• 제목/요약/키워드: limestone, soil

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Stabilization of Metals-contaminated Farmland Soil using Limestone and Steel Refining Slag

  • Lim, Jeong-Muk;You, Youngnam;Kamala-Kannan, Seralathan;Oh, Sae-Gang;Oh, Byung-Taek
    • 한국지하수토양환경학회지:지하수토양환경
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    • 제19권5호
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    • pp.1-8
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    • 2014
  • The metals contamination of farmland soil nearby abandoned metal mine was serious problem in Korea. Stabilization of contaminated soil was reported using various stabilizers. Application of limestone and steel refining slag was reported as effective stabilizers in the stabilization of metals. The batch studies confirmed that the mixture of limestone and steel refining slag was suitable for stabilization of metals in contaminated soil. The limestone and steel refining slag mixture (2 : 1 and 3 : 2) were used in column studies and it was confirmed that the stabilizers effectively stabilized heavy metals in contaminated soil. The pH of the soil was increased with the addition of stabilizers. Total leached concentration of metals from the column study was reduced 44, 17, and 93% in comparison to the control at arsenic, cadmium and copper, respectively. The sequential extraction studies showed that the exchangeable fraction was changed into carbonate bound fraction (Cd and Cu) and Fe-Mn oxide bound fraction (As). Based on the results we confirmed that 2:1 ratio of limestone and steel refining slag effectively stabilizes the heavy metals. The mixed treatment of lime stone with steel refining slag would be an effective and feasible method for controlling metals leaching in contaminated soil.

石灰岩地域 소나무림에서 지렁이 Casts 와 上層土 性質의 比較 (Comparisons of Soil Properties between Earthworm Casts and Top Soil of Red Pine Forests in a Limestone Area)

  • Mun, Hyeong-Tae;Joon-Ho Kim
    • The Korean Journal of Ecology
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    • 제14권1호
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    • pp.113-117
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    • 1991
  • Comparisons of the physico-chemical properties of earthworm(Lumbricus terrestris) soil casts and top soil of red pine forests in a limestone area were carried out. The casts production durign August and September in 1990 amounted to 6∼7t/ha. The particle of top soil and casts ranged 40∼50% and 10∼20% for sand , 25∼30% and 30∼35% for silt, and 20∼25% and 55∼65% clay, respectively. Significant difference in pH value was not observed between casts and top soil. The casts had 1.4times of organic matter, 1.5times of N, 1.8times of available P, 2times of exchangeable K, 1.3times of exchangeable Ca, and 1.6times of exchangeable Mg than the top 10cm of soil did. Earthworms have altered the soil texture and increased nutrient availability through production of the soil casts in this limestone area.

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모암이 토양미생물 다양성에 미치는 영향 (Effects of Parent Rocks on Soil Microbial Diversity)

  • 서장선;권장식;전길형
    • 한국토양비료학회지
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    • 제36권3호
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    • pp.127-133
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    • 2003
  • 토양미생물의 생태적 특성을 평가하기 위해 화강암, 석회암 및 현무암을 모재로 한 12개의 토양통의 미생물적 특성을 조사하였다. 토양미생물상은 토양화학성과 유의한 상관관계를 보였는데, 특히 토양 pH는 형광성 슈도모나스와, 토양 EC는 방선균, 사상균, 중온성 Bacillus 및 호알카리성균과 정의 관계를 보였다. 포자형성균인 Bacillus는 화강암과 현무암에 비해 석회암토양에서 높은 균수를 보였으나, 그람음성균은 모암간에 비슷한 수준을 유지하였다. 화강암유래 토양에서는 Burkholderia, Pseudomonas, Ralstonia가, 석회암토양에서는 Pseudomonas, Burkholderia, Phyllobacterium가, 현무암토양에서는 Burkholderia속이 우점적으로 분포하고 있었다.

특이산성토의 중화처리기법에 따른 생태적 녹화 (The Ecological Vegetation by the Neutralizing Treatment Techniques of the Acid Sulfate Soil)

  • 조성록;김재환
    • 한국환경복원기술학회지
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    • 제22권1호
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    • pp.47-59
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    • 2019
  • This study was composed of four treatments [no treatment, phosphate + limestone layer treatment, phosphate + sodium bicarbonate + cement layer treatment, and phosphate + sodium bicarbonate + limestone layer treatment] for figuring out vegetation effects on the acid drainage slope. Treated acid neutralizing techniques were effective for neutralizing acidity and vegetative growth in order of [first: phosphate + sodium bicarbonate + limestone layer treatment, second: phosphate + sodium bicarbonate+cement layer treatment, third: phosphate + limestone layer treatment and fourth: no treatment] on the acid drainage slope. We found out that sodium bicarbonate treatment was additory effect on neutralizing acidity and increasing vegetaive growth besides phosphate and neutralizing layer treatments. In neutralizing layer treatments, Limestone layer was more effective for vegetation and acidity compared to cement layer treatment. Cement layer showed negative initial vegetative growth probably due to high soil hardness and toxicity in spite of acid neutralizing effect. Concerning plants growth characteristics, The surface coverage rates of herbaceous plants, namely as Lotus corniculatus var. japonicus and Coreopsis drummondii L were high in the phosphate + sodium bicarbonate + limestone layer treatment while Festuca arundinacea was high in the phosphate + sodium bicarbonate + cement layer treatment. We also figured out that soil acidity affected more on root than top vegetative growth.

광산지역 비소오염 경사 농경지 토양의 안정화 및 유실 저감을 위한 석탄광산배수슬러지의 적용성 평가 (Soil Loss Reduction and Stabilization of Arsenic Contaminated Soil in Sloped Farmland using CMDS (Coal Mine Drainage Sludge) under Rainfall Simulation)

  • 고일하;권요셉;정문호;지원현
    • 한국지하수토양환경학회지:지하수토양환경
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    • 제26권6호
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    • pp.18-26
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    • 2021
  • Soil aggregation begins with flocculation of clay particles triggered by interfacial reactions of polyvalent cation such as Ca2+ and Fe3+, and they are also known as important elements to control the mobility of arsenic in soil environment. The objective of this study was to investigate the feasibility of CMDS (coal mine drainage sludge) for soil loss reduction and stabilization of arsenic-contaminated soil in a 37% sloped farmland under rainfall simulation. The amount of soil loss decreased by 43% when CMDS was applied, and this result was not significantly different from the case of limestone application, which yielded 46% decrease of soil loss. However, the relative amount of dispersed clay particles in the sediment CMDS-applied soil was 10% lower than that of limestone-applied soil, suggesting CMDS is more effective than limestone in inducing soil aggregation. The concentrations of bioavailable arsenic in CMDS amended soil decreased by 46%~78%, which was lower than the amount in limestone amended soil. Therefore, CMDS can be used as an effective amendment material to reduce soil loss and stabilize arsenic in sloped farmland areas.

전라남도 장성과 화순에 분포하는 석회암풍화토의 물성 및 전단 특성 (The Physical and Shear Strength Properties of the Weathered Limestone Soils in Changsung and Hwasun Area of Chonnam Province, Korea)

  • 김해경
    • 지질공학
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    • 제13권3호
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    • pp.335-344
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    • 2003
  • 본 연구에서는 전라남도 장성과 화순에 분포하는 석회암풍화토의 물성 및 전단 특성을 연구하였다. 석회암풍화토의 교란시료에 대한 물성 및 전단 특성을 파악하기 위하여 실내 시험이 수행되었다. 연구지역의 석회암풍화토에 대한 물성 및 전단 특성은 다음과 같다 비중(Gs)은 2.78~2.80, 액성한계(LL)는 37~38(%), 소성지수(PI)는 13.7~15.4이며 흙의 분류(USCS)는 CL에 해당된다. 불포화 시료의 직접전단시험 (vd, $1.5t/\textrm{m}^3$)에 의한 강도정수는 점착력(c)이 3.07~4.4 ($t/\textrm{m}^2$) 그리고 내부마찰각($\Phi$)은 $34.8~42.4^{\circ}$의 범위를 보인다. 화강암풍화토 (양, 1997; 문. 1998; 박, 1998)와 비교해 보면, 연구지역의 석회암 풍화토의 물리적 특성은 일반적으로 차이를 보이며, 전단 강도정수 중, 내부마찰각은 대체적으로 유사한 경향을 보이는 것으로 나타났다.

Environmental Factors Affecting the Abundance and Presence of Tree Species in a Tropical Lowland Limestone and Non-limestone Forest in Ben En National Park, Vietnam

  • Nguyen, Thinh Van;Mitlohner, Ralph;Bich, Nguyen Van;Do, Tran Van
    • Journal of Forest and Environmental Science
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    • 제31권3호
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    • pp.177-191
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    • 2015
  • The effect of environmental variables on the presence and abundance of tree species in a tropical lowland undisturbed limestone and non-limestone forest in Ben En National Park, Vietnam was investigated. The relationships between 13 environmental variables and 29 tree species with a DBH ${\geq}10cm$, as well as between six 6 physical variables with 26 species of seedling and sapling communities were assessed by canonical correspondence analysis (CCA). Data concerning all tree species ${\geq}10cm$ DBH were collected from eighteen $400m^2$ sample plots, while the abundance of regeneration (all individuals ${\leq}5cm$ DBH) was counted in fifty $2{\times}20m$ strip-plots. The significance of species-environments correlations were tested by distribution-free Monte Carlo tests. The CCA of the 29 examined tree species and 13 environmental variables indicated that the presence and abundance of the tree species were closely related to topographic factors. We may confirm that soil properties including pH, soil moisture content, and soil textures, were the most crucial factor in tree species composition and their distribution. Several species including Pometia pinnata, Amesiodendron chinense, Gironniera cuspidate, Cinnamomum mairei, and Caryodaphnopsis tonkinensis were not controlled by soil properties and topographic variables. The CCA also indicated that the abundance of regeneration tree species at all sites had positive and significant correlations with soil depth, while the occurrence of several other tree species (such as Koilodepas longifolium and Aglaia dasyclada) was positively correlated with a higher slope and rocky outcrop.

석회석과 제강슬래그를 이용한 오염토양 안정화에 따른 비소 및 중금속의 식물체 전이도 평가 (Assessment on the Transition of Arsenic and Heavy Metal from Soil to Plant according to Stabilization Process using Limestone and Steelmaking Slag)

  • 고일하;이상환;이원석;장윤영
    • 한국지하수토양환경학회지:지하수토양환경
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    • 제18권7호
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    • pp.63-72
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    • 2013
  • This study estimated stabilization efficiency of As and heavy metal contaminated agricultural soil in abandoned mine through pot experiment. Also contaminants uptake of plant (lettuce) was compared as function of amendment (limestone, steelmaking slag and the mixture of these) addition. In soil solution analysis, concentration of contaminants in soil solutions which added limestone or steelmaking slag were lower than that of the mixture. Especially in As analysis, concentration with 5% (wt) addition of steelmaking slag showed the lowest value among those with other amendments. This seems that As stabilization happens through Fe adsorption during precipitation of Fe by pH increasing. Leachability of As in stabilized soil by TCLP was represented similar result with soil solution analysis. However leachability of heavy metals in stabilized soil was similar with that of non-stabilized soil due to dissolution of alkali precipitant by weak acid. Contaminants uptake rate by plant was also lower when limestone or steelmaking slag was used. However this study revealed that concentration of contaminants in soil solution didn't affect to the uptake rate of plant directly. Because lower $R^2$ (coefficient of determination) was represented in linear regression analysis between soil solution and plant.

The Acid Buffer Capacity of a Horizons in Young Residual Entisols in Korea

  • Zhang, Yong-Seon;Sonn, Yeon-Kyu;Lee, Gye-Jun;Han, Kyung-Hwa;Cho, Hee-Rae
    • 한국토양비료학회지
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    • 제46권6호
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    • pp.519-524
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    • 2013
  • pH buffer capacities (pHBC, $cmol_c\;kg^{-1}\;pH^{-1}$) of 6 residual Entisols derived from granite, granite-gneiss, limestone, sandstone, shale, and basalt in Korea were studied. Soil acidity may become a problem if the soil pH is reduced to critical levels when nutrient cycles are unbalanced (especially N, C and S). The relation between the pHBC and the physico-chemical properties of the 6 soils was also studied. In the A horizons of all the soils except Euiseong series developed from sandstone, the contents of clay, organic matter and cation exchange capacity (CEC) were higher than those of C horizon, but bulk density and pH were lower than C horizon. Clay content of Euiseong series decreased with soil depth, which might be caused by the elluviation. The soils developed from granite, granite-gneiss and sandstone have a higher $SiO_2$ content than those developed from basalt and limestone. The contents of $Fe_2O_3$ and MgO were high in the soils from developed from basalt, limestone and shale comparing with the soils from granite, granite-gneiss and sandstone. The soils from basalt and limestone showed higher values of ignition loss than those from the other parent rocks. The pHBC of the soils was ranged from 1.8 to 3.2 $cmol_c\;kg^{-1}\;pH^{-1}$ showing as follows : basalt, limestone > shale, granite-gneiss > granite sandstone.