• Journal of the Korean Society of Environmental Restoration Technology
• /
• v.5 no.6
• /
• pp.24-29
• /
• 2002

Nitrate removal rate in three cattail wetland cells was investigated. They were a part of a pond-wetland system for stream water treatment demonstration. The system was composed of two ponds and six wetland cells. The acreage of each cell was approximately $150m^2$. The earth works for the system were finished from April 2000 to May 2000 and cattails were planted in the three cells in June 2000. Waters of Sinyang Stream flowing into Kohung Estuarine Lake were pumped into a primary pond, whose effluent was discharged into a secondary pond. The reservoir was formed by a tidal marsh reclamation project and located in southern coastal area of Korean Peninsula. Effluents from the secondary pond were funneled into the three cells. Volumes and water quality of inflow and outflow were analyzed from July 2000 through January 2001. Inflow and outflow averaged $20.2m^3/day$ and $19.8m^3/day$, respectively. Hydraulic retention time was about 1.6 days. Average influent and effluent nitrate concentration was $1.98mg/{\ell}$, $1.38mg/{\ell}$, respectively. Nitrate removal rate averaged $82.6mg\;m^{-2}\;day^{-1}$. Seasonal changes of nitrate retention rates were closely related to those of wetland cell temperatures. The average nitrate removal rate in the cells was a little lower, compared with that of $125.0mg\;m^{-2}\;day^{-1}$ for the wetlands operating in North America. This could be attributed to the initial stage of the cells and inclusion of three cold months into the seven-month study period. Root rhizosphere in wetland soils and litter-soil layers on cell bottoms could not developed. Increase of standing density of cattails within a few years will establish both root zones suitable for the nitrification of ammonia to nitrates and substrates beneficial to the denitrification of nitrates into nitrogen gases, which may lead to increase of the nitrate retention rate.

• Plant Resources
• /
• v.1 no.1
• /
• pp.53-59
• /
• 1998

Laboratory experiments for the removal efficiency of heavy metals in land application of sludge, the accumulation and translocation of heavy metals in x plants after transplanting, and the responses of Minari growth with different ratio of land application of sludge were conducted to determine the potential ability of bioremediation with Minari plants. The removal rate and translocation of copper. zinc. lead. and cadmium in soil and plants were compared after transplanting the Minari plants to soil treated with different ratio of sludge. The removal efficiency of heavy metals in soil incorporated with sludge was different with application ratio, but increased with growing periods of Minari plants. The removal efficiency of Cu, Zn, Pb, and Cd ranged from 67 to 74% from 51% to 63%, from 37% to 71%. and from 15% to 25% after 45 days of transplanting. respectively. The amount removed the copper value. 65.9 mg/kg, observed to be highest in soil incorporated 3% sludge after 45 days. The translocation of Cu. Zn. Pb. and Cd from shoots to roots ranged from 18 to 53%, from 17 to 32%, from 14 to 49%, and from 23 to 38% over growing periods. respectively. In plant responses it appeared to be inhibited the plant growth in the treatment compared with the control at early stage of growth. However, the fresh weights of Minari plant increased from 12.5 to 62.5% in the sludge application after 45 days relative to the control. Therefore the Minari might play a useful role in bioremediation of Cu, Zn, Pb, and Cd in the land application of sludge.

• Journal of Korean Society on Water Environment
• /
• v.38 no.2
• /
• pp.82-94
• /
• 2022

In this study, chemically modified biochar (NSBP500, KSBP500, OSBP500) derived from starfish was utilized to improve the adsorption ability of the SBP500 (Starfish Biochar Pyrolyzed at 500℃) in a solution contaminated with heavy metals. According to the biochar modification performance evaluation batch tests, the removal rate and adsorption amount of NSBP500 increased 1.4 times for Cu, 1.5 times for Cd, and 1.2 times for Zn as compared to the control sample SBP500. In addition, the removal rate and adsorption amount of KSBP500 increased 2 times for Cu, 1.8 times for Cd, and 1.2 times for Zn. The removal rate and adsorption amount of OSBP500 increased 5.8 times for Cu. The FT-IR analysis confirmed the changes in the generation and movement of new functional groups after adsorption. SEM analysis confirmed Cu in KSBP500 was in the form of Cu(OH)₂ and resembled the structure of nanowires. The Cd in KSBP500 was densely covered in cubic form of Cd(OH)₂. Lead(Pb) was in the form of Pb₃(OH)₂(CO₃)₂ in a hexagonal atomic layer structure in NSBP500. In addition, it was observed that Zn was randomly covered with Zn₅(CO₃)₂(OH)₆ pieces which resembled plates in KSBP500. Therefore, this study confirmed that biochar removal efficiency was improved through a chemical modification treatment. Accordingly, adsorption and precipitation were found to be the complex mechanisms behind the improved removal efficiency in the biochar. This was accomplished by electrostatic interactions between the biochar and heavy metals and ion exchange with Ca²⁺.

• Journal of The Korean Society of Agricultural Engineers
• /
• v.62 no.5
• /
• pp.39-46
• /
• 2020

This study evaluated the nitrogen oxide (NO_x) removal efficiency by air purification concrete blocks with titanium dioxide (TiO₂). The concrete in the mixtures had a 30% water:cement ratio, to which TiO₂ was added at 0%, 5%, and 10% of cement weight. The compressive strength reduction rate and removal efficiency of NO_x were investigated. The result of the compressive strength test in the study indicated that addition rate of TiO₂ did not lead to signifcant effect. In terms of the average removal efficiency of NO_x, mix No. 1 using a TiO₂ mixing ratio of 0% had a removal efficiency of 0.57% on average; thus, the removal effect w as not significant. For the other samples prepared by mixing, the average removal efficiencies for mix No. 2 (5% TiO₂) were 58.86% and 62.05% for normal and washing surface treatments, respectively, and those of sample No. 3 (10% TiO₂) were 59.94% and 67.61%. mixs No. 4 (5%) and No. 5 (10%), in which TiO₂ diluted with distilled water was sprayed onto the block surface, had an average NO_x removal efficiency of 61.72% and 68.48%, respectively. In terms of NOx removal efficiency, Mixs No. 3 and No. 5 with 10% TiO₂ were better than Mixs No. 2 and No. 4 with 5% TiO₂. In addition, analyzing the NO_x removal efficiency results from the fixing method, it was capable to apply mixing (washing) and the diluted spray methods. Therefore, it was found that the diluted spray method applied in this study can be employed in any manufacture of air purification concrete blocks.

• Journal of environmental and Sanitary engineering
• /
• v.22 no.4
• /
• pp.1-9
• /
• 2007

A wastewater treatment plant, operating process is physico-chemical/biological activated sludge attached sand filtration, was selected to evaluate effluent quality and pollutants removal efficiencies consideration for deriving the technology-based effluent limitation for petroleum refining industry discharge. The results of influent and effluent analysis were as follows: Average effluent quality were 0.076mg/l of copper, 0.084mg/l of lead, 0.036mg/l of zinc, 0.005mg/l of nickel and 0.004mg/l of cadmium, and the range of coefficient of reliability from 0.007 of copper to 1.0 of lead. Also, 95% of reliability, 0.112, 0.15, 0.063, 0.015 and 0.009mg/l, respectively, were remarkably lower than their effluent limitations. And to reach 95% reliability of effluent limitation at cleanness area, designed effluent quality of copper, lead, zinc and cadmium should be 0.268, 0.099, 0.526 and 0.008mg/l, respectively.

• Journal of the Korean Association of Oral and Maxillofacial Surgeons
• /
• v.26 no.2
• /
• pp.224-227
• /
• 2000

Gunshot wounds to the face are often dramatic at the time of presentation. Although care must be individualized, protocol approach helps the clinician rapidly evaluate patient and plan treatment. Early X-ray films help to determine the precise trajectory. Rapid neurologic assessment and early CT scanning based on physical examination ot trajectory will allow for identification of even occult injuries early. Lead poisoning arising from bullet lead in the synovial cavity of the hip, synovial cavity of the chest and pleural space have been reported. A combination of surgical debridement and chelation therapy with oral succimer produce a satisfactory outcome. We have managed a patient with Lt facial gunshot wound and Lt mandible angle fracture by open reduction of angle fracture and surgical removal of remnant bullet and medially advanced cheek skin flap. We have obtained good result and report this case with review of literatures.

• Proceedings of the Korean Vacuum Society Conference
• /
• 2014.02a
• /
• pp.189.1-189.1
• /
• 2014

Lead zirconium titanate (PZT) is usually used as bulk and thin films. Due to high flexibility and piezoelectric, ferroelectric and pyroelectric properties, PZT fiber has attracted in a variety of fields such as sensor devices, non-electromechanical systems and non-volatile ferroelectric memory devices. And PZT fiber can be numerously synthesized and almost with the diameter of PZT fiber thicker than $10{\mu}m$. However, the electrospinnig method is cost effective and convenient. PZT obtained by electrospinning methodhas the diameter from sub-micro to nanometer. In this paper, the PZT/PVP nanofibers were synthesized with three precursors, lead nitrate, zirconium ethoxide and titanium isopropoxide. And the PZT nanofibers were fabricated after removal of PVP by annealing process at various temperature. The obtained PZT nanofibers were characterized by means of X-ray photoelectron spectroscopy (XPS) for chemical properties, X-ray diffraction (XRD) for crystallinity and phase, scanning electron microscopy (SEM) for morphologies. The diameter of PZT nanofibers were measured with SEM. From the SEM images, we confirmed that diameter of PZT nanofibers was hundreds of nanometers and decreased with increasing the annealing temperature. When the annealing temperature increased, the crystallinity of PZT nanofibers changed from pyrochlore to perovskite structure.

• Carbon letters
• /
• v.15 no.1
• /
• pp.57-66
• /
• 2014

Three activated carbons (ACs) were prepared using NaOH (N) as an activating agent. Hydrofluoric acid pre-leached rice husk was used as a precursor. After leaching, the precursor was washed with distilled water, dried, crushed, and then sieved; a size fraction of 0.3-0.5 mm was selected for carbonization in the absence of air at $600^{\circ}C$. The carbonization product (LC) was mixed with NaOH at ratios of 1:2, 1:3, and 1:4 (wt of LC: wt of NaOH) and the produced ACs after activation at $800^{\circ}C$ were designated NLC21, NLC31, and NLC41, respectively. Surface and textural properties were determined using nitrogen adsorption at $-196^{\circ}C$, scanning electron microscopy images, thermogravimetric analysis, and Fourier transform infrared spectra. These ACs were used as adsorbents for lead(II) from aqueous solutions. The effects of the textural properties and the chemistry of the carbon surfaces were investigated and the impact of the operation conditions on the capacity for lead(II) sorption was also considered. Modification of NLC41 with $H_2O_2$ and $HNO_3$ gave two other adsorbents, $H_{NLC41}$ and $N_{NLC41}$ respectively. These two new samples exhibited the highest removal capacities for lead(II), i.e.117.5 and 128.2 mg/g, respectively. The adsorption data fitted the Langmuir isotherm and the kinetic adsorption followed pseudo-second order kinetics. The thermodynamic parameters have been determined and they indicated a spontaneous endothermic process.

• Proceedings of the Korean Fiber Society Conference
• /
• 2003.04a
• /
• pp.13-16
• /
• 2003

Vinyl acetate monomer can be polymerized through bulk, solution, emulsion, and suspension polymerization processes. However, in the preparation of PVA from bulk or solution polymerization, there are several technical limitations for obtaining high yield and high molecular weight simultaneously. Thus, the improvement of polymerization method is necessary to prepare the PVA with high yield and high molecular weight because that the difficulty in control of high viscosity and in removal of the heat of polymerization, which might lead to side reactions like branching. (omitted)

• Journal of Korean Neurosurgical Society
• /
• v.29 no.7
• /
• pp.959-962
• /
• 2000

Gliosarcoma is a rare malignant tumor of the central nervous system consist of gliomatous and sarcomatous elements. The authors report a case of gliosarcoma in the right frontal lobe. Sharp demarcation of the tumor from surrounding tissue and its superficial location may lead to complete removal and prolonged survival despite high malignancy.