• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.33 no.2
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• pp.41-48
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• 2001

This paper was made to evaluate the effect of the type of latex for coating on the printability by investigating the structure of pore such as the pore fraction, the number of pores, pore size and distribution of coated paper. The coated structure is mainly depend on the results of interaction between pigment and binder. It means that the structure of pore formed is chiefly affected by the type of latex. This physical properties of pore have a close relation with ink set-off associated with the drying rate, the speed of penetration of ink into base paper and printing gloss. Therefore it was necessary to find out the relationship between pore structure and the performance of printability by modifying the type of latex to vary the pore structure of coated paper. Acrylic latex was superior to S/B latex in the sedimentation volume, compressibility, smoothness, pore fraction and its number, the weight of transferred ink onto the coated paper and ink repellance. In contrast, water retention and ink setting were not good. in the comparison of anionic and amphoteric latex, amphoteric latex showed better performance in the thickness, smoothness, pore fraction and its number, pore size, the weight of ink transmitted and K&N ink receptivity, etc.

• Journal of Industrial Technology
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• v.21 no.B
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• pp.249-256
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• 2001

The purpose of this study was to remove the excessive air foaming which was produced in mixing the RSLMC(latex-modified concrete with rapid-setting cement) by choosing the best antifoam agent type. A series of RSLMM(latex-modified mortar with rapid-setting cement) experiments were carried out as a basic experiments for RSLMC with the main experimental variables such as antifiamer types(A, B, C, D), antifoamer contents(0, 1, 2, 3%), and latex contents(10, 15%). Air content test and compressive strength tests were carried out to measure the improved properties of RSLMM. SEM analysis, also, was carried to observe the formation of latex film. The results of RSLMM showed that the decrease of 50% air content was obtained by admixturing an antifoam agent by 1%. This made the strength enhanced and the workability be within the purposed. The best properties of compressive strengths was obtained at latex content of 15% and D antifoam agent of 1%. compressive strength increased about 32.6%. The analysis of SEM results no difference in a formation of later film.

• Proceedings of the Korea Concrete Institute Conference
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• 2002.05a
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• pp.151-156
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• 2002

Drying shrinkage cracking which may be caused by the relatively large specific surface is a matter of grave concern for latex modified concrete(LMC) overlay and rapid-setting cement latex modified concrete(RSLMC) overlay. LMC and RSLMC were studied for field applications very actively in terms of strength and durability in Korea. However, there were no considerations in drying shrinkage. Therefore, the purpose of this study was to investigate the drying shrinkage properties of LMC and RSLMC with the main experimental variables such as cement types(ordinary portland cement, rapid setting cement), latex contents(0, 5, 10, 15, 20%), W-C ratios, and curing days at a controlled environment of 60% of relative humidity and 2$0^{\circ}C$ of temperature. The drying shrinkage for specimens was measured with a digital dial gauge of Demec. The test results showed that the drying shrinkage of LMC and RSLMC were considerably lower than that of OPC and RSC, respectively. This might be attributed to the interlocking of hydrated cement and aggregates by a film of latex particles, water retention due to hydrophobic, and colloidal properties of the latexes resulting in reduced water evaporation.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.30 no.3
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• pp.63-72
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• 1998

This research was intended to evaluate the effect of carboxymethylcellulose(CMC) on the coating structure and surface strength of coated paper prepared with amphoteric latex based coating color. Printability and optical properties of coated papers were compared. The influence of the consolidation behavior of coating color on the coating structure and the surface strength of coated paper was investigated. Compared with the conventional anionic latex, amphoteric latex formed bulkyer, smoother and more porous coating layer, which in turn, restricted binder migration in the coating layers, and facilitated immobilization of coating colors. However, dry pick strength of coated paper was decreased. The addition of CMC to these systems had strongly influenced on. the consolidation behavior and porosity in the dry state, through forming the network structure of coating layers by the interaction with amphoteric latex particles. Thus, printability and optical properties of coated papers were improved. Results indicated that amphoteric latex could be practically applied to the paper coating to improve printability and optical properties of coated papers.

• Journal of Industrial Technology
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• v.22 no.A
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• pp.161-168
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• 2002

Latex modified concrete is governed by both cement hydration and polymer film formation processes in its binder phase. Such the reactions are expected to improve the polymer-cement co-matrixes themselves and the bond between the cement hydrates and aggregates, and to improve the properties of hardened latex-modified concrete. The purpose of this study was to study the strength and chemical resistance of Rapid-setting latex modified concrete(RSLMC) with the main experimental variables such as latex content(0, 5, 10, 15, 20%) and water-cement ratio(36, 38, 40%) at latex content 15%. Water absorption test was earned out to estimate water permeability resistance. Chemical resistance test was carried out to measure the weight change and to observe the appearance of RSLMC immersion in hydrochloric acid, sulfuric acid, and calcium choloride.

• Journal of the Korean Wood Science and Technology
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• v.25 no.3
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• pp.75-82
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• 1997

To improve the quality of coated paper, the continuous research to the coating components and development of alternative latices is required. Recently, amphoteric latex is getting a great concern due to their changable properties of surface charge through controlling pH and some methods have been tried to prepare amphoteric latices. This study was carried out to synthesize amphoteric latex using seeding polymerization method with low concentration emulsifier. Styrene was used as a main monomer in addition to acrylonitrile for a hydrophilic comonomer. acrylic acid for a anionic comonomer and N,N-dimethylaminoethyl methacrylate for a cationic comonomer. Particle size and viscosity of latex were greatly affected by addition of acrylic acid and ammonium persulfate as an initiator. Negative charge of latex in alkali condition was changed to zero to positive charge in around pH 4.

• Journal of Industrial Technology
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• v.21 no.B
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• pp.317-324
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• 2001

This study focused on the investigation of strength development and permeability of LMC(Latex Modified Concrete) and RSLMC(Rapid-Setting Cement Latex Modified Concrete) as the latex content, cement types and w/c ratio changed. The compressive strength of latex modified concrete decreased slightly and the flexural strength increased quitely at 15% of latex content. This may be due to the flexibility of latex filled in voids and interconnections of hydrated cement and aggregates by a film of latex particles, respectively. The permeability test results showed that the permeability of LMC was considerably lower than that of conventional concrete. Results of chloride permeability test, for RSLMC indicated very low at an early age caused by the early formation of needle-shape ettringites and latex film.

• Elastomers and Composites
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• v.39 no.4
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• pp.301-308
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• 2004

Three types of parylene (PA-N, PA-C, PA-D) were used for coating the surface on natural latex rubbers in order to improve surface characteristics including mechanical properties and biocompatibility. The parylene coating was the CVD (chemical vapor deposition) method, and the surface properties of the modified latex were measured. Annealing effects on the mechanical properties of the coated latex were also investigated. The adhesion between latex and parylene was good for all the types of parylene used. As annealing temperature was increased, latex modified with PA-N became more hydrophobic, while the latex treated with PA-C and PA-D became more hydrophilic. As the annealing temperature was raised, the tensile strength was increased, and the elongation was decreased. The biocompatibility was noticeably improved on the latex surface modified with the parylenes through CVD method.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.34 no.1
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• pp.22-29
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• 2002

The coated paper was greatly affected by the basic physical properties of the binder as well as the amount of the coating formula. High glass transition temperature (Tg) of the styrene-butadiene (SB) latex, selected as the binder in our study, gave the high stiffness to the coated paper, but lowered the binding force and print gloss. The average particle size of the SB latex also greatly affected to the coated paper so that the smaller particle size improved the rheological property of the coating formula and increased the binding force and print gloss. Another property of the SBR latex, gel content, was important because when its value was small, the latex was easily deformed at the high temperature and increased air permeability to the coated paper. Therefore, the lower gel content consequently resulted in the higher blistering resistance, especially in the web paper. The larger portion of the SB latex in the coated formula improved the binding force and print gloss, but decreased the ink set-off and ink-trapping to the coated paper. The heavier coating improved optical properties such as opacity, paper gloss and paper smoothness, to the coated paper.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.35 no.1
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• pp.13-18
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• 2003

This study was done in an effort to evaluate the possibility of recyclability of moisture-proof paper. Because it is difficult to recycle laminated moisture-proof paper, a mixture of styrene-butadiene latex(SB latex) and wax emulsion was used as moisture-proof paper chemicals. A bar coater was applied to make moisture-proof paper and the coated weight was 17 g/$m^2$. The mixing ratios of SB latex to wax emulsion were 85 : 15, 87 : 13, and 90 : 10, respectively. It was observed that the moisture-proof paper treated with SB latex and wax emulsion at the appropriate ratio could be recycled effectively. The moisture-proof paper was similar to base paper in degree of pulping, and there was no significant difference in dispersion between moisture-proof paper and base paper. Most of wax particle which caused the spots during drying process could be removed by flotation process. Tensile strength and tear strength of handsheets made of both moisture-proof paper and base paper after pulping was measured to examine the fiber bonding and no significant difference in mechanical properties was observed.