopy (FE-SEM). The electrochemical performance of the anode was investigated by galvanostatic charge/discharge, cyclic voltammetry (CV), and electrochemical impedance spectroscopy (EIS). The MoO3/C shows higher specific capacity, better cyclic performance and rate performance than pristine MoO3 at room temperature. The electrochemical of MoO3/C properties at various temperatures were also investigated. At elevated temperature, MoO3/C exhibited higher specific capacity but suffered rapidly declines. While at low temperature, the electrochemical performance was mainly limited by the low kinetics of lithium ion diffusion and the high charge transfer resistance.

Thermal and Mineralogical Characterization of Ca-Montmorillonite from Gampo Area (감포지역(甘浦地域) Ca-몬모릴로나이트의 열적(熱的) 및 광물학적(鑛物學的) 특성(特性))

  • Moon, Hi-Soo;Choi, Sun Kyung;Kim, Moon Young
    • Economic and Environmental Geology
    • /
    • v.21 no.2
    • /
    • pp.175-184
    • /
    • 1988
  • Ten under 2 micron size fractions of the montmorillonite from Yongdongri area, Gyeongsangbug-Do were studied using X-ray powder diffraction, cation exchange measurement, differential thermal analysis, thermogravimetric analysis, differential thermal scanning calorimetry and chemical analysis. Montmorillonites occurring at same deposit show limited variation in chemical composition whereas in thermal properties they do not. Their dehydroxylation endothermic peaks are "abnormal" type with a small range of variation of peak temperature reflecting tetrahedral substitution of Al for Si. Data from DSC show that divalent-cation saturated montmorillonite has relatively a higher endothermic heat capacity than monovalent-cation saturated montmorillonite, indicating that cations with higher electronegativity hold more water molecules.

  • PDF