• 제목/요약/키워드: lead particle

검색결과 260건 처리시간 0.027초

THE MICROSTRUCTURE OF Pb-DOPED SOLIDIFIED WASTE FORMS USING PORTLAND CEMENT AND CALCITE

  • Yoo, Hee-Chan;Lee, Dong-Jin
    • Environmental Engineering Research
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    • 제11권1호
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    • pp.54-61
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    • 2006
  • An electron probe microanalysis (EPMA) investigation can provide quantitative and qualitative insight into the nature of the surface and bulk chemistry on solidified waste forms(SWF). The proportion of Pb in grain areas is below 0.3 wt. %, and the proportion near the border of the grain slightly increases to 0.98 wt. % but in the inter-particle areas farther from the grain, the concentration of Pb markedly increases. It is apparent that very little Pb diffuses into the tricalcium silicate($C_3S$) particles and most of the Pb exists as precipitates of sulfate, hydroxide, and carbonate in the cavity areas between $C_3S$ grains. Calcite additions on Pb-doped SWF are also observed to induce deeper incorporation of lead into the cement grains with EPMA line-analysis of cross-sections of cement grains. The line-analysis reveals the presence of $0.2{\sim}5$ weight % Pb over $5\;{\mu}m$ from cement grain boundaries. In the inter-particle areas, the ratio of Ca, Si, Al and S to Pb is relatively similar even at some distance from the grain border and the Pb (wt. %) ratio is reasonably constant throughout the whole inter-particles area. It is apparent that the enhanced development of C-S-H on addition of calcite can increasingly absorbs lead species within the silica matrix.

Comparison of nano/micro lead, bismuth and tungsten on the gamma shielding properties of the flexible composites against photon in wide energy range (40 keV-662 keV)

  • Asgari, Mansour;Afarideh, Hossein;Ghafoorifard, Hassan;Amirabadi, Eskandar Asadi
    • Nuclear Engineering and Technology
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    • 제53권12호
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    • pp.4142-4149
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    • 2021
  • In the radiation protection application, the metal-polymer composites have been developed for their radiation shielding properties. In this research, the elastomer composites doped by 10 ㎛ and 100nm size of lead, bismuth and tungsten particles as filler with 30 and 60 wt percentages were prepared. To survey the shielding properties of the polymer composites using gamma-ray emitted from 152Eu and 137Cs sources, the gamma flux was measured by using NaI(Tl) detector, then the linear attenuation coefficient was calculated. Also, the Monte Carlo simulation (MCs) method was used. The results showed a direct relationship between the linear attenuation coefficients of the absorbent and filler ratio. Also, the decrease in the particle size of the shielding material in each weight percentage improved the radiation shielding features. When the dimension of the particles was in the order of nano-size, more attenuation was achieved. At low energies used for medical diagnostic X-ray applications due to the predominance of the photoelectric effect, bismuth and lead were suitable selection as filler.

파티클 시스템을 이용한 실시간 인터랙티브 퍼포먼스 :Rhythmic Gesture(마리오네트의 꿈)사례를 중심으로 (Real-time Interactive Performing Arts using Particle System)

  • 유미옥;박경주
    • 한국콘텐츠학회논문지
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    • 제10권9호
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    • pp.117-125
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    • 2010
  • 디지털 미디어의 발달과 컴퓨터 그래픽스 관련 연구 분야의 발달은 문화 예술의 전반적인 흐름과 일상을 바꾸어 놓았을 뿐만 아니라 뉴미디어 아트, 인터랙티브 아트, 실시간 퍼포밍 등의 신선하고 흥미로운 문화 예술 분야에 많은 영향을 미치고 있다. 본 논문은 컴퓨터 그래픽스의 파티클 시스템을 공연 영상에 접목 시켜 자연스럽게 소통하는 과정을 관객과 함께 이끌어 가는 감성적 표현 기법으로 사용하였다. 본 논문의 제안한 방법은 오브젝트 모델링에 영상을 입력받아 배우 움직임을 추적하여 파티클 시뮬레이션을 함으로서 마지막 최종 영상이 출력되게 하는 구조로 꽃잎 파티클 즉 오브젝트 모델링을 통하여 공연 영상을 실시간 파티클 시뮬레이션으로 표현한다. 이는 음향과 동작, 파티클 간에 동기화된 파티클의 생성과 위치 속도 등을 캡쳐링하여 과학기술과 예술의 접목이라는 실험적 구조 형태로 공연 영상을 만드는데 목적이 있다. 또한 파티클 시스템을 이용하여 기존 공영영상 보다 다양한 비주얼 이펙트 효과 영역을 확대된 개념의 공연성과를 볼 수 있다. 이 실험적 공연은 로봇과 영상, 그리고 배우와의 교감되는 공연구성으로 인터랙티브 융합 공연을 함으로써 더 나아가 앞으로의 인터랙티브 공연예술에서의 영역을 확장하고 표현의 확대를 할 수 있는데 목적이 있다.

Effect of Particle Size on the Dielectric and Piezoelectric Properties of 0.95(K0.5Na0.5)NbO3-0.05BaTiO3 Lead-free Piezoelectric Ceramics

  • Bae, Seon-Gi;Shin, Hyea-Gyiung;Chung, Kwang-Hyun;Yoo, Ju-Hyun;Im, In-Ho
    • Transactions on Electrical and Electronic Materials
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    • 제16권4호
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    • pp.179-182
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    • 2015
  • The particle sizes of 0.95(K0.5Na0.5)NbO3-0.05BaTiO3 powder were controlled by secondary milling time after calcination. The average particle sizes, Dmean, of 0.95(K0.5Na0.5)NbO3-0.05BaTiO3 powders were critically changed from 14.31 μm to 0.91 μm by secondary milling time. The dielectric and piezoelectric properties of 0.95(K0.5Na0.5)NbO3-0.05BaTiO3 ceramics depended on the particle sizes of powders after calcination and the secondary milling process. As secondary milling times after calcination were increased to more than 48 hr, the dielectric and piezoelectric properties of 0.95(K0.5Na0.5)NbO3-0.05BaTiO3 ceramics were deteriorated.

초음파동전기기법을 이용한 비소, 카드뮴, 납으로 오염된 사질토 정화 연구 (Removal of As, Cadmium and Lead in Sandy Soil with Sonification-Electrokinetic Remediation)

  • 오승진;오민아;이재영
    • 한국지하수토양환경학회지:지하수토양환경
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    • 제18권7호
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    • pp.1-11
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    • 2013
  • The actively soil pollution by the toxic heavy-metals like the arsenic, cadmium, lead due to the industrialization and economic activity. The uses the electrokinetic remediation of contaminated soil has many researches against the fine soil having a small size in the on going. However, it is the actual condition which the research result that is not effective due to the low surface charge of the particle and high permeability shows in the electrokinetic remediation in comparison with the fine soil in the case of the sandy soil in which the particle size is large. In this research, the electrokinetic remediation and ultrasonic wave fetch strategy is compound applied against the sandy soil polluted by the arsenic, cadmium, and lead removal efficiency of the sandy soil through the comparison with the existing electrokinetic remediation tries to be evaluated. First of all, desorption of contaminants in soil by ultrasonic extraction in the Pre-Test conducted to see desorption effective 5~15%. After that, By conducted Batch-Test results frequency output century 200 Khz, reaction time 30 min, contaminated soil used in experiment was 500 g. Removal efficiency of arsenic, cadmium, lead are 25.55%, 8.01%, 34.90%. But, As, Cd, Pb remediation efficiency less than 1% in EK1(control group).

Analysis of Mobile Lead in Soil Using Carboxylated Magnetic Particle

  • So, Hyung-Suk;Shin, Hyun-Chul;Yoo, Yeong-Seok;Schaeffer Andreas
    • Journal of Magnetics
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    • 제10권3호
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    • pp.89-92
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    • 2005
  • The analytic possibility of mobile lead contained in soil has been studied using carboxylated magnetic beads. Extraction of heavy metal was performed to contaminated soil that has been collected and supplied for tests. As experiment materials, soil sample, distilled water and magnetic beads were only used. It means that the lead was extracted under neutral condition. In this condition, only the mobile fraction of lead could be extracted by magnetic beads. The mobile lead in the soil was quickly combined with magnetic beads in the mixture process. Then, the magnetic beads were dissolved into acids after collection by external magnetic force, and the lead combined with the beads was eluted and analyzed by Graphite Furnace Atomic Absorption Spectroscopy (GFAAS). In the results of extraction experiments for 3 sandy soils, the efficiency using beads was similar to or higher than that of EDTA (Ethylendiamintetraacetic acid), which is normally used for analyzing mobile heavy metal concentration in soil. With this, it was shown that this method is a more accurate and simple method to analyze mobile lead when analyzing mobile heavy metal concentration in sandy soil, rather than conventional method using EDTA.

입자 파쇄가 사질토의 DMT 결과에 미치는 영향 (Effect of Particle Crushing on the Results on DMT in Sand)

  • 이문주;최영민;김민태;배경두;이우진
    • 한국지반공학회:학술대회논문집
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    • 한국지반공학회 2010년도 춘계 학술발표회
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    • pp.740-746
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    • 2010
  • Most important characteristics of calcareous sand are the particle angularity and hollow structure. These characteristics lead to the different behavior of calcareous sand compared to siliceous sand. This study performs a series of dilatometer test using calibration chamber, in order to analyze the effect of particle characteristic of calcareous sand on DMT indices. From experimental test, it is observed that the horizontal stress index($K_D$) and dilatometer modulus($E_D$) of calcareous Jeju sand is underestimated compared to siliceous sand. This is because the particle crushing during penetration induces the less contraction of the dilatometer membrane. A slightly smaller influence of particle crushing is reflected in $E_D$ rather than $K_D$, because $P_1$ pressure reflects the deformation characteristics of un-crushed particle relatively well. It is also observed that $K_D$ of Jeju sand is differently influenced by the vertical effective stress compared with that of siliceous sand.

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입자 크기의 함수로 나타낸 대기 중 블랙카본의 변성시간척도 (Particle-size-dependent aging time scale of atmospheric black carbon)

  • 박성훈
    • 한국입자에어로졸학회지
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    • 제5권2호
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    • pp.45-52
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    • 2009
  • Black carbon, which is a by-product of combustion of fossil fuel and biomass burning, is the component that imposes the largest uncertainty on quantifying aerosol climate effect. The direct, indirect and semi-direct climate effects of black carbon depend on its state of the mixing with other water-soluble aerosol components. The process that transforms hydrophobic externally mixed black carbon particles into hygroscopic internally mixed ones is called "aging". In most climate models, simple parameterizations for the aging time scale are used instead of solving detailed dynamics equations on the aging process due to the computation cost. In this study, a new parameterization for the black carbon aging time scale due to condensation and coagulation is presented as a function of the concentration of hygroscopic atmospheric components and the black carbon particle size. It is shown that the black carbon aging time scale due to condensation of sulfuric acid vapors varies to a large extent depending on the sulfuric acid concentration and the black carbon particle size. This result indicates that the constant aging time scale values suggested in the literature cannot be directly applied to a global scale modeling. The aging time scale due to coagulation with internally mixed aerosol particles shows an even stronger dependency on particle size, which implies that the use of a particle-size-independent aging time scale may lead to a large error when the aging is dominated by coagulation.

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IGCC 합성가스 냉각기 상부의 열유동 및 입자거동 특성에 대한 전산해석 연구 (Numerical simulations on flow and particle behaviors in the upper part of a syngas cooler for IGCC)

  • 박상빈;예인수;류창국;김봉근
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 2012년도 제45회 KOSCO SYMPOSIUM 초록집
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    • pp.147-148
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    • 2012
  • The syngas produced from coal gasification is cooled down for gas cleaning by a syngas cooler that produces steam. Due to the presence of fly slag in the syngas, erosion, slagging and corrosion especially in the upper part of the syngas cooler may cause major operational problems. This study investigates the flow, heat transfer and particle behaviors in the syngas cooler of a 300MWe IGCC plant by using computational fluid dynamics. For various operational loads and geometry, the gas and particle flows directly impinged on the wall opposite to the syngas inlet, which may lead to erosion of the membrane wall. In the evaporate channels inside the syngas cololr, the particle flows were concentrated more on the outer channel where slagging becomes more serious. The heat transfer to the wall was mainly by convection which was larger on the side wall below the inlet level.

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