• Title/Summary/Keyword: large square

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Electrooxidation of Zolpidem and its Voltammetric Quantification in Standard and Pharmaceutical Formulation using Pencil Graphite Electrode

  • Naeemy, A.;Sedighi, E.;Mohammadi, A.
    • Journal of Electrochemical Science and Technology
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    • v.7 no.1
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    • pp.68-75
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    • 2016
  • In this study a new, simple, precise, accurate and economic electrochemical method was developed and validated for the voltammetric determination of zolpidem (ZP) using disposable pencil graphite (PG) electrode. The anodic oxidation of ZP on the surface of the PG electrode was examined in a britton robinson (BR) buffer. Square wave and cyclic voltammetry were used as electrochemical techniques in the potential range of 0-1.2 V in the pH 8 BR buffer. In cyclic voltammetry studies, the diffusion coefficient of ZP oxidation was found to be 3.6×10-6 cm2 s-1. On the other hand, the ZP has shown a well-defined irreversible anodic peak at 0.98 V in the square wave voltammetry mode. The PG electrode, primarily being graphite which has a large active surface area gives rise to increasing peak current with respect to ZP electrooxidation. PG electrode showed an electrocatalytic effect in anodic oxidation of ZP. A linear relationship between catalytic current response and ZP concentration was obtained over a concentration range of 10-30 μM with R.S.D. values ranging from 0.29-3.89. Limits of detection and quantitation were found to be 1 and 3 μM, respectively. Finally, the PG electrode was successfully used to determine ZP in standard and tablet dosage forms with a mean recovery of 100.69 %.

Comparison of Model Fitting & Least Square Estimator for Detecting Mura (Mura 검출을 위한 Model Fitting 및 Least Square Estimator의 비교)

  • Oh, Chang-Hwan;Joo, Hyo-Nam;Rew, Keun-Ho
    • Journal of Institute of Control, Robotics and Systems
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    • v.14 no.5
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    • pp.415-419
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    • 2008
  • Detecting and correcting defects on LCD glasses early in the manufacturing process becomes important for panel makers to reduce the manufacturing costs and to improve productivity. Many attempts have been made and were successfully applied to detect and identify simple defects such as scratches, dents, and foreign objects on glasses. However, it is still difficult to robustly detect low-contrast defect region, called Mura or blemish area on glasses. Typically, these defect areas are roughly defined as relatively large, several millimeters of diameter, and relatively dark and/or bright region of low Signal-to-Noise Ratio (SNR) against background of low-frequency signal. The aim of this article is to present a robust algorithm to segment these blemish defects. Early 90's, a highly robust estimator, known as the Model-Fitting (MF) estimator was developed by X. Zhuang et. al. and have been successfully used in many computer vision application. Compared to the conventional Least-Square (LS) estimator the MF estimator can successfully estimate model parameters from a dataset of contaminated Gaussian mixture. Such a noise model is defined as a regular white Gaussian noise model with probability $1-\varepsilon$ plus an outlier process with probability $varepsilon$. In the sense of robust estimation, the blemish defect in images can be considered as being a group of outliers in the process of estimating image background model parameters. The algorithm developed in this paper uses a modified MF estimator to robustly estimate the background model and as a by-product to segment the blemish defects, the outliers.

Variable Step LMS Algorithm using Fibonacci Sequence (피보나치 수열을 활용한 가변스텝 LMS 알고리즘)

  • Woo, Hong-Chae
    • Journal of the Institute of Convergence Signal Processing
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    • v.19 no.2
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    • pp.42-46
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    • 2018
  • Adaptive signal processing is quite important in various signal and communication environments. In adaptive signal processing methods since the least mean square(LMS) algorithm is simple and robust, it is used everywhere. As the step is varied in the variable step(VS) LMS algorithm, the fast convergence speed and the small excess mean square error can be obtained. Various variable step LMS algorithms are researched for better performances. But in some of variable step LMS algorithms the computational complexity is quite large for better performances. The fixed step LMS algorithm with a low computational complexity merit and the variable step LMS algorithm with a fast convergence merit are combined in the proposed sporadic step algorithm. As the step is sporadically updated, the performances of the variable step LMS algorithm can be maintained in the low update rate using Fibonacci sequence. The performances of the proposed variable step LMS algorithm are proved in the adaptive equalizer.

Performance Enhancement Technique in Visible Light Communication System for Smart Building (스마트 빌딩을 위한 가시광 통신 시스템의 성능 향상 기법)

  • Seo, Sung-Il
    • The Journal of the Institute of Internet, Broadcasting and Communication
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    • v.20 no.5
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    • pp.39-43
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    • 2020
  • In this paper, we propose the multi-channel interference cancellation algorithm for visible light communication (VLC) in smart building. The VLC system is communication technology using visible rays that come out in Light Emitting Diode (LED) device. It has energy curtailment effect and possible to use in ubiquitous network service applications. When a large number of users communicate indoors, the performance can be reduced due to channel interference. To remove interference, at the first, the minimum mean square error (MMSE) scheme as interference cancellation methods used, and then the successive interference cancellation (SIC) is applied to obtain additional diversity gain and improve interference cancellation performance. Indoor VLC channel model is employed. The performance is evaluated in terms of bit error rate (BER). From the simulation results, it is confirmed that the proposed scheme has better BER performance compared to the previous systems. As a result, the proposed interference cancellation improves the signal quality of VLC systems by effectively removing the channel noise. The results of the paper can be applied to VLC for smart building and general communication systems.

Radioassay of Multiple Beta-Labeled Mixtures using Least-Square Method (최소자승법을 이용한 다수 베타 방출 핵종 혼합물의 방사능 분석)

  • Seon, Kwang-Il;Nam, Uk-Won;Kong, Kyoung-Nam;Kim, Chang-Kyu;Lee, Dong-Myung;Lee, Sang-Kook
    • Journal of Radiation Protection and Research
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    • v.26 no.4
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    • pp.375-384
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    • 2001
  • It is possible to count and perform quench correction on two ${\beta}$ -label samples so long as the maximum ${\beta}$-energies are sufficiently different. However, when 4he conventional technique is applied to the radioassay of a mixture of more than three nuclides, the reliability of the activities determined is considerably reduced, resulting from the large overlapping of liquid scintillation pulse height distributions of each nuclide. A technique that allows the activities of multiple ${\beta}$-labeled samples to be radioassayed was proposed by using the least square method. The technique was applied to mixture samples of $^3H,\;^{14}C,\;^{36}Cl$, and $^{90}Sr$. The analytical values were in good agreement with the reference values within 7% relative error.

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Performance Improvement Algorithm for Wireless Localization Based on RSSI at Indoor Environment (RSSI의 거리 추정 방식에 바탕을 둔 실내 무선 측위 성능 향상 알고리즘)

  • Park, Joo-Hyun;Lee, Jung-Kyu;Kim, Seong-Cheol
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.36 no.4C
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    • pp.254-264
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    • 2011
  • In this paper, we propose two algorithm for improving the performance of wireless localization(Trilateration and Least Square) based on the range based approach method in indoor environment using RSSI for ranging distance. we propose a method to discriminate the case that has relatively large estimation errors in trilateration using Heron''s formula for the volume of a tetrahedron. And we propose the algorithm to process the discriminated types of distance using the absolute value calculated by Heron''s formula. In addition, we propose another algorithm for the case of which the number of anchor nodes larger than three. In this case, Residual Weighting Factor(RWGH) improves the performance of Least Square. However, RWGH requires many number of calculations. In this paper, we propose Iterative Weighted Centroid Algorithm(IWCA) that has better performance and less calculation than RWGH. We show the improvement of performance for two algorithms and the combination of these algorithm by using simulation results.

A Study on the Treatment of Uncertainty in Linear Regression Method for Chemical Analysis (회귀식 사용에 따른 화학 분석 과정의 불확도 처리 연구)

  • Woo, Jin-Chun;Suh, JungKee;Lim, MyungChul;Park, MinSu
    • Analytical Science and Technology
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    • v.16 no.3
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    • pp.185-190
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    • 2003
  • We applied modified least square method (MLS) and ordinary least square method (OLS) to 1st order equation for the comparison of the uncertainties calculated by these methods. The uncertainty calculated by OLS covered statistically safe interval because it was over-estimated in many cases of measurement and concentration level. But, if the uncertainty of the concentration as a reference value was comparably large (about 5% of the relative standard deviation of random scattering from the regression line and about 7% of relative standard uncertainty of reference values), then uncertainty calculated by OLS was seriously under-estimated at high concentration level. It was revealed that the calculated uncertainty didn't cover statistically safe interval at the stated confidence level. It was found that the method, MLS, described in the previously article would be valid for this calculation of uncertainty.

The efficient implementation of the multi-channel active noise controller using a low-cost microcontroller unit (저가 microcontoller unit을 이용한 효율적인 다채널 능동 소음 제어기 구현)

  • Chung, Ik Joo
    • The Journal of the Acoustical Society of Korea
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    • v.38 no.1
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    • pp.9-22
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    • 2019
  • In this paper, we propose a method that can be applied to the efficient implementation of multi-channel active noise controller. Since the normalized MFxLMS (Modified Filtered-x Least Mean Square) algorithm for the multi-channel active noise control requires a large amount of computation, the difficulty has lied in implementing the algorithm using a low-cost MCU (Microcontoller Unit). We implement the multi-channel active noise controller efficiently by optimizing the software based on the features of the MCU. By maximizing the usage of single-cycle MAC (Multiply- Accumulate) operations and minimizing move operations of the delay memory, we can achieve more than 3 times the performance in the aspect of computational optimization, and by parellel processing using the auxillary processor included in the MCU, we can also obtain more than 4 times the performance. In addition, the usage of additional parts can be minimized by maximizing the usage of the peripherals embedded in the MCU.

ESTIMATED PRODUCTIVITY OF THE GIANT MAGELLAN TELESCOPE (거대 마젤란 망원경의 논문 생산성 예측)

  • Ahn, S.H.;Park, B.G.;Kim, Y.S.;Chun, M.Y.;Kim, H.I.;Sung, H.I.;Lee, D.W.;Kim, S.C.
    • Publications of The Korean Astronomical Society
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    • v.23 no.2
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    • pp.123-128
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    • 2008
  • Productivity of the Giant Magellan Telescope is estimated based on the annual number of papers produced by the currently operating large telescopes such as the telescope at the ESO La Silla observatory, CFHT, AAT, the Magellan telescopes, ESO VLT, Japanese Subaru, the Gemini telescopes, and the Keck telescopes. We find that the amount of papers produced by a large telescope is roughly proportional to the diameter of its primary mirror. With this fact, we estimate the SCI-paper productivity of the Giant Magellan Telescope by extrapolating the productivity of the above-mentioned large telescopes. Moreover, according to the paper written in 2001 by Benn and Sanchez, the amount of highly-cited papers produced by a large telescope is roughly proportional to the light-gathering power of the telescope or the square of the diameter. Hence, we survey the productivity of Nature-class papers of the large telescopes and extrapolate the relationship to estimate the productivity of the Nature-class papers by using the Giant Magellan telescope of a filled aperture 21.4 meters in diameter. We expect that Korean astronomers will be able to produce annually 60 SCI-class papers and 20 Nature-class papers with high scientific impact by using the telescope-time corresponding to the 10% share of the Giant Magellan Telescope.

Large-Displacement Electromagnetic Actuators with the Meander Springs Partially Exposed to Magnetic Field (부분적으로 자기장에 노출된 굴곡형 스프링을 이용한 대변위 전자기력 구동기)

  • Seo, Dae-Geon;Han, Won;Cho, Young-Ho
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.36 no.5
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    • pp.481-486
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    • 2012
  • We discuss the design, fabrication, and testing of a large-displacement electromagnetic actuator with the meander springs partially exposed to a magnetic field. We compared two prototypes: a prototype (F) of the conventional actuator with the meander springs fully exposed to a magnetic field and a prototype (P) of the proposed actuator with the meander springs partially exposed to a magnetic field. For a 5 Hz square input current varying from 10.40 mA, P showed an increase of $16.9{\pm}1.2%$ in the amplitude, which was greater than the increase in the case of F. Thus, we experimentally demonstrated the large-displacement actuation performance of the proposed actuator in a small volume and at low currents (below 40 mA). The proposed electromagnetic actuator can be used for low-power and large-displacement manipulation of optical switches and optical choppers.