• 환경위생공학
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• 제9권2호
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• pp.1-7
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• 1994

Rainwater was collected in Seoul area from January 1991 to December 1993 (over 3years) and by the analysis of the chemical components contained in rainwater, investigated the components that effect on rainwater pH Through the above studies the following conclusions were obtained. 1) Method for Averaging pH Volume weighted method is considered to be acceptable providing that precipitation is measured at the same time when the samples are taken, without precipitation data a simple averaging method should be the next choice. 2) Annual average rainwater pH was 4.98 in 1991, 4.80 in 1992, 4.67 in 1993, measurement range was 3.6-8.1. 3) In the relationship between rainwater pH and rainfall amounts rainwater pH for light rain(<15mm rainfall) was existent in the wide range(pH 4-7), but for heavy rain was corresponded to the annual average values. 4) Annual frequency of pH was Birrndat the frequency($\gamma $) between the density of the [$H^{+}$] and pH in the rainwater(over 3years ), $NO_{3}^{-}$ was excellent and the obtained results was 0.62 in 1992. Also In the correlation coefficient($\gamma $) according to the pH range $SO_{4}^{2-}, NO_{3}^{-}$, were 0.85 ,0.68 at 3.6 $Cl^-$ was 0.99(1993). At 4.1$NO_{3}^{-}(\gamma=0.48)$ in 1992, SO_4^{2-}($\gamma$=0.54), $NO_{3}^{-}(\gamma$=0.72), $Cl^- (\gamma$=0.49) in 1993. 6) pH values gradually increased with increase in $Ca^{2+}/SO_{4}^{2-}$.

• 한국결정성장학회지
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• 제27권1호
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• pp.18-21
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• 2017

본 연구에서는 homogeneous precipitation method를 통하여 구형의 단분산(monodispersed) YAG : $Ce^{3+}$를 합성했다. 단분산 YAG : $Ce^{3+}$의 전구체를 합성하는 과정에서 aluminum ion들이 먼저 석출되어 aluminum 화합물을 형성하고 후에 yttrium 화합물들이 aluminum 화합물들의 표면에서 석출된다. 합성된 전구체를 파우더형태로 얻기 위해 건조과정을 거치는데, oven에서 건조했을 때 보다 동결건조기에서 건조했을 때 비교적 구형의 단분산 YAG : $Ce^{3+}$ 입자를 얻을 수 있었다. 하소 과정에서 공정을 진행하는 온도로서 $1100^{\circ}C$와 $1200^{\circ}C$를 비교해 보았다. 실험 결과 $1200^{\circ}C$의 온도로 상압에서 6시간 동안의 하소 과정을 진행하였을 때 400~500 nm 입자크기를 가진 단분산된 구형의 나노 YAG : $Ce^{3+}$ 입자가 합성되었다.

• 원예과학기술지
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• 제17권4호
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• pp.494-496
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• 1999

새우난초의 자생지 생태환경은 낙엽활엽수림대로 비자생지보다 여름철 기온이 낮고 강수량이 많았으며, 상태습도가 연중 75~90%로 고른 분포를 보였다. 새우난초의 자생분포에 가장 중요한 영향을 끼치는 환경요인은 광(光)이었는데, 낙엽이 지기 전까지는 수관에 의해 강한 광선이 차단되었고, 자생지의 온도가 낮아졌으며, 광도가 400~1,500lux에서 가장 많은 분포를 보였다. 낙엽이 진 겨울철에는 30,000~50,000lux의 광이 유입되어 자생지의 온도를 높여 새우난초의 월동이 가능하였다. 새우난초는 낙엽활엽수림대에 자생하여 여름철에는 강한 광선의 차단효과를 얻었고, 겨울철에는 광선의 유입을 도모하고 낙엽으로 인한 피복으로 보온효과를 얻은 것으로 사료되었다.

• Bulletin of the Korean Chemical Society
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• 제35권3호
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• pp.913-918
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• 2014

Five mol % tungsten-doped tin oxide ($W_{0.05}Sn_{0.95}O_2$, TTO5) was prepared by co-precipitation of $SnCl_4{\cdot}5H_2O$ and $WCl_4$, followed by calcination at $1000^{\circ}C$. The as-prepared TTO5 was in the pure cassiterite phase with a particle size of ~50 nm and optical bandgap of 2.51 eV. Herein it was applied for the formation of TTO5/$TiO_2$ heterojunctions by covering the TTO5 surface with $TiO_2$ by sol-gel method. Under visible-light irradiation (${\lambda}{\geq}420$ nm), TTO5/$TiO_2$ showed a significantly high photocatalytic activity in removing gaseous 2-propanol (IP) and evolving $CO_2$. It is deduced that its high visible-light activity is caused by inter-semiconductor holetransfer between the valence band (VB) of TTO5 and $TiO_2$, since the TTO5 nanoparticle (NP) exhibits the absorption edge at ~450 nm and its VB level is located more positive side than that of $TiO_2$. The evidence for the hole-transport mechanism between TTO5 and $TiO_2$ was also investigated by monitoring the holescavenging reaction with 1,4-terephthalic acid (TA).

• 대기
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• 제21권3호
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• pp.301-309
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• 2011

In this study, we compared light-absorption properties of aerosols observed in East and South Asia from black carbon (BC) mass concentration, aerosol scattering (${\sigma}_s$) and absorption (${\sigma}_a$) coefficients measurements at four sites: Korea Climate Observatory-Gosan (KCO-G), Korea Climate Observatory-Anmyeon (KCO-A), Maldives Climate Observatory-Hanimaadhoo (MCO-H) and Nepal Climate Observatory-Pyramid (NCO-P). No significant seasonal variations of BC mass concentration, ${\sigma}_s$ and ${\sigma}_a$, despite of wet removal of aerosols by precipitation in summer, were observed in East Asia, whereas dramatic changes of light-absorbing aerosol properties were observed in South Asia between dry and wet monsoon periods. Although BC mass concentration in East Asia is generally higher than that observed in South Asia, BC mass concentration at MCO-H during winter dry monsoon is similar to that of East Asia. The observed solar absorption efficiency (${\alpha}$) at 550 nm, where ${\alpha}={\sigma}_a/({\sigma}_s+{\sigma}_a)$, at KCO-G and KCO-A is higher than that in MCO-H due to large portions of BC emission from fossil fuel combustion. Interestingly, ${\alpha}$ at NCO-P is 0.14, which is two times great than that in MCO-H and is about 40% higher than that in East Asia, though BC mass concentration at NCO-P is the lowest among four sites. Consistently, the highest elemental carbon to sulphate ratio is found at NCO-P.

• Korean Journal of Chemical Engineering
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• 제35권12호
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• pp.2442-2451
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• 2018

Novel highly active visible-light photocatalysts in the form of zinc bismuth oxide ($ZnBi_2O_4$) and graphite hybrid composites were prepared by coupling via a co-precipitation method followed by calcination at $450^{\circ}C$. The asprepared $ZnBi_2O_4$-graphite hybrid composites were tested for the degradation of rhodamine B (RhB) solutions under visible-light irradiation. The existence of strong electronic coupling between the two components within the $ZnBi_2O_4$-graphite heterostructure suppressed the photogenerated recombination of electrons and holes to a remarkable extent. The prepared composite exhibited excellent photocatalytic activity, leading to more than 93% of RhB degradation at an initial concentration of $50mg{\cdot}L^{-1}$ with 1.0 g catalyst per liter in 150 min. The excellent visible-light photocatalytic mineralization of $ZnBi_2O_4-1.0graphite$ in comparison with pristine $ZnBi_2O_4$ could be attributed to synergetic effects, charge transfer between $ZnBi_2O_4$ and graphite, and the separation efficiency of the photogenerated electrons and holes. The photo-induced $h^+$ and the superoxide anion were the major active species responsible for the photodegradation process. The results demonstrate the feasibility of $ZnBi_2O_4-1.0graphite$ as a potential heterogeneous photocatalyst for environmental remediation.

• 대한화학회지
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• 제54권1호
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• pp.120-124
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• 2010

용액침전법에 의해 $TiO_2$ 및 $TiO_{2-x}N_x$를 제조하였다. $TiO_{2-x}N_x$ 시료는 순수한 $TiO_2$의 띠 간격인 3.20 eV (390 nm 흡광)로부터 1.77 eV (700 nm 흡광)까지 띠 간격이 줄어들게 되어 자외선 영역 뿐 아니라 가시광선 전체 영역에서도 흡광이 발생하였다. 가시광선에서의 광촉매 활성에서도 $TiO_{2-x}N_x$ 시료는 순수한 $TiO_2$ 및 P-25보다도 더 높은 활성도를 나타냈다.

• 대한화장품학회:학술대회논문집
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• 대한화장품학회 2003년도 IFSCC Conference Proceeding Book II
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• pp.319-329
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• 2003

Ursolic acid (UA) and oleanolic acid (OA) are pentacyclic triterpenoids which are widely distributed in plants, and their derivatives are aglycones of many naturally occurring saponins. It is known that pentacyclic acids may possibly enhance the mechanical barrier functions of cell membranes in plants. Recently, it has been reported that OA and UA have interesting biological activities on skin, such as anti-inflammatory and anti-wrinkle activities. Since triterpenoids are extremely insoluble and their solubility problem limits skin-care application, OA and UA were encapsulated in liposomes via micelle-to-vesicle transition to overcome poorly soluble property and enhance biological efficacy. Optimal molar ratio of OA to lecithin was found to exist for producing liposomes of small hydrodynamic size and liposomal suspensions without recrystallized precipitation of OA. From electron micrograph and dynamic light scattering studies, reconstituted OA-containing liposomes without severe mechanical treatment showed small hydrodynamic size about 150 nm. Wide-angle X-ray diffraction coupled with dynamic light scattering revealed that optimal amount of OA in liposome was 25.4 mole %. In biological evaluation, OA-containing liposome significantly increased filaggrin and transglutaminase as markers of keratinocyte differentiation in epidermal layer of hairless mouse, whereas ursolic acid-containing liposome did not show noticeable increase of filaggrin and transglutaminase compared to empty liposome. It is concluded that nano-scaled liposomes containing triterpenoids were spontaneously prepared by vesicular transition from mixed micelle and liposomal triterpenoids can enhance skin absorption of triterpenoid and biological efficacy.

• 방사선산업학회지
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• 제17권4호
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• pp.551-557
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• 2023

In recent years, radiation has become a socially important issue, increasing the need for accurate prediction of radiation levels. In this study, machine learning-based models such as Multiple Linear Regression (MLR), Random Forest (RF), XGBoost, and LightGBM, which predict the dose rate by time(nSv h^-1) by selecting only important variables, were used, and the correlation between temperature, humidity, cumulative precipitation, wind direction, wind speed, local air pressure, sea pressure, solar radiation, and radiation dose rate (nSv h^-1) was analyzed by collecting weather data and radiation dose rate for about 6 months in Jangseong, Jeollanam-do. As a result of the evaluation based on the RMSE (Root Mean Squared Error) and R-Squared (R-Squared coefficient of determination) scores, the RMSE of the XGBoost model was 22.92 and the R-Squared was 0.73, showing the best performance among the models used. As a result of optimizing hyperparameters of all models using the GridSearch method and comparing them by adding variables inside the measuring instrument, it was confirmed that the performance improved to 2.39 for RMSE and 0.99 for R-Squared in both XGBoost and LightGBM.

• 환경생물
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• 제34권1호
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• pp.30-36
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• 2016

이 연구는 한국 중부지방 용인과 남부지방 무안에서 봄 출현 나방의 다양성 양상과 나방 종 및 개체수에 영향을 주는 기후 요인을 알아보기 위해서 이루어졌다. 나방은 2013년부터 2015년까지 4월 한 달 동안 일주일 간격으로 자외선등 트랩을 이용하여 채집하였다. 기후요인은 $8^{\circ}C$를 기본으로 한 적산온도 (GDD8), 평균온도, 강우량, 일조시간, 풍속, 신적설 등이다. 나방 종 수 및 개체수에 영향을 주는 기후요인은 단기 (채집주부터 3주전까지)와 장기 (채집 4~12주전)로 나누어 분석하였다. 봄 출현 나방은 과 구성에서 유사한 양상을 띠었지만 지역별로 우점한 과는 차이를 나타내었다. 자나방과는 중부지방에서 우점한 반면 밤나방과는 남부지방에서 우점하였다. 밤나방과의 우점종은 4월 초에 나타난 반면 자나방과의 우점종은 4월 말에 나타나 시간적인 차이도 나타내었다. GDD8, 일조시간, 채집 일주일 전 강우량 등 3개의 단기 기후요인은 나방 종 수 및 개체수에 영향을 준 요인으로 나타난 반면 채집 4주전 평균기온만 장기 기후요인으로 나방 종 수에 영향을 준 것으로 나타났다. 이 연구에서는 한국에서 봄 출현 나방으로 자나방과와 밤나방과 종이 우점하며 이들은 4월 중 우점도와 비행시기에 차이가 있는 것도 알 수 있었다. 봄 출현 나방은 따뜻함과 강우량에 영향을 받는 것으로 나타났다. 최근 기후변화는 봄 출현 나방에도 영향을 줄 수 있어 이에 대한 지속적인 감시가 필요할 것으로 생각한다.