Journal of Korean Society on Water Environment (한국물환경학회지)

Korean Society on Water Environment (한국물환경학회)
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Surface Analysis and Heavy Metal Adsorption Evaluation of Chemically Modified Biochar Derived from Starfish (Asterina pectinifera)

화학적 개질을 통한 별 불가사리 바이오차 표면 분석 및 중금속 흡착 효율 평가

  • Jang, Ha Rin (Department of Environmental Engineering, Chosun University) ;
  • Moon, Deok Hyun (Department of Environmental Engineering, Chosun University)
  • Received : 2022.02.10
  • Accepted : 2022.02.28
  • Published : 2022.03.30
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Abstract

In this study, chemically modified biochar (NSBP500, KSBP500, OSBP500) derived from starfish was utilized to improve the adsorption ability of the SBP500 (Starfish Biochar Pyrolyzed at 500℃) in a solution contaminated with heavy metals. According to the biochar modification performance evaluation batch tests, the removal rate and adsorption amount of NSBP500 increased 1.4 times for Cu, 1.5 times for Cd, and 1.2 times for Zn as compared to the control sample SBP500. In addition, the removal rate and adsorption amount of KSBP500 increased 2 times for Cu, 1.8 times for Cd, and 1.2 times for Zn. The removal rate and adsorption amount of OSBP500 increased 5.8 times for Cu. The FT-IR analysis confirmed the changes in the generation and movement of new functional groups after adsorption. SEM analysis confirmed Cu in KSBP500 was in the form of Cu(OH)2 and resembled the structure of nanowires. The Cd in KSBP500 was densely covered in cubic form of Cd(OH)2. Lead(Pb) was in the form of Pb3(OH)2(CO3)2 in a hexagonal atomic layer structure in NSBP500. In addition, it was observed that Zn was randomly covered with Zn5(CO3)2(OH)6 pieces which resembled plates in KSBP500. Therefore, this study confirmed that biochar removal efficiency was improved through a chemical modification treatment. Accordingly, adsorption and precipitation were found to be the complex mechanisms behind the improved removal efficiency in the biochar. This was accomplished by electrostatic interactions between the biochar and heavy metals and ion exchange with Ca2+.

Keywords

Acknowledgement

본 연구는 한국연구재단(NRF)의 기초연구사업(과제번호 : 2019R1F1A1053374)의 지원으로 수행한 연구이며, 이에 감사드립니다.

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