• Title/Summary/Keyword: latent properties

Search Result 187, Processing Time 0.021 seconds

Effects of Strain-Induced Crystallization on Mechanical Properties of Elastomeric Composites Containing Carbon Nanotubes and Carbon Black (탄소나노튜브 및 카본블랙 강화 고무복합재료의 변형에 의한 결정화가 기계적 특성에 미치는 영향)

  • Sung, Jong-Hwan;Ryu, Sang-Ryeoul;Lee, Dong-Joo
    • Transactions of the Korean Society of Mechanical Engineers A
    • /
    • v.35 no.9
    • /
    • pp.999-1005
    • /
    • 2011
  • The effects of strain-induced crystallization (SIC) on the mechanical properties of elastomeric composites as functions of extension ratio (${\lambda}$), multiwalled carbon nanotube (CNT) content, and carbon black (CB) content are investigated. The differential scanning calorimetry (DSC) analysis shows that the degree of crystallinity increases with the increase in the CB and CNT content. As ${\lambda}$ increases, the glass transition temperature (Tg) of the composites increases, and the latent heat of crystallization (LHc) of the composites is maximum at ${\lambda}$=1.5. It is found that the mechanical properties have a linear relation with LHc, depending on the CNT content. According to the TGA (thermogravimetric analysis), the weight loss of the composite matrix is 94.3% and the weight of the composites decreases with the filler content. The ratio of tensile modulus ($E_{comp}/E_{matrix}$) is higher than that of tensile strength (${\sigma}_{comp}/{\sigma}_{matrix}$) because of the CNT orientation inside the elastomeric composites.

Psychometric Properties of the Korean Version of 12-Item Obsessive-Compulsive Inventory in Accordance With Obsessive-Compulsive Symptom Dimensions in Individuals With Obsessive-Compulsive Disorder (강박장애 환자에서 강박증상차원에 부합하는 12문항 강박증상목록의 심리측정적 특성)

  • Ho Seok Seo;Mina Choi;Seung Jae Lee
    • Anxiety and mood
    • /
    • v.19 no.1
    • /
    • pp.10-18
    • /
    • 2023
  • Objective : The 18-item Obsessive-Compulsive Inventory-Revised (OCI-R) is widely employed to assess symptoms of obsessive-compulsive disorder (OCD). However, this instrument's factor structure does not align with contemporary dimensional models of OCD. Therefore, the objective of this study was to examine psychometric properties of the 12-item Korean OCI (OCI-12) on four obsessive-compulsive symptom dimensions, in patients with OCD. Methods : A total of 157 patients with OCD and 51 healthy controls completed psychological measures, including the OCI-R, Dimensional Obsessive-Compulsive Scale (DOCS), and scales evaluating anxiety and depressive symptoms. Pychometric characteristics of the OCI-12 with three neutralizing and three hoarding items eliminated from the OCI-R, were analyzed. Results : All OCI-12 items registered excellent internal consistency at 0.83. Confirmatory factor analysis revealed strong association between individual items and their proposed latent factors (i.e., subscales). Convergent validity was appropriate. A high correlation was particularly observed for the DOCS score (r=0.71, p<0 .001). Moreover, the OCI-12 was as sensitive as the OCI-R for determining effects of empirically supported treatment for OCD. Conclusion : The OCI-12 is a 12-item measure that adheres to the prevailing 4-factor model of OCD dimensions. Like OCI-R, it possesses good to excellent psychometric properties, including reliability, validity, and sensitivity to treatment.

Regulation of Tumor Neceosis Factor-${\alpha}$ Receptors and Signal Transduction Pathways

  • Han, Hyung-Mee
    • Toxicological Research
    • /
    • v.8 no.2
    • /
    • pp.343-357
    • /
    • 1992
  • Tumor necrosis factor-${\alpha}$(TNF), a polypeptide hormone secreted primarily by activated macrophages, was originally identified on the basis of its ability to cause hemorrhagic necrosis and tumor regression in vivo. Subsequently, TNF has been shown to be an important component of the host responses to infection and cancer and may mediate the wasting syndrome known as cachexia. These systemic actions of TNF are reflected in its diverse effects on target cells in vitro. TNF initiates its diverse cellular actions by binding to specific cell surface receptors. Although TNF receptors have been identified on most of animal cells, regulation of these receptors and the mechanisms which transduce TNF receptor binding into cellular responses are not well understood. Therefore, in the present study, the mechanisms how TNF receptors are being regulated and how TNF receptor binding is being transduced into cellular responses were investigated in rat liver plasma membranes (PM) and ME-180 human cervical carcinoma cell lines. $^{125}I$-TNF bound to high ($K_d=1.51{\pm}0.35nM$)affinity receptors in rat liver PM. Solubilization of PM with 1% Triton X-100 increased both high affinity (from $0.33{\pm}0.04\;to\;1.67{\pm}0.05$ pmoles/mg protein) and low affinity (from $1.92{\pm}0.16\;to\;7.57{\pm}0.50$ pmoles/mg protein) TNF binding without affecting the affinities for TNF, suggesting the presence of a large latent pool of TNF receptors. Affinity labeling of receptors whether from PM or solubilized PM resulted in cross-linking of $^{125}I$-TNF into $M_r$ 130 kDa, 90 kDa and 66kDa complexes. Thus, the properties of the latent TNF receptors were similar to those initially accessible to TNF. To determine if exposure of latent receptors is regulated by TNF, $^{125}I$-TNF binding to control and TNF-pretreated membranes were assayed. Specific binding was increased by pretreatment with TNF (P<0.05), demonstrating that hepatic PM contains latent TNF receptors whose exposure is promoted by TNF. Homologous up-regulation of TNF receptors may, in part, be responsible for sustained hepatic responsiveness during chronic exposure to TNF. As a next step, the post-receptor events induced by TNF were examined. Although the signal transduction pathways for TNF have not been delineated clearly, the actions of many other hormones are mediated by the reversible phosphorylation of specific enzymes or target proteins. The present study demonstrated that TNF induces phosphorylation of 28 kDa protein (p28). Two dimensional soidum dodecyl sulfate-polyacrylamide gel electrophoresis(SDS-PAGE) resolved the 28kDa phosphoprotein into two isoforms having pIs of 6.2 and 6.1. The pIs and relative molecular weight of p28 were consistent with those of a previously characterized mRNA cap binding protein. mRNA cap binding proteins are a class of translation initiation factors that recognize the 7-methylguanosine cap structure found on the 5' end of eukaryotic mRNAs. In vitro, these proteins are defined by their specific elution from affinity columns composed of 7-methylguanosine 5'-triphosphate($m^7$GTP)-Sepharose. Affinity purification of mRNA cap binding proteins from control and TNF treated ME-180 cells proved that TNF rapidly stimulates phosphorylation of an mRNA cap binding protein. Phosphorylation occurred in several cell types that are important in vitro models of TNF action. The mRNA cap binding protein phosphorylated in response to TNF treatment was purifice, sequenced, and identified as the proto-oncogene product eukaryotic initiation factor-4E(eIF-4E). These data show that phosphorylation of a key component of the cellular translational machinery is a common early event in the diverse cellular actions of TNF.

  • PDF

Analysis of a Cryogenic Nitrogen-Ambient Air Heat Exchanger Including Frost Formation (착상을 고려한 극저온 질소-대기 열교환기의 해석)

  • 최권일;장호명
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
    • /
    • v.12 no.9
    • /
    • pp.825-834
    • /
    • 2000
  • A heat exchanger analysis is performed to investigate the heating characteristics of cryogenic nitrogen by ambient air for the purpose of cryogenic automotive propulsion. The heat exchanger is a concentric triple-passage for supercritical nitrogen, and the radial fins are attached on the outermost tube for the crossflow of ambient air. The temperature distribution is calculated for the nitrogen along the passage, including the real gas properties of nitrogen, the fluid convections and the conductions through the tube walls and the fins. Since the wall temperature of the outer (ambient side) tube is very low in most cases, a heavy frost can be formed on the surface, affecting the heat exchange performance. By the method of the similarity between the heat and the mass transfer of moist air, the frost growth and the time-dependent effectiveness of the heat exchanger are calculated for various operating conditions. It is concluded that the frost formation can augment the heating of nitrogen during the initial period because of the latent heat, then gradually degrades the heat exchange because of the increased thermal resistance. Practical design issues are discussed for the flow rate of nitrogen, the velocity and humidity of ambient air, and the sizes of the fin.

  • PDF

Effect of Ground Granulated Blast Furnace Slag, Pulverized Fuel Ash, Silica Fume on Sulfuric Acid Corrosion Resistance of Cement Matrix

  • Jeon, Joong-Kyu;Moon, Han-Young;Ann, Ki-Yong;Kim, Hong-Sam;Kim, Yang-Bea
    • International Journal of Concrete Structures and Materials
    • /
    • v.18 no.2E
    • /
    • pp.97-102
    • /
    • 2006
  • In this study, the effect of supplementary materials(GGBS, PFA, SF) on sulfuric acid corrosion resistance was assessed by measuring the compressive strength, corroded depth and weight change at 7, 28, 56, 91, 180 and 250 days of immersion in sulfuric acid solution with the pH of 0.5, 1.0, 2.0 and 3.0. Then, it was found that an increase in the duration of immersion and a decrease in the pH, as expected, resulted in a more severe corrosion irrespective of binders: increased corroded depth and weight change, and lowered the compressive strength. 60% GGBS mortar specimen was the most resistant to acid corrosion in terms of the corroded depth, weight change and compressive strength, due to the latent hydraulic characteristics and lower portion of calcium hydroxide. The order of resistance to acid was 60% GGBS>20% PFA>10% SF>OPC. In a microscopic examination, it was found that acid corrosion of cement matrix produced gypsum, as a result of decomposition of hydration products, which may loose the structure of cement matrix, thereby leading to a remarkable decrease of concrete properties.

Effect of Flue Gas Heat Recovery on Plume Formation and Dispersion

  • Wu, Shi Chang;Jo, Young Min;Park, Young Koo
    • Particle and aerosol research
    • /
    • v.8 no.4
    • /
    • pp.161-172
    • /
    • 2012
  • Three-dimensional numerical simulation using a computational fluid dynamics (CFD) was carried out in order to investigate the formation and dispersion of the plume discharged from the stack of a thermal power station. The simulation was based on the standard ${\kappa}{\sim}{\varepsilon}$ turbulence model and a finite-volume method. Warm and moist exhaust from a power plant stack forms a visible plume as entering the cold ambient air. In the simulation, moisture content, emission velocity and temperature of the flue gas, air temperature and wind speed were dealt with the main parameters to analyze the properties of the plume composed mainly of water vapor. As a result of the simulation, the plume could be more apparent in cold winter due to a big difference of latent heat capacity. At no wind condition, the white plume rises 120 m upward from the top of the stack, and expands to 40 m around from the stack in cold winter after flue gas heat recovery. The influencing distance of relative humidity will be about 100 m to 400 m downstream from the stack with a cross wind effect. The decrease of flue gas temperature by heat recovery of thermal energy facilitates the formation of the plume and restrains its dispersion. Wind speed with vertical distribution affects the plume dispersion as well as the density.

Analytical Study of heat Transfer in Evaporative Cooling of a Porous Layer (다공층의 증발냉각 열전달에 관한 해석적 연구)

  • 김홍제;이진호
    • Transactions of the Korean Society of Mechanical Engineers
    • /
    • v.16 no.1
    • /
    • pp.104-111
    • /
    • 1992
  • In this study, the heat transfer characteristics of the evaporative transpiration cooled system is analytically investigated considering the occurrence of the two-phase evaporation zone. Under the condition of the external heat input, analytical solutions of the three regions (i.e., vapor, liquid and two-phase evaporation zone) are respectively obtained using the matching conditions for the steady-state problem where properties are constant. As results, the length of the evaporation zone increases with increasing heat input and with decreasing mass flow rate. It also increases with increasing particle size, system porosity, thermal conductivity of material, inlet temperature and latent heat of coolant. The position of the lower interface of the evaporation zone have a lot of efforts on the evaporation zone length, the position of the upper interface penetrates deeper into the porous layer with lower thermal conductivity of porous material, higher system porosity and larger particle size.

Fininte element analysis of electron beam welding considering for moving heat source (이동 열원을 고려한 전자빔 용접의 유한요소해석)

  • Cho, Hae-Yong;Jung, Seok-Young;Kim, Myung-Han;Cho, Chang-Yong;Lee, Je-Hoon;Seo, Jung
    • Laser Solutions
    • /
    • v.4 no.1
    • /
    • pp.21-28
    • /
    • 2001
  • Simulation on the electron beam welding of Al 2219 alloy was carried out by using commercial FEM code MARC, which encounters moving heat sources. Due to axisymmetry of geometry, a half of the cylinder was simulated. A coupled thermo-mechanical analysis was carried out and subroutine for heat flux was substituted in the program. The material properties such as specific heat, heat transfer coefficient and thermal expansion coefficient were given as a function of temperature and the latent heat associated with a given temperature range is considered. As a result, the proper beam power is 60㎸${\times}$60㎃ and welding speed is 1∼1.5 m/min. The residual stress in the heat-affected zone as well as the fusion zone does not increase. It is necessary to use jigs for preventing distortion of cylinder and improving weld quality.

  • PDF

Preparation of spherical shape of PCM by using sodium acetate trihydrate (Sodium Acetate Trihydrate를 이용한 구형의 PCM 입자의 제조)

  • Kim, Jong-Kuk;Jung, Kyeong-Taek;Shul, Yong-Gun;Kim, Dong-Hyung;Lee, Tae-Kyu
    • Solar Energy
    • /
    • v.17 no.2
    • /
    • pp.67-74
    • /
    • 1997
  • Spherical shape of phase change material(PCM) has been prepared by using sodium acetate trihydrate as a latent heat storage medium. Gelatin was used as an effective thickener to prevent undesirable phase separation. Sodium pyrophosphate decahydrate was used as nucleator to decrease the degree of supercooling in the thickened phase change material. Spherical PCM particles of 3-3.5 mm in diameter continuously manufactured with molten PCM with those conditions. The particle size of PCM was not affected by the effluent velocity of molten PCM in range of 1.3-1.8 ml/min. DSC, SEM and XRD were also used to characterize the properties of PCM particles.

  • PDF

A Determinant Factors on Supply Chain Performance of Shipping and Logistics Firm in International Logistics (국제물류에서 해운물류기업의 공급사슬성과 결정요인)

  • Yun, Kwang-Woon;Bae, Hee-Sung
    • THE INTERNATIONAL COMMERCE & LAW REVIEW
    • /
    • v.30
    • /
    • pp.3-26
    • /
    • 2006
  • Supply chain is viewed as a number of organizations(at least three) working cooperatively with at least some shared objectives. The concept of supply chain management represents the most advanced state in the evolutionary development of purchasing, procurement and other supply chain activities. This study aims to analyze and develop a measurement instrument for supply chain performance in international logistics. A measurement instrument for supply chain performance in international logistics are developed by Lai et al(2002). Supply chain reliability, customer service and cost are constructed reflecting service effectiveness and operations efficiency between shipper, forwarder and liner. The results of this study are as follow. We firstly tested the measurement properties of the sub-dimension of the supply chain performance construct using reliability test and confirmatory factor analysis follow by exploratory factor analysis. For each of the factor, reliability and validity are achieved because of the significant loading of the measurement items on their latent factors. Further research perform the analysis of variance by multi respondents within each firm and across partner firms in the supply chain. The result of analysis present the difference with shipper, forwarder and liner in statistics.

  • PDF